A kind of preparation method of binary polyacrylonitrile-based carbon fiber precursor
A polyacrylonitrile-based carbon fiber and acrylonitrile technology, which is applied in the direction of spinning solution preparation, fiber type, fiber treatment, etc., can solve the problems of difficulty in controlling the structural regularity of polyacrylonitrile polymers and the large amount of comonomers, and achieve Small fineness, improved structural regularity, and high purity
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Embodiment 1
[0032] (1) Vacuumize the polymerization reactor and circulate nitrogen for 3 times. Add 9.9kg of acrylonitrile, 60g of β-methyl itaconate amide, and 41.67kg of dimethyl sulfoxide into a 100L polymerization reactor. Azodiisobutyronitrile, gradually increase the temperature from 35°C to 60°C (taking 5 hours), and gradually add the remaining 40g of the second monomer β-methyl itaconate amide dropwise (continuing 12 hours), while maintaining the reaction at 60°C After 24 hours, the molecular weight of the prepared polyacrylonitrile was 3.9×10 5 g / mol, and the molecular weight distribution is 2.44. The above-mentioned polymer solution is filtered through a pressure-sensitive automatic scraper cylindrical filter, and then singled and defoamed to obtain a spinning stock solution.
[0033] (2) The spinning stock solution obtained in step (1) is subjected to dry-jet wet spinning, the positive draft of the spinneret is 2.2 times, the content of dimethyl sulfoxide in the primary coagula...
Embodiment 2
[0035] (1) Vacuumize the polymerization reactor and circulate nitrogen for 3 times. Add 9.9kg of acrylonitrile, 60g of β-methyl itaconate amide, and 38.46kg of dimethyl sulfoxide into a 100L polymerization reactor. Azodiisobutyronitrile, gradually increase the temperature from 35°C to 60°C (taking 5 hours), and gradually add the remaining 40g of the second monomer β-methyl itaconate amide dropwise (continuing 12 hours), while maintaining the reaction at 60°C After 24 hours, the molecular weight of the prepared polyacrylonitrile was 4.6×10 5 g / mol, molecular weight distribution is 2.56. The above-mentioned polymer solution is filtered through a pressure-sensitive automatic scraper cylindrical filter, and then singled and defoamed to obtain a spinning stock solution.
[0036] (2) The spinning stock solution obtained in step (1) is subjected to dry-jet wet spinning, the positive draft of the spinneret is 2.2 times, the content of dimethyl sulfoxide in the primary coagulation bat...
Embodiment 3
[0038] (1) Vacuumize the polymerization reactor and circulate nitrogen for 3 times. Add 9.9kg of acrylonitrile, 60g of β-methyl itaconate amide, and 41.67kg of dimethyl sulfoxide into a 100L polymerization reactor. Azodiisobutyronitrile, gradually increase the temperature from 35°C to 60°C (taking 5 hours), and gradually add the remaining 40g of the second monomer β-methyl itaconate amide dropwise (continuing 12 hours), while maintaining the reaction at 60°C After 24 hours, the molecular weight of the prepared polyacrylonitrile was 3.6×10 5 g / mol, the molecular weight distribution is 2.42. The above-mentioned polymer solution is filtered through a pressure-sensitive automatic scraper cylindrical filter, and then singled and defoamed to obtain a spinning stock solution.
[0039] (2) The spinning stock solution obtained in step (1) is subjected to dry-jet wet spinning, the positive draft of the spinneret is 2.2 times, the content of dimethyl sulfoxide in the primary coagulation...
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