Thermoplasticity environmentally-friendly stone paper and preparation method

An environmentally friendly stone paper, thermoplastic technology, applied in the direction of paper, papermaking, textiles and papermaking, etc., can solve problems such as the inability to meet the development of stone paper

Inactive Publication Date: 2010-10-27
CHENDU NEW KELI CHEM SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, only coupling filling of inorganic powder

Method used

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  • Thermoplasticity environmentally-friendly stone paper and preparation method
  • Thermoplasticity environmentally-friendly stone paper and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0033] Example 1

[0034] 1) Heat up the L-100 / 200 mixing mixer to a constant temperature of 80°C, add 85kg of bentonite with a particle size of 1250 mesh and 3kg of stearic acid into the mixer, and stir for 10 minutes at a stirring speed of 400rpm;

[0035] 2) Increase the stirring speed to 1500rpm, slowly and evenly add 2kg of styrene, and stir at a high speed for 10 minutes, so that the styrene monomer is evenly coated on the surface of the bentonite particles;

[0036] 3) Send the coated bentonite to a cold mixer, add 5kg of polypropylene, stir and cool to below 50°C, then add 0.05kg of azobisisobutyronitrile and mix well.

[0037] 4) Send the above mixture into a co-rotating twin-screw extruder (screw length-to-diameter ratio greater than 52:1) for extrusion and granulation, the screw speed of the host machine is 200rpm, and the temperature of each zone is controlled at: 1 zone 80°C; 2 zone 100°C ; 165°C in the third zone; 195°C in the fourth zone; 170°C in the fifth zon...

Example Embodiment

[0042] Example 2

[0043] 1) Heat up the W-100 / 200 mixing mixer to a constant temperature of 120°C, add 70kg of light calcium carbonate with a particle size of 2000 mesh, 10kg of titanium dioxide with a particle size of 2500 mesh, 1kg of isotridecyl phosphate, and 3kg of aluminate into the mixer. Stirring and reacting for 5 minutes at a stirring speed of 900rpm;

[0044] 2) Increase the stirring speed to 1200rpm, slowly and evenly add 2.5kg methyl methacrylate, and stir at a high speed for 10 minutes, so that the methyl methacrylate monomer is evenly coated on the surface of the bentonite particles;

[0045] 3) Send the coated powder to a cold mixer, add 8kg of high-density polyethylene and 2kg of ethylene-vinyl acetate copolymer, continue to stir and cool to below 50°C, add 0.01kg of dicumyl peroxide and mix well.

[0046] 4) Send the above mixture into a co-rotating twin-screw extruder for extrusion and granulation. The length-to-diameter ratio of the screw is greater than ...

Example Embodiment

[0051] Example 3

[0052] 1) Heat up the L-300 / 600 mixing mixer to a constant temperature of 100°C, mix 25kg wollastonite powder with a particle size of 1250 mesh, 60kg calcite powder with a particle size of 1250 mesh, 0.5kg titanate, 3kg zirconate, 0.5kg amino poly Alcohol ester (JL-G02 amino polyol ester, produced by Nanjing Jinlaiwang Co., Ltd.) was added to the mixer, and stirred and reacted for 8 minutes at a stirring speed of 500rpm;

[0053] 2) Increase the stirring speed to 1500rpm, slowly and evenly add 2.5kg of methyl acrylate, and stir at high speed for 10 minutes, so that the monomer is evenly coated on the surface of the particles;

[0054] 3) Send the coated particles to a cold mixer, add 4kg of polycaprolactone and 4kg of ethylene-acrylic acid copolymer, continue to stir and cool to below 50°C, add 0.01kg of dibenzoyl peroxide and mix well.

[0055] 4) Send the above mixture into a co-rotating twin-screw extruder for extrusion and granulation. The length-to-dia...

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Abstract

The invention discloses a thermoplasticity environmentally-friendly stone paper and a preparation method. The thermoplasticity environmentally-friendly stone paper comprises the following components in parts by weight: 80-90 parts of inorganic mineral powder, 3-5 parts of surface active ingredient, 2-3 parts of polymer monomer, 0.01-0.05 part of initiator and 5-15 parts of lubrication accessory ingredient, wherein the inorganic mineral powder is at least one of various inorganic mineral powders, such as wollastonite of which the grain diameter is 5-10 mu m, bentonite and the like; the surface active ingredient comprises at least one of anion surface active ingredient comprising inorganic acid ester; and the polymer monomer is one of methyl methacrylate, methyl acrylate, butyl acrylate and styrene. The thermoplasticity environmentally-friendly stone paper contains 90% of inorganic mineral powder, has favoarble thermoplasticity processing performance and can use the thermoplasticity processing equipment to carry out quick blow molding or calendaring and drawing shaping; and paper has obvious vertical and horizontal orientation, good deflection and strong rigidity, and appearance texture more approaches the traditional paper. The thermoplasticity environmentally-friendly stone paper is a novel environmentally-friendly paper.

Description

technical field [0001] The invention relates to an environmentally friendly paper with inorganic powder as the main component, commonly known as "stone paper" and a corresponding preparation method, more specifically, an environmentally friendly stone paper with thermoplastic processability and a preparation method. Background technique [0002] "Stone paper" is called "stone paper" because it contains inorganic powder components. It is a new type of paper derived from synthetic paper. It uses polymer resin as the main material and calcium carbonate as an auxiliary material. The synthetic paper is prepared by calendering processing equipment. Since the raw material of synthetic paper is mainly resin, the content of calcium carbonate powder is less than 40%, so not only the cost is high, but also depends on petroleum, and its application and development have been affected by petroleum. In recent years, this type of technology has made new breakthroughs in technological means,...

Claims

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Application Information

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IPC IPC(8): D21H17/68D21H17/53D21H17/35
Inventor 陈庆曾军堂刘宏
Owner CHENDU NEW KELI CHEM SCI CO LTD
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