34results about How to "Small denier" patented technology

The invention relates to the field of chemical fibers, in particular to a cellulous fiber, a preparation method thereof and equipment. The cellulose fiber mainly comprises cellulous, is prepared by the solidifying liquid co-current drawing and spinning technology, and meets the following conditions that the tension breakage strength of the fiber is higher than or equal to 2.0cN/dtex, the fineness of the fiber is equal to or smaller than 1.67dtex, the content of S elements in the fiber is smaller than or equal to 100ppm, the fibrillation index (F.I.) of the fiber is smaller than or equal to 2. In addition, the cellulose fiber is free of chemical compositions relevant to fibrillation treatment resistance. The invention further relates to the preparation method of the cellulous fiber and the equipment. The cellulose fiber is high in strength, low in fineness and free of fibrillation tendency, the preparation method is simple, and is easy to control and applicable to large-scale industrialized production, and the equipment is simple in structure, skillful in design and stable in condition.

The invention relates to extracting and drying methods in the process for preparing uhmwpe fiber, belonging to the field for polymers preparing technology. The method comprises that the uhmwpe powder, assistant and solvent is solidified by extruding after they are mixed in uniformity and solved sufficiently; the solvent is eliminated in extracting process and the extraction agent is eliminated by drying technology; the final product is formed by heat drawing. It is characterized in that because dichloromethane is used as the extraction agent, there is good safety, low boiling point and it is eliminated easily. Because countercurrent extraction operation is adopted in the extracting process and there is no ultrasonic wave, it is provided with low drying temperature, simple technology, high intensity of fiber product, high modulus and low oil percentage of fiber.

The invention provides a solidification method for preparing para-aramid by adopting dry jet-wet spinning. The method is characterized by comprising the following specific steps: extruding a PPTA-H2SO4 spinning solution from a spinneret plate; enabling liquid flow extruded from the spinneret plate to vertically pass through an air layer and feeding to a solidification bath; leading out through a godet wheel, so as to obtain a nascent fiber; and washing, winding and drying, so as to obtain a para-aramid fiber precursor, wherein the solidification bath is sulfuric acid solution and is formed by sulfuric acid and water; the mass fraction of the solidification bath is 2.0%-15.0%; and the temperature of the solidification bath is 1-12 DEG C. The fineness of the fiber can be significantly reduced under the condition of the solidification bath; the strength of the para-aramid fiber is improved; the apparent defects of the fiber can be reduced; and the fiber quality is improved, thus the stability of a spinning process and the quality of a fiber product can be effectively improved.

The invention relates to a method of preparing ultrahigh molecular weight polyethylene fiber through gel spinning method. The method comprises the following steps: (1) preparing gel protofilament of ultrahigh molecular weight polyethylene; and (2) processing the gel protofilament through extracting, drying and hot drawing to obtain the ultrahigh molecular weight polyethylene fiber. The method is characterized in that the method also comprises the step of pre-drawing the gel protofilament obtained in the step (1) before the step (2), wherein the pre-drawing time is 2.2-24 times and the total hot drawing time in the step (2) is 30-45 times. The method of the invention can be used to obtain ultrahigh molecular weight polyethylene fiber product with low size and high breaking strength and the production cost is low.

The invention relates to a superfine dacron low stretch yarn and a preparation method thereof. Modified polyester fusant is subjected to metering, extrusion, cooling, oiling and winding to prepare POYyarns; the POY yarns are subjected to yarn guide tube passing, networking, heating stretching, false twisting, heat setting and winding formation to prepare DTY yarns, i.e., the superfine dacron lowstretch yarn is obtained. During cooling, the longitudinal height is kept unchanged; the cross section area of a slow cooling chamber is increased; meanwhile, the slow cooling chamber maintains the plate surface temperature of a spinneret plate in a heat insulation mode; an oil agent for oiling contains crown ether; the content of the crown ether is 67.30 to 85.58 weight percent; the dihydric alcohol chain segment with branched chain is introduced into modified polyester; the prepared superfine dacron low stretch yarn has the filament number being smaller than 0.3dtex; the crimp shrinkage is 8.0+/-1.0 percent; the crimp stability is greater than or equal to 75 percent. The method is simple and reasonable; the prepared superfine dacron low stretch yarn has the advantage of low fiber number.

