Novel chinlon cord thread oil agent and preparation method thereof

A technology for nylon cords and cords, which is applied in fiber types, textiles and papermaking, and fiber treatment, and can solve problems such as poor adhesion between cord fabrics and tires, poor compatibility between oil and latex, and low degree of tarring. Achieve excellent adhesion performance, improve soft performance, and low waste silk rate

Active Publication Date: 2012-06-20
ZHEJIANG HUANGMA TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] There are two types of existing oil compositions, one is ester type, most of which are based on natural esters, such as US4293460, which mainly consists of natural oils, polyoxyethylene alkylphenols, phosphates, etc., and its characteristics It has strong adhesion with rubber, low strength loss after twisting and weaving of raw silk, but poor spinnability and high degree of tarring; the other is polyether type oil composition, such as CN242451A, from 60 to 90% of ethylene oxide and propylene oxide copolyether, the rest of antistatic agent and defoamer, etc., among which polyether is unmodified ordinary polyether, which is characterized by good spinnability and smoke L

Method used

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  • Novel chinlon cord thread oil agent and preparation method thereof
  • Novel chinlon cord thread oil agent and preparation method thereof
  • Novel chinlon cord thread oil agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A kind of novel nylon cord finish of the present embodiment, described cord finish composition is made up of the following components by weight percentage:

[0044] (a) Triolein 18;

[0045] (b) methyl-terminated butanol-based EO / PO random addition polyether (EO / PO=25 / 75% (weight), V=2000) 42;

[0046] (c) lauryl alcohol-based EO / PO block addition polyether (EO / PO=50 / 50% (weight), MV=5000) 25;

[0047] (d) Sodium Cocoyl Monoethanolamide Sulfate 6;

[0048] (e) dodecylamine 8EO 3; castor oil polyoxyethylene ether (20EO) 5;

[0049] (f) Simethicone 0.8,

[0050] Ethanol 0.3.

[0051] The preparation method of a kind of novel nylon cord oil agent of the present embodiment comprises the following steps: pumping the above-mentioned component (c), component (d) and component (e) into the reactor, start stirring, and heat up to 50 ~60°C, stir evenly, then pump component (a) and component (b) into the reaction kettle, keep the temperature at around 50°C, stir for 40min, fi...

Embodiment 2

[0054] A kind of novel nylon cord finish of the present embodiment, described cord finish composition is made up of the following components by weight percentage:

[0055] (a) pentaerythritol tetralaurate 19;

[0056] (b) methyl-terminated lauryl alcohol EO / PO random addition polyether (EO / PO=40 / 60% (weight), MV=2500) 35;

[0057] (c) Octanol-based EO / PO block addition polyether (EO / PO=50 / 50% (weight), MV=8000) 15, butanol-based EO / PO random addition polyether (EO / PO =40 / 60% (weight), MV=10000) 15;

[0058] (d) Sodium Lauric Monoethanolamide Sulfosuccinate 4.5;

[0059] (e) octadecylamine 10EO 2,

[0060] S-80 3,

[0061] Isomerized tridecyl alcohol polyoxyethylene ether (8EO) 5;

[0062] (f) Simethicone 1.0,

[0063] Oleic acid 0.5.

[0064] The preparation method of a kind of novel nylon cord oil agent of the present embodiment comprises the following steps: pumping the above-mentioned component (c), component (d) and component (e) into the reactor, start stirring, an...

Embodiment 3

[0067] A kind of novel nylon cord finish of the present embodiment, described cord finish composition is made up of the following components by weight percentage:

[0068] (a) trimethylolpropane triisostearate 20;

[0069] (b) Butyl-terminated lauryl alcohol-based EO / PO random addition polyether (EO / PO=50 / 50% (weight), M V =5000) 20,

[0070] Methyl-terminated octanol block addition polyether (EO / PO=60 / 40% (weight), MV=2500) 25;

[0071] (c) cetyl alcohol EO / PO random addition polyether (EO / PO=50 / 50% (weight), MV=5000) 10,

[0072] Butanol-based EO / PO random addition polyether (EO / PO=35 / 65% (weight), MV=12000) 10;

[0073] (d) Isostearic acid monoethanolamide potassium sulfate 2, caprylic acid monoethanolamide sodium sulfate 2.5;

[0074] (e) octadecylamine 10EO 2,

[0075] S-80 3,

[0076] Isomerized tridecyl alcohol polyoxyethylene ether (8EO) 5;

[0077] (f) grafted silicone oil 0.5,

[0078] Oleic acid 0.5,

[0079] Ethanol 0.5.

[0080] The preparation metho...

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Abstract

The invention discloses a novel chinlon cord thread oil agent and a preparation method thereof. A cord thread oil agent composition consists of the following ingredients in percentage by weight: (a) 5 to 50 percent of synthetic ester, (b) 10 to 70 percent of modified end sealing polyether, (c) 5 to 40 percent of polyether, (d) 1 to 15 percent of anti-static agents, (e) 5 to 15 percent of emulsifying agents and (f) 1 to 3 percent of additives. When products prepared according to the invention are used, the anti-static effect is good, the spinnability after the use is good, the strength loss after the original silk twisting weaving is small, and in addition, the compatibility of the oil agent and latex is good. The oil agent has stable performance, is convenient to use and has good compatibility with water. In addition, in the false twisting process, the tension is automatically regulated to the reasonable surface tension, and the tar formation can be inhibited, so the stable operation can be prolonged in the false processing step. The smoothness and the heat resistance performance are excellent, the process requirements of chinlon cord thread spinning can be met, and in addition, the biodegradability is good.

Description

technical field [0001] The invention relates to a novel nylon cord oil agent and a manufacturing method thereof, belonging to the technical field of auxiliary agent manufacturing in synthetic fiber processing technology. Background technique [0002] Tire cord is the reinforcing material of tires. In the past, viscose fiber was mainly used as raw material. With the development of synthetic fibers, nylon, polyester, aramid, etc. are also used. Nylon cord is widely used due to its excellent heat resistance, impact resistance and fatigue resistance. Since the 1980s, my country has introduced several sets of high-speed spinning cord production equipment, and the corresponding oil agents are all dependent on imports. The price of these oil agents is relatively expensive, and it takes a lot of foreign exchange every year. In recent years, some domestic manufacturers have successively developed some nylon cord oil agents. However, due to problems in research and development techn...

Claims

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Application Information

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IPC IPC(8): D06M15/53D06M13/224D06M101/34
Inventor 俞芳金一丰王新荣张晨辉
Owner ZHEJIANG HUANGMA TECH
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