Method for jointly treating high-fluorine sewage by utilizing waste slag

A combined treatment and high fluorine technology, applied in water/sewage treatment, chemical instruments and methods, multi-stage water/sewage treatment, etc., can solve problems such as unfavorable sustainable development, environmental pollution, harmful animal and plant growth, etc.

Inactive Publication Date: 2009-10-21
河南未来铝业(集团)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The currently adopted method is lime precipitation method, but the cost of this method is high, which is not conducive to sustainable development
[0004] Calcium carbide is mainly used to prepare polyvinyl chloride, polyethylene and acetylene, but at the same time it will produce calcium carbide slag; red mud is the waste residue produced in the production process of alumina or aluminum hydroxide, and fly ash is mainly used in coal-fired thermal power plants Or waste discharged from thermal power plants, these industrial wastes only have about 20% of the waste to be reused, and most of them have not been used on a large scale. Most of the wastes are directly stacked in the open air after simple treatment. It will cause serious environmental pollution, endanger the growth of animals and plants, and even pollute water sources. How to make reasonable use of these industrial wastes has become a challenge today

Method used

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  • Method for jointly treating high-fluorine sewage by utilizing waste slag

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Embodiment 1: the method for utilizing waste slag to jointly treat high-fluorine sewage as described in the present invention comprises the following steps: adding 50 kg of calcium carbide slag and 50 kg of powder to a treatment tank containing 1 ton of high-fluorine sewage with a fluorine content of 3000 mg / L Coal ash and 50kg red mud were stirred and reacted for 10 minutes and sent to the overflow tank, where the reaction continued for 10 minutes, and the clear liquid in the overflow tank overflowed into the reaction tank; (2) Added Carbide slag, adjust PH=9, after 10 minutes of reaction, part of the clear liquid overflows into the coagulation tank; (3) Add 0.72kg of aluminum sulfate to the coagulation tank, adjust PH=6, and after 10 minutes of reaction, the clear liquid partly overflows Enter the coagulation aid tank; (4) Add 0.01kg polyacrylamide to the coagulation aid tank, filter and discharge after 10 minutes of reaction. After testing, the fluorine content in th...

Embodiment 2

[0018] Embodiment 2: the method for utilizing waste residues to jointly treat high-fluorine sewage as described in the present invention comprises the following steps: adding 70 kg of calcium carbide slag and 70 kg of powder to a treatment tank containing 1 ton of high-fluorine sewage with a fluorine content of 5000 mg / L Coal ash and 70kg red mud were stirred and reacted for 15 minutes and sent to the overflow tank, where the reaction was continued for 15 minutes, and the clear liquid in the overflow tank partially overflowed into the reaction tank; (2) adding Carbide slag, adjust PH=9.5, after 15 minutes of reaction, the clear liquid partly overflows into the coagulation tank; (3) add 0.8kg anhydrous aluminum chloride to the coagulation tank, adjust PH=7, after 15 minutes of reaction, the clear liquid Part of the overflow enters the coagulation aid pool; (4) Add 0.02kg cationic polyacrylamide to the coagulation aid pool, react for 15 minutes, and then filter and discharge. Af...

Embodiment 3

[0019] Embodiment 3: the method for utilizing waste slag to jointly treat high-fluorine sewage as described in the present invention comprises the following steps: adding 100 kg of calcium carbide slag and 100 kg of powder to a treatment tank containing 1 ton of high-fluorine sewage with a fluorine content of 8000 mg / L Coal ash and 100kg red mud were stirred and reacted for 20 minutes and sent to the overflow tank, where the reaction continued for 20 minutes, and the clear liquid in the overflow tank overflowed into the reaction tank; (2) Added Carbide slag, adjust PH=10, after 20 minutes of reaction, part of the clear liquid overflows into the coagulation tank; (3) add 1.2kg polyaluminum sulfate to the coagulation tank, adjust PH=7.5, and part of the clear liquid overflows after 20 minutes of reaction (4) Add 0.03kg of anionic polyacrylamide to the coagulation aid pool, react for 20 minutes, and then filter and discharge. After testing, the fluorine content in the filtered se...

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Abstract

The invention provides a method for jointly treating high-fluorine sewage by utilizing waste slag, which comprises the following steps: (1) carbide slag, pulverized fuel ash and red mud are added into a treatment pond containing the high-fluorine sewage and sent into an overflow pond after being stirred and reacting for 10-20 minutes, and clear liquid in the overflow pond flows into a reaction pond; (2) the carbide slag is added into the reaction pond, and the pH is regulated to 9-10; after 10-20 minutes of reaction, a coagulating agent is added to the clear liquid, and the pH is regulated to 6-7.5; after 10-20 minutes of reaction, a coagulant aid is added to the clear liquid; and after 10-20 minutes of reaction, the clear liquid is filtered and drained. The method uses the industrial waste slag for treating the high-fluorine sewage so as to ensure that the fluorine content in the treated sewage conforms to an environmental protection standard specified by the nation, thus the pollution of the high-fluorine sewage to the environment is greatly reduced. Meanwhile, the harm of the industrial slag to the environment is also reduced, thus the method has higher economic benefit and social benefit.

Description

technical field [0001] The invention belongs to sewage treatment technology, and relates to a method for jointly treating high-fluorine sewage by utilizing waste residues. Background technique [0002] Fluorine is a trace element. Drinking water with a fluorine content of 0.4-0.6 mg / L is beneficial to humans, but drinking high-fluorine water with a fluorine content greater than 1.5 mg / L for a long time will have adverse effects on the human body. Severe cases can cause dental fluorosis and bone disease; the discharge of high-concentration fluorine-containing industrial wastewater will cause great pollution to the environment, poison animals and plants, affect animal husbandry and agricultural production, and even cause serious harm to human health. Therefore, the treatment of fluoride-containing sewage is of great significance. At present, there are many methods for treating fluorine-containing wastewater at home and abroad, mainly including adsorption method, electrocoagul...

Claims

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Application Information

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IPC IPC(8): C02F1/58C02F9/04C02F1/52C02F101/14
Inventor 王志勇郎胜利史智慧廖学建段志强
Owner 河南未来铝业(集团)有限公司
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