The invention relates to a high-shrinkage superfine acrylic fiber and a preparation method thereof. The high-shrinkage superfine acrylic fiber consists of 91-94 percent of acrylonitrile and 6-9 percent of vinyl acetate, wherein the fineness is 0.8-1.2dtex, and the shrinkage rate is 18-30 percent. The preparation method comprises the following steps: performing spinning forming, washing, drafting, oiling, drying, setting and performing high-shrinkage treatment. The prepared vivid cashmere-imitated high-shrinkage superfine acrylic fiber has excellent performances on strength, elongation, shrinkage rate, dyeing property, elasticity, glossiness, gas permeability and the like.

The invention relates to a preparation method of a binary polyacrylonitrile carbon fiber precursor. The method comprises the following steps: mixing acrylonitrile, a second comonomer beta-itaconic acid ester amide and a solvent in the presence of nitrogen, and adding an initiator; reacting for 22-38 hours under the condition of 35-75 DEG C, so as to obtain an acrylonitrile polymer; then filtering, taking off and defoaming, so as to prepare a spinning solution; spinning the spinning solution by virtue of a dry-jet wet process, stretching, oiling, drying, densifying, drawing by hot steam, and thermoforming, so as to obtain the binary polyacrylonitrile carbon fiber precursor. By adopting the preparation method, double functional group beta-itaconic acid ester amide is adopted as a comonomer, and a polyacrylonitrile macromolecule for the carbon fiber precursor is prepared by binary copolymerization and substituted ternary copolymerization. Thus, the dosage of the comonomer is reduced, meanwhile, the structural regularity of the polyacrylonitrile macromolecule is improved, and the prepared carbon fiber precursor is even in structure, small in fineness and high in strength.

The invention relates to a method for preparing a carbon fiber precursor by polymerization from a mixed solvent. The method for preparing the carbon fiber precursor by polymerization from the mixed solvent comprises the following steps: (1) initiating copolymerization on acrylonitrile, 3-carboxyl-3 butylene amide and itaconic acid diester at the temperature of 50-80 DEG C while dimethyl sulfoxide/deionized water or N,N-dimethyl formamide/deionized water is taken as the solvent and azodiisobutyronitrile is taken as an initiating agent; and (2) dissolving an acrylonitrile polymer obtained in the step (1), defoaming, filtering, carrying out dry jet wet spinning, drawing, oiling, compacting by drying, drawing in superheated steam, and carrying out heat setting, so that the carbon fiber precursor is obtained. The method for preparing the carbon fiber precursor by the polymerization from the mixed solvent has the advantages that the characteristic that the chain transfer constant of the deionized water is zero is utilized, the molecular weight of the polymer is regulated and controlled by regulating the ratio of the deionized water to the organic solvent, the molecular weight of the prepared polymer is more than 1.5 times of the molecular weight of the polymer obtained by the polymerization from the traditional solvent, and the prepared carbon fiber precursor is uniform in structure, low in fineness and high in strength; meanwhile, water is adopted for substituting part of the organic solvent, the environment protection can be facilitated, and the production cost is effectively reduced.

The invention provides a clothes-hanger shaped spinning die head runner structure for uniform melt distribution and a clothes-hanger shaped spinning die head with the die head runner structure. The structure is characterized in that firstly, the flow rate of high polymer melt in the breadth direction of a slit runner outlet is equal everywhere; secondly, the pressure drop of the high polymer meltflowing from a feeding port to the slit runner outlet is equal everywhere in the breadth direction; thirdly, the staying time of the high polymer melt in the whole spinning die head runner structure is short and equal everywhere at the slit runner outlet along the in the breadth direction. The equalities in three aspects have unique advantages in production of high polymers with poor thermal stability or with dependency of the rheological property on time. By adoption of the clothes-hanger shaped spinning die head runner structure, stable and uniform products can be prepared, such as ultrafinenanofibers and related products thereof. A wide application range is realized, and a great spinning performance aiming at high polymers which can be hardly processed and utilized by conventional spinning equipment is achieved.

