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Method for extracting algae iodine by using aluminum ion secondary sedimentation and produced algae iodine salt using same

A technology of seaweed iodized salt and seaweed iodine, applied in chemical instruments and methods, food science, inorganic chemistry, etc., can solve the problems of large loss of organic iodine, large residual amount, difficult removal of heavy metals, etc., and achieves high removal rate and technological process. simple effect

Active Publication Date: 2012-11-28
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The alcohol precipitation method is to hydrolyze the iodine-containing seaweed with water and alkali, settle with ethanol, and then evaporate the supernatant ethanol to concentrate and extract, but the alcohol precipitation method obtains a mixture of iodine-containing polysaccharides containing various seaweed components, and the extraction process flow Complicated, the loss of organic iodine is large, and the yield is low. The extracted seaweed iodine contains a large amount of seaweed polysaccharides soluble in water and ethanol, and the heavy metals in seaweed are not easy to remove in the seaweed iodine extract, and the residual amount is large.
Although the calcium ion precipitation method has basically solved the problem of heavy metal residues, glycerol is used as a protective agent and one-time sedimentation, and the content of glycerol and other seaweed components in the obtained seaweed iodine is relatively high, and the purity of seaweed iodine remains to be determined. improve

Method used

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  • Method for extracting algae iodine by using aluminum ion secondary sedimentation and produced algae iodine salt using same
  • Method for extracting algae iodine by using aluminum ion secondary sedimentation and produced algae iodine salt using same
  • Method for extracting algae iodine by using aluminum ion secondary sedimentation and produced algae iodine salt using same

Examples

Experimental program
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Effect test

Embodiment 1

[0031] Take 1 kg of kelp, break it to about 20 cm, add 10 kg of water to soak, and add sodium carbonate to make it alkaline, extract at 50 ° C for 6 hours to obtain the filtrate, add 20% AlCl dropwise to the filtrate 3 The aqueous solution was settled, and then 20% Na was added 2 CO 3 The aqueous solution is settled for the second time to obtain a clear liquid, concentrated, and then centrifuged to remove the residue and salt crystals of the concentrated liquid, adjust the iodine content of the concentrated liquid, neutralize, and obtain a sprayable iodized seaweed iodine solution with an iodine content of 4%. agent.

[0032] Utilize the spray equipment in the production line to spray the seaweed iodine concentrate of 4% (mass percentage) prepared by the above method in the iodine-free salt evenly in the weight ratio of 1000: 0.75 in the processing process, stir, and then pack into 200g, Small packages of 400g, 500g, 1000g.

Embodiment 2

[0034] Take 1kg of wakame, break it to about 20cm, add 10kg of water to soak, and add sodium carbonate to make it alkaline, extract at 55°C for 12 hours, filter to obtain the filtrate, and add an appropriate amount of 15% AlCl dropwise to the filtrate 3 The aqueous solution settles, then add 10% Na 2 CO 3 The aqueous solution is settled for the second time, and the clear liquid is concentrated by centrifugation, then the sediment and salt crystals are removed, neutralized, the concentrated liquid is added to the seaweed polysaccharide, stirred, dried and dehydrated, granulated to obtain the finished seaweed iodine crystal, and packaged.

[0035] Fully mix 100kg of iodine-free salt with seaweed iodine crystals with an iodine content of 3%, so that the iodine content of the mixture reaches 0.0234% (weight ratio) to obtain iodine-containing mother salt, and then mix the mother salt with 500kg of iodine-free salt in a cone mixer Mix well, and then sub-package into 200g, 400g, 500...

Embodiment 3

[0037] Take 1 kg of leaf algae, break it to about 20 cm, add 10 kg of water to soak, and add sodium carbonate to make it alkaline, extract at 50 ° C for 12 hours, filter to obtain the filtrate, and add an appropriate amount of 3% AlCl to the filtrate dropwise 3 The aqueous solution settles, then add 5% Na 2 CO 3 The aqueous solution is settled for the second time, and the clear liquid is concentrated by centrifugation, then the sediment and salt crystals are removed, neutralized, the concentrated liquid is added to the seaweed polysaccharide, stirred, dried and dehydrated, granulated to obtain the finished seaweed iodine crystal, and packaged.

[0038] Fully mix 100kg of iodine-free salt with seaweed iodine crystals with an iodine content of 1%, so that the iodine content of the mixture reaches 0.0084% (weight ratio) to obtain iodine-containing mother salt, and then mix the mother salt with 500kg of iodine-free salt in a cone mixer Mix well, and then sub-package into 200g, 40...

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Abstract

The invention relates to a method for extracting algae iodine by using aluminum ion secondary sedimentation and produced algae iodine salt using same, which comprises the following steps: 1) taking a raw material and directly crushing, adding water of which the weight is equivalent to 10 times of that of the raw material, adding sodium carbonate of which the weight is equivalent to 1%-5% of weight of the raw material in a mixture, mixing and extracting for 6-18 hours under the temperature of 45-55 DEG C, and filtering to obtain a filtrate; 2) adding an aluminum compound aqueous solution in the filtrate drop by drop until mass precipitates are generated, filtering and centrifuging to obtain a supernatant; 3) adding a sodium carbonate aqueous solution in the supernatant, generating flocculent precipitates on the supernatant, and centrifuging and removing the precipitates; and 4) concentrating the extracted supernatant without generation of flocculent precipitates, and preparing to obtain the algae iodine concentrate. According to the invention, the heavy metals and most alga polysaccharides in the algae iodine products can be effectively removed by the method, the purity and the recovery rate can be substantially increased, the technology is simple, the cost is low, the standard algae iodine can be produced with large scale, and the prepared algae iodine concentrate can be used for preparing algae iodine crystal and algae iodine salt.

Description

technical field [0001] The invention belongs to the field of food processing, in particular to a method for extracting iodine-containing products and preparing seaweed iodized salt. Background technique [0002] Iodine is an essential trace element for the body. It is an indispensable component for the synthesis of thyroid hormones. Insufficient iodine in food can reduce thyroid secretion and reduce body metabolism, leading to goiter, endemic goiter and endemic cretinism. It can also cause growth retardation, mental retardation or dementia in children. All the effects on human development due to iodine deficiency are called "iodine deficiency diseases". Pregnant women, lactating mothers, and children are especially indispensable for iodine deficiency. [0003] Iodine is usually in a state of dynamic balance in the human body, and excess iodine will be excreted with urine. At present, the main way of supplementing iodine is potassium iodate, which is a kind of chemically sy...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B7/16A23L1/237A23L1/304A23L27/40
Inventor 杨革生
Owner DONGHUA UNIV
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