Cellular metal screen catalyst for selective catalytic reduction of nitrogen oxide and preparation method thereof

A honeycomb metal and nitrogen oxide technology, applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc. The problem of poor quality and performance, to achieve the effect of improved thermal shock resistance, rapid thermal response, and good catalytic performance

Inactive Publication Date: 2009-03-25
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to solve the problems of poor thermal shock resistance, poor mass transfer performance and slow thermal response of catalysts commonly used in the existing SCR process technology, and the catalyst is easily inactivated by dust and fly ash blocking the pores, resulting in poor catalytic performance and To solve the problem of high cost, and provide a selective catalytic reduction of nitrogen oxides honeycomb metal mesh catalyst and its preparation method

Method used

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Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0009] Specific Embodiment 1: In this embodiment, the selective catalytic reduction of nitrogen oxides honeycomb metal mesh catalyst consists of a wire mesh, a carrier deposited on the wire mesh, and V loaded on the carrier. 2 o 5 and MoO 3 composition; the wire mesh is a three-dimensional transparent structure, and the carrier is Al 2 o 3 and TiO 2 .

specific Embodiment approach 2

[0010] Specific embodiment two: the method for preparing selective catalytic reduction of nitrogen oxide honeycomb metal mesh catalyst in this embodiment is realized according to the following steps: the method for preparing selective catalytic reduction of nitrogen oxide honeycomb metal mesh catalyst is realized according to the following steps: a. Pretreat the wire mesh and pure aluminum powder respectively; b. Prepare 500-1000 parts by mass of absolute ethanol, 0.2-1 part of aluminum isopropoxide and 5-12 parts of pure aluminum powder after pretreatment. Mix aluminum powder and ultrasonically oscillate for 4 to 5 hours, then use it as an electrophoretic solution; c, inject the electrophoretic solution into the electrophoresis tank, use the pretreated wire mesh as the cathode, graphite as the anode, and the distance between the two electrodes is 10mm, and conduct electrophoretic deposition for 1 to 2 2min; d. After deposition, take out the cathode, dry it at room temperature ...

specific Embodiment approach 3

[0014] Specific embodiment three: the difference between this embodiment and specific embodiment two is that in step a, 950 parts of absolute ethanol, 0.7 parts of aluminum isopropoxide and 10 parts of pretreated pure aluminum powder are mixed according to the mass fraction, Ultrasonic oscillation for 4.5h. Other steps and parameters are the same as in the second embodiment.

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Abstract

Disclosed is a selective catalytic reduction nitrogen oxide honeycomb metallic sieve catalyst as well as a preparation method thereof, relating to a catalyst as well as a preparation method thereof. The invention solves the problems of poor thermal shock resistance, poor mass transfer performance, slow thermal response, poor catalytic performance and high treatment cost of the catalyst in common use in the existing SCR process technique. The selective catalytic reduction nitrogen oxide honeycomb metallic sieve catalyst is composed of a wire mesh, a carrier depositing on the wire mesh as well as V2O5 and MoO3 loading on the carrier. The method comprises: a. material pretreatment; b. preparing an electrophoretic liquid; c. electrophoretic deposition; d. making an Al2O3 / wire mesh; e. making a TiO2 / Al2O3 / wire mesh; and f. weaving a honeycomb metallic sieve, then obtaining the selective catalytic reduction nitrogen oxide honeycomb metallic sieve catalyst after dipping, drying and calcinations. The invention has advantages of good catalyst catalytic performance, low cost, good thermal shock resistance, good mass transfer performance and fast thermal response.

Description

technical field [0001] The invention relates to a catalyst and a preparation method thereof. Background technique [0002] Nitrogen oxides (NO x ) to air pollution is a worldwide environmental problem, and its impact on the atmosphere mainly includes acid rain and higher ground ozone concentration. my country NO x The emission is estimated to be more than 10 million tons, and it will continue to grow with the development of the economy. NO x Emissions will also continue to increase. For NO in industrial waste gas x Pollution control methods can be divided into two categories: preventing NO x Production and removal of NO x . Commonly used to prevent NO x produced by way of low NO x Combustion technology and boiler improvement technology. remove NO x The commonly used methods are selective non-catalytic reduction technology (SNCR) and selective catalytic reduction technology (SCR). The SCR process technology is the future NOx due to its high efficiency, high selecti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/28B01J23/22B01J35/04B01D53/56
Inventor 姚杰翟旭李俊生
Owner HARBIN INST OF TECH
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