47results about How to "Improve structural regularity" patented technology

The present invention relates to a positive electrode material for secondary battery and the preparation method thereof, wherein the said positive electrode material comprises Li_xNi_1−y−zCo_yMe_zO_2±n as the main component, 0.9≦x≦1.1, 0<y≦0.3, 0≦z≦0.1, 0≦n≦0.1 and Me is selected at least one or two elements from the group consisting of Mg, Zn, Mn, Co, Al and Ca in the formula, and Li_vNi_1−aMe′_aO_2±m or Li_xNi_1−yMe″_yPO₄ existed on the polycrystalline surface of the main component and/or among the crystal phase of the main component. The proportion of peak intensity ratio of (003) to (104) of the positive electrode material in the polycrystalline X-ray diffraction spectrum is 2.0≦I₍₀₀₃₎/I₍₁₀₄₎≦3.0. The secondary battery comprising said positive electrode material is liquid, solid or polymer lithium secondary battery or lithium ion battery.

A method for manufacturing a carbon molecular sieve with increased microporosity; a method for manufacturing a carbon molecular sieve with increased microporosity and improved structural regularity; a carbon molecular sieve with increased microporosity; a carbon molecular sieve with increased microporosity and improved structural regularity; a catalyst for a fuel cell using the carbon molecular sieve; and a fuel cell using the catalyst are provided.

The invention relates to a differential shrinkage composite filament and a preparing method thereof. According to the invention, modified polyester employs a porous spinneret for spinning to prepare the differential shrinkage composite filament; an arrangement mode of the spinneret holes on the porous spinneret is in an elliptical shape, the aperture center of the spinneret holes is positioned on concentric ellipses, the concentric ellipses are a series of ellipses, the long shafts of all ellipses are collinear, and the short shafts are collinear. The differential shrinkage composite filament is subjected to plying and doubling by modified polyester POY filament and FDY filament, then is composited through network, and finally reeled. A preparation method of the modified polyester comprises the following steps: terephthalic acid and glycol are subjected to a reaction to prepare ethylene glycol terephthalate, terephthalic acid and branched chain-containing dihydric alcohol are subjected to a reaction to obtain terephthalic acid glycol ester, and continuous reacting is carried out on the material to obtain the product. The filament has excellent fiber performance, the linear density deviation ratio is less than or equal to 2.0%, a breaking tenacity CV value is less than or equal to 4.0%, a breaking elongation CV value is less than or equal to 8.0%, and a crimp contraction variation coefficient CV value is less than or equal to 8.0%.

The invention relates to a porous soft polyester fiber FDY yarn and a preparing method thereof. According to the invention, modified polyester employs a porous spinneret for spinning to prepare the porous soft polyester fiber FDY yarn; an arrangement mode of the spinneret holes on the porous spinneret is in an elliptical shape, the aperture center of the spinneret holes is positioned on concentric ellipses, the concentric ellipses are a series of ellipses, the long shafts of all ellipses are collinear, and the short shafts are collinear. the porous soft polyester fiber FDY yarn is prepared by metering modified polyester slices, extruding, cooling, oiling, stretching, thermoforming and reeling the material. A preparation method of the modified polyester comprises the following steps: terephthalic acid and glycol are subjected to a reaction to prepare ethylene glycol terephthalate, terephthalic acid and branched chain-containing hexanediol are subjected to a reaction to obtain the terephthalic acid glycol ester, and continuous reacting is carried out on the material to obtain the product. The yarn has excellent fiber performance, the linear density deviation ratio is less than or equal to 0.5%, the breaking tenacity CV value is less than or equal to 4.0%, breaking elongation CV value is less than or equal to 8.0%, and a yarn unevenness CV value is less than or equal to 2.0.

