A kind of micro-nano reinforced plastic wood composite material board and preparation method thereof

A composite material, micro-nano technology, applied in the field of plastic-wood composite materials, can solve the problems of low natural fiber reinforcement effect, large polarity difference, poor interface compatibility, etc., to achieve convenient production and manufacturing, reduce the amount of plastic, The effect of low production cost

Active Publication Date: 2011-12-14
江苏福瑞森塑木科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since plant fibers, one of the main raw materials for preparing wood-plastic composite materials, are mainly composed of cellulose, hemicellulose and lignin, which contain a large number of polar groups such as alcoholic hydroxyl groups, oxygen and phenolic hydroxyl groups, the preparation of wood-plastic composite materials The surface of thermoplastic polyolefin, another main raw material of the material, is non-polar (low) polar, so the polarity of the two is very different, and the hydroxyl groups in the plant fibers can form intermolecular hydrogen bonds and entangle with each other, making it uneven The above two factors often lead to poor interfacial compatibility between fibers and plastics, coupled with the low reinforcing effect of natural fibers themselves, resulting in some obvious deficiencies in wood-plastic composite products, such as static The bending strength is low, the bearing capacity is poor, and bending may occur after long-term use. Especially when it is used in the air, bending deformation is more likely to occur, which affects its use effect, shortens its service life, and limits its use range.

Method used

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  • A kind of micro-nano reinforced plastic wood composite material board and preparation method thereof
  • A kind of micro-nano reinforced plastic wood composite material board and preparation method thereof
  • A kind of micro-nano reinforced plastic wood composite material board and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0029]

[0030] (1) Weigh 1 part of vinyltriethoxysilane, mix vinyltriethoxysilane and water uniformly at a weight ratio of 1:80, wherein water is the solvent, and adjust the pH value of the aqueous solution to 4.5.

[0031] (2) Weigh the wood flour according to the weight ratio of wood flour and vinyltriethoxysilane 100:2, add it to the aqueous solution of vinyltriethoxysilane, mix well, seal and pressurize, the pressure is 2MPa, and react After 4 hours, the pressure was released, the wood powder was taken out, and washed repeatedly with tap water until the wood powder was neutral and dried to obtain micro-nano modified wood powder;

[0032] (3), take each raw material by the weight proportion amount of formula;

[0033] (4), plastic particles, maleic anhydride grafted plastic particles, calcium carbonate powder, and stearic acid were placed in a mechanical stirring tank and stirred for 2 minutes, extruded and granulated, the barrel temperature of the extruder was 180°C, a...

Embodiment 2

[0038]

[0039] (1) Weigh 1 part of vinyltriethoxysilane, mix vinyltriethoxysilane and water uniformly at a weight ratio of 1:60, wherein water is the solvent, and adjust the pH value of the aqueous solution to 4.

[0040] (2) Weigh the wood flour according to the weight ratio of wood flour and vinyltriethoxysilane 100:1, add it to the aqueous solution of vinyltriethoxysilane, mix well, seal and pressurize, the pressure is 1MPa, and react After 3 hours, the pressure was released, the wood powder was taken out, and washed repeatedly with tap water until the wood powder was neutral and dried to obtain micro-nano modified wood powder;

[0041] (3), take each raw material by the weight proportion amount of formula;

[0042] (4), plastic particles, maleic anhydride grafted plastic particles, calcium carbonate powder, and stearic acid are placed in a mechanical stirring tank and stirred for 1 minute, extruded and granulated, the barrel temperature of the extruder is 160 ° C, and ...

Embodiment 3

[0047]

[0048](1) Weigh 1 part of vinyltriethoxysilane, mix vinyltriethoxysilane and water uniformly at a weight ratio of 1:100, wherein water is the solvent, and adjust the pH value of the aqueous solution to 5.

[0049] (2) Weigh the wood flour according to the weight ratio of wood flour and vinyltriethoxysilane 100:3, add it to the aqueous solution of vinyltriethoxysilane, mix well, seal and pressurize, the pressure is 3MPa, and react After 5 hours, the pressure was released, the wood powder was taken out, and washed repeatedly with tap water until the wood powder was neutral and dried to obtain micro-nano modified wood powder;

[0050] (3), take each raw material by the weight proportion amount of formula;

[0051] (4), plastic particles, maleic anhydride grafted plastic particles, calcium carbonate powder, and stearic acid were placed in a mechanical stirring tank and stirred for 3 minutes, extruded and granulated, the barrel temperature of the extruder was 200°C, and...

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Abstract

The invention relates to a wood plastic material, in particular to a micro nanometer-enhanced wood plastic composite board and a preparation method thereof. The preparation method comprises the following steps of: hydrolyzing ethenyl triethoxy silane, and modifying wood powder by sealing pressurization reaction; mixing plastic granules, maleic anhydride grafting plastic granules, calcium carbonate powder and stearic acid, and extruding to obtain modified plastic granules; blending the modified plastic granules, the modifying wood powder, talcpowder, terpene resin and an antioxidant and granulating to obtain micro nanometer-enhanced wood plastic granules; and extruding the micro nanometer-enhanced wood plastic granules to form the micro nanometer-enhanced wood plastic board. The micro nanometer-enhanced wood plastic board can be recycled, is low in cost, has high mechanical properties and is an ideal material for replacing wood; and compared with the conventional wood material, the micro nanometer-enhanced wood plastic composite board has a longer service life, is a novel upgrading and updating product of the conventional wood plastic material, and can be widely applied in fields of traffic, buildings, decoration, municipal administration, gardens, packaging and the like.

Description

technical field [0001] The invention relates to a plastic-wood composite material, in particular to a micro-nano reinforced plastic-wood composite material plate and a preparation method thereof. Background technique [0002] In recent years, with the enhancement of people's awareness of environmental protection, wood-plastic composite materials with a wide range of raw materials, environmentally friendly, renewable and recyclable materials have attracted more and more attention. Wood-plastic composite materials are prepared by compounding polymers (mostly thermoplastic polyolefins) and plant fibers (mostly wood powder). This material has the excellent properties of both plastics and wood, no cracking, no deformation, and corrosion resistance , strong plasticity, can realize personalized modeling very simply, high environmental protection, no pollution, no pollution, the product does not contain benzene, formaldehyde and other substances, and can be recycled, etc. It is a ne...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L97/02C08L23/06C08L23/12C08L25/06C08L45/00C08L51/06C08L51/00C08K13/02C08K3/26C08K3/34C08K5/134C08K5/13
Inventor 周华强景露雷文
Owner 江苏福瑞森塑木科技股份有限公司
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