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Hollow internal-pressing fiber film and preparation method thereof

A fiber and internal pressure technology, which is applied in the field of hollow fiber internal pressure membrane and its preparation, can solve the problems of limited maintenance and cleaning methods, inapplicability of hollow fiber membrane, and small pore size of hollow fiber membrane, so as to reduce deep pollution and improve affinity Water-based, viscosity-increasing effect

Active Publication Date: 2014-01-08
TIANJIN MOTIMO MEMBRANE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the relatively large volume of bacteria (such as yeast, etc.) and pulp cells, the existing conventional hollow fiber ultra / microfiltration membranes cannot be fully applied, and generally have small pore diameters (resulting in low filtration efficiency) and high tortuous pore structures. The problems that lead to low equipment operation efficiency and limited maintenance and cleaning methods are not suitable for use in high-concentration and high-viscosity environments
[0003] Polyethersulfone resin (PES) is a thermoplastic polymer material with excellent comprehensive properties developed by the British ICI company in 1972. The molecule has the rigidity of the benzene ring, the flexibility of the ether group, and the formation of the sulfone group and the entire structural unit. Large conjugated system, so the whole molecule has considerable stability, good chemical and biological corrosion resistance, outstanding hydrolysis resistance stability and radiation resistance, etc., but the pore size of the PES hollow fiber membrane is generally small, and the hollow fiber membrane produced It is not suitable for the separation of high-concentration and high-viscosity liquids such as the recovery of bacteria (such as yeast, etc.) and the concentration of fruit juice.

Method used

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  • Hollow internal-pressing fiber film and preparation method thereof
  • Hollow internal-pressing fiber film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] By weight percentage, 5% polyethersulfone resin, 5% molecular weight is 10 6 Add Dalton's polyacrylonitrile resin, 3% lithium chloride, 3% polyvinylpyrrolidone and 5% ethylene glycol to 79% dimethylacetamide (DMAc), stir and dissolve at 80°C , mix evenly, and remove the air bubbles to obtain the casting solution.

[0027] The above casting solution is extruded through the spinneret and enters the coagulation bath. After gelling for a certain period of time, the as-spun polyethersulfone hollow fiber with a through-hole structure and uniform large-diameter internal pressure film is obtained. Among them, the outer coagulation bath is a dimethylacetamide (DMAc) aqueous solution with a water concentration of 70% at 50°C, and the inner coagulation bath is pure water.

[0028] figure 1 It is the topography diagram of the cross-section of the obtained hollow fiber membrane. In the figure, the magnification = 170X, the field of view width = 7mm, the test voltage = 2.00KV, the...

Embodiment 2

[0030] By weight percentage, with 8% polyethersulfone resin, 3% molecular weight is 10 5 Dalton's polyacrylonitrile resin, 5% calcium chloride, 1% polyoxyethylene and 3% ethylene glycol were added to 80% dimethyl sulfoxide (DMSO), stirred and dissolved at 50°C, After mixing evenly and removing air bubbles, the casting solution is obtained.

[0031] The above-mentioned casting solution is extruded through the spinneret and enters the coagulation bath. After gelling for a certain period of time, the as-spun polyethersulfone hollow fiber with a through-hole structure and uniform large-aperture internal pressure film is obtained. The outer coagulation bath is 30°C , The concentration of water is 80% dimethylformamide (DMF) aqueous solution, and the inner coagulation bath is pure water.

Embodiment 3

[0033] By weight percentage, with 12% polyethersulfone resin, 1% molecular weight is 10 5 Polyacrylonitrile, 1% lithium nitrate, 2% polyvinylpyrrolidone mixed with 1% polyvinyl alcohol and 5% diethylene glycol were added to 78% dimethylformamide (DMF), in Stir and dissolve at 60°C, mix evenly, and remove air bubbles to obtain a casting solution.

[0034] The above-mentioned casting solution is extruded through the spinneret and enters the coagulation bath. After gelling for a certain period of time, the as-spun polyethersulfone hollow fiber with a through-hole structure and uniform large-aperture internal pressure film is obtained. The outer coagulation bath is 70°C , The concentration of water is 90% N-methylpyrrolidone (NMP) aqueous solution, and the internal coagulation bath is pure water.

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Abstract

The invention discloses a hollow internal-pressing fiber film and a preparation method thereof, and provides a hollow internal-pressing fiber film with uniform large hole diameter and a through hole structure and a preparation method of the hollow internal-pressing fiber film. The preparation method includes stirring 5-15% of polyether sulfone resin, 1-5% of ultra-high molecular weight polyacrylonitrile resin, 75-80% of solvent, 1-5% of micromolecule additives, 1-5% of polymeric additives and liquid pore-forming agents at the temperature of 50-80 DEG C for dissolution, evenly mixing, and obtaining film casting liquor after removing of bubbles; extruding the film casting liquor by a spinneret plate, subjecting the film casting liquor to a coagulating bath at the temperature of 10-70 DEG C, and obtaining raw silks of the hollow internal-pressing fiber film after completion of gelling. Through determination of polyether sulfone resin / polyacrylonitrile resin blending ratio, solid content, additive types and concentration, the polyether sulfone hollow internal-pressing fiber film with the through hole structure and the uniform large hole diameter can be obtained.

Description

technical field [0001] The invention relates to the technical field of membranes, in particular to a hollow fiber internal pressure membrane and a preparation method thereof. Background technique [0002] With the development of separation technology, membrane technology has begun to be used in high-concentration and high-viscosity liquid separation fields such as recovery of bacteria (such as yeast, etc.), fruit juice concentration, etc., especially hollow fiber membrane technology. With the characteristics of low power consumption and simple equipment operation, it has gradually become the core technology in this field. Due to the relatively large volume of bacteria (such as yeast, etc.) and pulp cells, the existing conventional hollow fiber ultra / microfiltration membranes cannot be fully applied, and generally have small pore diameters (resulting in low filtration efficiency) and high tortuous pore structures. It leads to low operating efficiency of equipment and limited...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/68B01D69/08B01D67/00B01D71/42
Inventor 胡晓宇李洪港梁义
Owner TIANJIN MOTIMO MEMBRANE TECH
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