The invention provides a preparation method of a high regularity mesoporous molecular sieve Fe-MCM-41. The preparation method is characterized in that an aftertreatment for a Si-MCM-41 matrix is carryed out to make the Si-MCM-41 matrix have an interaction with at least one soluble ferric salt to introduce a hetero atom Fe into the Si-MCM-41 matrix without any influence for a structure of the Si-MCM-41 matrix and thus a high regularity mesoporous molecular sieve Fe-MCM-41 is synthesized. The high regularity mesoporous molecular sieve Fe-MCM-41 has the advantages of uniform aperture sizes, big specific surface area and aperture volume, and favorable thermostability.

The invention discloses a preparation method of polyfuran dioctyl phthalate glycol ester. The preparation method comprises the following steps: (1) esterification or ester exchange reaction: adding furan dioctyl phthalate or furan dioctyl phthalate diester, ethylene and nitrogen-containing catalyst to a reactor, and reacting for 2-5 hours at 160-210 DEG C to obtain an esterification or ester exchange product; (2) polycondensation: reacting the esterification or ester exchange product in the conditions of pressure of less than or equal to 150Pa and temperature of 220-250 DEG C to prepare polyfuran dioctyl phthalate glycol ester. According to the invention, the efficient and high-selectivity nitrogen-containing catalyst is adopted, thus being favorable for improving the esterification or ester exchange rate, promoting polycondensation and improving molecular weight; and the prepared product is colorless or shallow in color, less in byproducts and good in structure regularity. According to the preparation method, only one nitrogen-containing catalyst is needed and is only added before reaction, adding of catalyst is not needed in the medium process, the process is very simple, the process is environmentally friendly, and realization of industrialization is facilitated.

The present invention is a composition for forming a porous film obtainable by hydrolysis and condensation, in an acidic or alkaline condition, of a mixture of 100 parts by weight of one or more compounds selected of the group consisting of hydrolysable silicon compounds represented by Formulas (1) and (2) as described herein and partially hydrolyzed and condensed products of the hydrolysable silicon compounds represented by Formulas (1) and (2), and 0.1 to 20 parts by weight of one or more cross-linking agents selected from the group consisting of structure-controlled cyclic or multi-branched oligomers represented by Formulas (3) to (8) as described herein.

The invention discloses a preparation method of a sulfur dioxide and epoxide copolymer. According to the method, a novel polysulfone material is prepared through copolymerization of sulfur dioxide and epoxide under the catalytic action of SalenMX, epoxide and SalenMX are sequentially added to a high-pressure reaction kettle, sulfur dioxide is introduced and has a reaction at the temperature of 50-100 DEG C for 8-48 h, then, a product, namely, the sulfur dioxide and epoxide copolymer is obtained, the product is dissolved with chloroform, a hydrochloric acid and methanol mixed solution is used for precipitation, amber precipitates are filtered and repeatedly washed with methanol for 2-4 times, the washed product is transferred to a vacuum drying box and dried in vacuum at the room temperature for 8-24 h, and the sulfur dioxide and epoxide copolymer with higher stereoregularity can be obtained. The preparation method is simple, few catalysts are used, the reaction temperature is mild, the yield is high, the structure regularity of the product is good, the cost is low, and industrial production is easy to realize.

The invention relates to a preparation method of a binary polyacrylonitrile carbon fiber precursor. The method comprises the following steps: mixing acrylonitrile, a second comonomer beta-itaconic acid ester amide and a solvent in the presence of nitrogen, and adding an initiator; reacting for 22-38 hours under the condition of 35-75 DEG C, so as to obtain an acrylonitrile polymer; then filtering, taking off and defoaming, so as to prepare a spinning solution; spinning the spinning solution by virtue of a dry-jet wet process, stretching, oiling, drying, densifying, drawing by hot steam, and thermoforming, so as to obtain the binary polyacrylonitrile carbon fiber precursor. By adopting the preparation method, double functional group beta-itaconic acid ester amide is adopted as a comonomer, and a polyacrylonitrile macromolecule for the carbon fiber precursor is prepared by binary copolymerization and substituted ternary copolymerization. Thus, the dosage of the comonomer is reduced, meanwhile, the structural regularity of the polyacrylonitrile macromolecule is improved, and the prepared carbon fiber precursor is even in structure, small in fineness and high in strength.

