Method for electrochemically preparing thermoelectric film by using seeding layer

A thermoelectric thin film and electrochemical technology, applied in the field of electrochemical preparation of thermoelectric thin films on the seed layer, can solve problems such as poor bonding, and achieve the effects of high deposition rate, low growth temperature, and low cost

Inactive Publication Date: 2013-01-09
SHANGHAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This can overcome the disadvantages of poor bonding between the traditional che...

Method used

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  • Method for electrochemically preparing thermoelectric film by using seeding layer
  • Method for electrochemically preparing thermoelectric film by using seeding layer
  • Method for electrochemically preparing thermoelectric film by using seeding layer

Examples

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Embodiment 1

[0023] Embodiment one: Constant current deposition seed layer on the glass sheet, then constant potential growth Bi 2 Te 3

[0024] Cleaning of glass slides: First, clean manually with cotton dipped in detergent, then ultrasonically clean with water containing detergent for 10 minutes, then ultrasonically clean with ultrapure water for 5 minutes to remove residual detergent, then ultrasonically clean with acetone and absolute ethanol for 10 minutes minute. Dry it with high-purity N2 and put it into the sample box for later use.

[0025] Use constant current deposition as the preparation of the seed layer, the specific parameters are: current density 1mA / cm 2 , the deposition time is 2 minutes, and the thickness of the obtained seed layer is about 100m.

[0026] The solution used for electrochemical growth was Bi(NO 3 ) 3· 5H 2O, at a concentration of 0.008 M / L; TeO 2 , the concentration is 0.01 M / L; HNO 3 The concentration is 1M / L. The deposition potential ...

Embodiment 2

[0027] Embodiment two: silicon substrate magnetron sputtering seed layer, then constant potential growth Bi 2 Te 3

[0028] Cleaning of silicon substrate: use RCA chemical cleaning process to clean, the specific steps are: first in liquid A (H 2 O:H 2 o 2 :NH 3 h 2 O=5:1:1) in an 80°C water bath for 10 minutes, then in solution B (HCl:H 2 0 2 :H 2 0=1:1:6) in 80°C water bath for 10min, then in liquid C BOE (HF:NH 4 Soak in F=1:6) for 5 minutes, and finally rinse with a large amount of deionized water, ultra-pure N 2 Blow dry and store in sample box.

[0029] The specific parameters for the preparation of the seed layer by magnetron sputtering are: the co-sputtering method of Bi target and Te target is used, and the background vacuum is less than 2*10 -6 torr, the sputtering working gas is high-purity argon with a purity of 99.999%, the working pressure of argon is 1.5mTorr, the sputtering power of the Bi target is 15 w, the sputtering power of the Te target...

Embodiment 3

[0031] Example 3: Molecular beam epitaxy deposits a seed layer on a glass sheet, and then grows Bi at a constant potential 2 Te 3

[0032] Cleaning of glass slides: First, clean manually with cotton dipped in detergent, then ultrasonically clean with water containing detergent for 10 minutes, then ultrasonically clean with ultrapure water for 5 minutes to remove residual detergent, then ultrasonically clean with acetone and absolute ethanol for 10 minutes minute. With high purity N 2 Blow dry and put into the sample box for later use.

[0033] The seed layer is grown by molecular beam epitaxy, and the specific parameters are: the degree of vacuum is 3*10 -7 pa, the temperature of the glass sheet is 200°C, the temperature of the Bi beam source furnace is 490°C, the temperature of the Te beam source furnace is 280°C, the epitaxy time is 20 minutes, and the obtained film thickness is 30nm.

[0034] Electrochemical growth, the selected solution is Bi(NO 3 ) 3· 5H 2...

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Abstract

The invention belongs to the field of electrochemical preparation of a thermoelectric material, and relates to a method for electrochemically preparing a thermoelectric film by using a seeding layer, which comprises the following steps: preparing a seeding layer having a nano-level thickness on a substrate through molecular beam epitaxy, magnetron sputtering and other modes; and electrochemically growing a thermoelectric film material, wherein the thickness of the film can be of the nano level. By using the method, the growth orientation of the epitaxial film can be controlled, and a thermoelectric film having an obviously column structure orientation is prepared, so that the thermoelectric properties of the electrochemically grown film can be improved. Due to the self characteristics of electrochemistry such as low cost and convenient growing process, a material preparation foundation is provided for the assembly of a thermoelectric device in future.

Description

technical field [0001] The invention relates to a method for electrochemically preparing a thermoelectric thin film from a seed layer, and belongs to the technical field of electrochemically preparing thin films. Background technique [0002] Electrochemical deposition technology means that in an electrolytic cell, there is a working electrode (cathode), on which the required materials are deposited, such as traditional metals and current semiconductor materials. The entire deposition process is carried out in an electrolyte where redox reactions occur. Coupled with the counter electrode (anode) and reference electrode, the current and potential between the two electrodes can be precisely controlled to achieve the purpose of deposition on the substrate. The basic principle of electrochemical deposition is the theory of nucleation and crystal growth, that is, the ions in the solution are first reduced, nucleated on the surface of the substrate, and then crystallized along a ...

Claims

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Application Information

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IPC IPC(8): H01L35/34
Inventor 胡志宇严晓霞曹毅刘艳玲沈超张向鹏
Owner SHANGHAI UNIV
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