The invention belongs to the field of spinning materials, and provides a nylon 66 resin. The nylon 66 resin is prepared by polymerization and post condensation polymerization reaction after nylon 66 salt melt and a compound of a first main group metal are mixed, wherein based on the weight of the nylon 66 salt, the weight of the compound of the first main group metal is 0.03 to 1.0 percent. The invention also provides a nylon 66 filament prepared from the nylon 66 resin. The nylon 66 filament is obtained by melt spinning of the nylon 66 resin. The fine denier or superfine denier nylon 66 filament with fineness of about 0.30 to 1.0dtex can be obtained by using the nylon 66 resin and a preparation method, the strength and the breaking elongation of the fibers meet the requirements of post weaving, the blank of producing the fine denier/superfine denier nylon 66 filament by adopting the conventional high-speed spinning method at home and abroad is filled, and the technological content and the additional value of the nylon 66 fiber product are promoted.

The invention relates to a method for preparing a binary polyacrylonitrile-based carbon fiber protofilament. The method comprises the following steps of: (1) performing copolymerization reaction on acrylonitrile and beta-ammonium itaconate for 10 to 30 hours at the temperature of between 50 and 70 DEG C by using dimethyl sulfoxide as a solvent and using azodiisobutyronitrile as an initiator, filtering, removing residual monomers, and defoaming to obtain a spinning solution; and (2) sequentially performing dry-spray wet spinning, drawing, oiling, drying densification, hot steam drawing and heat setting on the spinning solution, and thus obtaining the carbon fiber protofilament. By the method, the consumption of copolymerization monomers is reduced, and the structural regularity of polyacrylonitrile macromolecules is improved; and the prepared carbon fiber protofilament is uniform in structure, low in fineness and high in strength, and is suitable for preparing high-performance carbon fibers.

The invention discloses a fine denier yarn leather base fabric and a preparation method thereof. In the leather base fabric, fine denier yarn grey cloth is weaved by using fine denier yarns warps and wefts, and the leather base fabric with the thickness below 0.15mm is prepared by dyeing and finishing the grey cloth. The preparation method comprises the following steps of: (1) desizing, scouring and dyeing by adopting a full width jig dyeing machine, wherein the temperature for desizing, scouring and dyeing is 90+/-2 DEG C, and the velocity for desizing, scouring and dyeing is 95+/-2m/min; (2) selecting a desizing mode: bio-enyzme desizing is adopted, wherein a bio-enzyme preparation is intermediate temperature alpha-amylase, the proportion of the substances in desizing is as follows: 2 to 10g of intermediate temperature alpha-amylase and 2 to 10g of salt are contained in water per liter; (3) raising: raising is realized by an imported raising machine the model of which is 92067-R2094; and (4) shaping the finished product: the shaping temperature is controlled within a range from 180 to 185 DEG C, and the shaping time is controlled within a range from 35 to 45 seconds.

The invention concerns a spinning method without recourse to a flyer, for the direct spinning of sliver and also concerns an apparatus with a draft system in accord with the principal concepts of the independent claims. Various attempts have been made known, of directly spinning fiber on a ring spinning machine. In the case of spinning methods of this type, it is possible to eliminate the use of the flyer so that costs and space can be saved. It is particularly well known, that sliver with a band fineness of ca. 5 ktex in connection with a first draft system, which is normally a component of a draw frame, can be stored in a can. These cans are then brought to a movable creel, on which they are pulled away and fed into respectively one spinning position of a ring spinning machine. Since on the said creel, distortions of the sliver can occur, at this location no bands of less than 3.5 ktex are allowed. Since the distortion at the ring spinning machine is machine-limited, it is possible with this known method, to spin chiefly only rough ring yarn. This method has not been particularly well accepted due to: difficult access for maintenance, necessary space for the cans and the said distortion. One achieves finer yarns normally by the interposition of a flyer, by means of which a fiber with a band weight, for example, of 5 ktex is drawn to a pre-yarn with a roving of 200-1200 tex and wound onto a spool, in order that this can then be delivered to a ring spinning machine.

The invention belongs to the technical field of fibers, and particularly relates to a melt-blown fiber, a preparation method thereof and an application of the fiber. The diameter of the melt-blown fiber is 200-2000 nanometers, and the weight percentage content of the melt-blown fiber within the range of the diameter is larger than or equal to 80%. A melt-blown fiber mesh is prepared from the melt-blown fiber, the filtering effect, thermal insulation, oil absorbency and the sound absorption effect of the melt-blown fiber and the prepared melt-blown fiber mesh are improved by 10-60% as comparedwith those of a common melt-blown fiber and a common melt-blown fiber mesh, and the melt-blown fiber and the melt-blown fiber mesh have the advantages of poisonless and harmless properties and the like.