Surface sizing enhancer

A technology of surface sizing and reinforcing agent, which is applied in the direction of water-repellent addition, etc., can solve problems such as easy to be emulsified, poor water-resistance performance, and prolongation of curing period, so as to achieve the improvement of wet strength fracture performance index and water-resistance performance Improve and solve the effect of moisture return deformation

Inactive Publication Date: 2013-05-15
天津市奥东化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Usually, the surface sizing agent is composed of a variety of active monomers with different functions. The polymer formed by the copolymerization of the surface sizing agent is the current mainstream product of the surface sizing agent. This kind of surface sizing agent can be mainly divided into three types: 1. Water-soluble polymer surface sizing agent, 2. Polymer water-dispersible surface sizing agent, 3. Styrene and butyl acrylate as main monomers, using different degrees of hydrolysis to use fluorine-containing monomers as auxiliary materials Strengthening agent, and compounded with silicon solution of different degrees of hydrolysis and polyvinyl alcohol to form a surface sizing enhancer. In contrast, although this type of surface sizing agent and sizing enhancer can improve the sizing degree of paper, Stiffness, smoothness and printing adaptability, etc., and the storage stability and sizing performance are also good, but its chemical stability is low, and it is easy to be emulsified under the action of organic solutions. In addition, when mixed with each other, there will be miscibility defects. If the overall viscosity of the paper machine becomes higher, it will affect the normal operation of the paper machine
To sum up, at present, the biggest defect of sizing agents at home and abroad is that they cannot solve the problem of gradual deformation of the paper and are easily affected by external factors during the sizing process, prolonging the curing period, and deteriorating water resistance. A problem that the industry has been waiting to solve for a long time

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A surface sizing enhancer comprising the following ingredients, in Kg by weight

[0017] Ferrous sulfate 930Kg, polyoxyethylene 0.8Kg, polyacrylamide 0.6Kg, sodium polyacrylate 0.6Kg, acryloyloxyethyltrimethylammonium chloride 6Kg, N-methylolacrylamide 8Kg, ammonium persulfate 6Kg.

[0018] The preparation method of the above-mentioned surface sizing enhancer, at room temperature, add ferrous sulfate 930Kg, polyoxyethylene 0.8Kg, polyacrylamide 0.6Kg, polyacrylic acid sodium 0.6Kg, acryloyloxyethyl trimethyl chloride Ammonium 6Kg, N-methylolacrylamide 8Kg, ammonium persulfate 6Kg, stir for 10 minutes to fully dissolve and mix evenly, and react for 0.5h under mechanical stirring to obtain a multi-component polycation cross-linked network polymer paste water liquid.

Embodiment 2

[0020] A surface sizing enhancer comprising the following ingredients, in Kg by weight

[0021] Ferrous sulfate 950Kg, polyoxyethylene 6Kg, polyethylene glycol 3Kg and polyacrylamide 3Kg, methacryloyl ethyl dimethyl benzyl ammonium chloride 12Kg, ethoxymethacrylamide 10Kg, 6 methylene tetra Amine 6Kg, sodium persulfate 12Kg.

[0022] Prepared according to the method of Example 1.

Embodiment 3

[0024] A surface sizing enhancer comprising the following ingredients, in Kg by weight

[0025] Ferrous sulfate 935Kg, sodium polyacrylate 2Kg, polyurethane 2Kg, polyvinyl alcohol 2Kg, polyoxyethylene 2Kg, acryloyloxyethyltrimethylammonium chloride 5Kg, acryloyloxypropyltrimethylammonium chloride 5Kg, hydroxyl Ethylacrylamide 5Kg, ethoxymethacrylamide 5Kg, ammonium persulfate 8Kg.

[0026] Prepared according to the method of Example 1.

[0027] The embodiment can replace part of the starch surface sizing enhancer, and use domestic waste paper 100% to make 120 g / m 2 The amount of starch used in surface sizing of corrugated base paper is 60 kg / ton of paper, which can replace part of the reinforcing agent for starch surface sizing of 20 kg / ton of paper, and the Cobb value of corrugated base paper after testing is 28 g / m 2 The ring pressure index is 8.2 Nm 2 / g, the cobb value of sizing inter-flute base paper after 5 days is 27 g / m 2 The ring pressure index is 8.1 Nm 2 / gram...

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PUM

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Abstract

The invention relates to a surface sizing enhancer which is characterized by comprising the following components in parts by weight: 930-950 parts of ferrous sulfate, 2-12 parts of a combined polymer, 6-12 parts of a cationic monomer, 8-16 parts of a crosslinking agent and 6-12 parts of an initiator. The surface sizing enhancer has the beneficial effects that the surface sizing enhancer can replace partial pasty starch and can comprehensively improve the quality of paper; according to requirements of different pieces of paper, by a pasting process, 15-30 percent of starch can be replaced; compared with the conventional surface sizing enhancer, the surface sizing enhancer has the advantages that the water resistance is greatly improved; and furthermore, the annular pressure of the paper, the breakage resistance and the humidity breakage property are obviously improved. Various macromolecule copolymers are used as ligand polymers and are mixed and crosslinked with the original starch to form a whole; and during surface sizing, coating can be effectively prevented from inwards penetrating into the paper, off-machine curing is performed without influence of the environment, and a phenomenon that the paper is wetted and deforms can be well solved.

Description

technical field [0001] The invention belongs to chemical auxiliary agents for papermaking, in particular to a surface sizing enhancer. Background technique [0002] With the rapid development of my country's paper industry, the recycling of old paper has become the main source of pulp in my country. This can solve the shortage of paper pulp and overcome the harm caused by the serious pollution of straw pulp. However, the recycled old paper cellulose becomes short, which has a greater impact on paper quality. In order to solve paper cellulose defects, people add multifunctional chemical additives in sizing, its function is to reduce the water absorption and ink absorption of the paper, enhance the ring pressure, stiffness, improve the smoothness of the paper and reduce the printing adaptability Lint and powder fall off, while maintaining the dimensional stability of the paper sheet and preventing shrinkage, thereby improving the quality of paper products. In the sizing pro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H21/16C08F291/00C08F291/12
Inventor 田成杰李端
Owner 天津市奥东化工有限公司
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