The invention discloses a preparation method of a sulfur dioxide, carbon dioxide and epoxide copolymer. According to the method, epoxide, SalenCr<III>Cl and PPNCl are sequentially added to a high-pressure reaction kettle, sulfur dioxide and carbon dioxide are introduced and have a reaction at the temperature of 50-100 DEG C for 8-48 h, then, a product is dissolved with chloroform, a hydrochloric acid and methanol solution is used for precipitation, amber precipitates are filtered and repeatedly washed with methanol, the washed product is dried in vacuum at the room temperature, and the sulfur dioxide, carbon dioxide and epoxide terpolymer with higher stereoregularity can be obtained. The sulfur dioxide, carbon dioxide and epoxide terpolymer has structural characteristics of polycarbonate and polysulfone and has a wide application prospect in the fields of packaging, filtration and the like; the preparation method is simple, few catalysts are used, the reaction temperature is mild, the yield is high, the structure regularity of the product is good, the cost is low, and industrial production is easy to realize.

The invention relates to a method for preparing a carbon fiber precursor by polymerization from a mixed solvent. The method for preparing the carbon fiber precursor by polymerization from the mixed solvent comprises the following steps: (1) initiating copolymerization on acrylonitrile, 3-carboxyl-3 butylene amide and itaconic acid diester at the temperature of 50-80 DEG C while dimethyl sulfoxide/deionized water or N,N-dimethyl formamide/deionized water is taken as the solvent and azodiisobutyronitrile is taken as an initiating agent; and (2) dissolving an acrylonitrile polymer obtained in the step (1), defoaming, filtering, carrying out dry jet wet spinning, drawing, oiling, compacting by drying, drawing in superheated steam, and carrying out heat setting, so that the carbon fiber precursor is obtained. The method for preparing the carbon fiber precursor by the polymerization from the mixed solvent has the advantages that the characteristic that the chain transfer constant of the deionized water is zero is utilized, the molecular weight of the polymer is regulated and controlled by regulating the ratio of the deionized water to the organic solvent, the molecular weight of the prepared polymer is more than 1.5 times of the molecular weight of the polymer obtained by the polymerization from the traditional solvent, and the prepared carbon fiber precursor is uniform in structure, low in fineness and high in strength; meanwhile, water is adopted for substituting part of the organic solvent, the environment protection can be facilitated, and the production cost is effectively reduced.

The invention relates to a preparation method of a ternary polyacrylonitrile copolymer, which comprises the steps of heating an aqueous solution of maleic anhydride, acrylamide and a dispersing agent to 55-75 DEG C under a nitrogen shielding condition, adding acrylonitrile to keep constant temperature for 20-30min, adding an initiator solution for reaction for 3-12h, and carrying out washing, demonomerisation, filtration and drying. The method employs a mixed solvent precipitation polymerization method for polymerization and has the advantages of high reaction yield, high viscosity average molecular weight, narrow distribution, easiness in temperature control, stable product quality and the like. The thermal property of the polyacrylonitrile copolymer prepared by the method can be effectively improved, and the copolymer has certain practical application prospects.

The invention relates to a method for preparing a binary polyacrylonitrile-based carbon fiber protofilament. The method comprises the following steps of: (1) performing copolymerization reaction on acrylonitrile and beta-ammonium itaconate for 10 to 30 hours at the temperature of between 50 and 70 DEG C by using dimethyl sulfoxide as a solvent and using azodiisobutyronitrile as an initiator, filtering, removing residual monomers, and defoaming to obtain a spinning solution; and (2) sequentially performing dry-spray wet spinning, drawing, oiling, drying densification, hot steam drawing and heat setting on the spinning solution, and thus obtaining the carbon fiber protofilament. By the method, the consumption of copolymerization monomers is reduced, and the structural regularity of polyacrylonitrile macromolecules is improved; and the prepared carbon fiber protofilament is uniform in structure, low in fineness and high in strength, and is suitable for preparing high-performance carbon fibers.

The invention discloses a preparation method of a flexible brain nerve electrode coating and an electrode assembled by the flexible brain nerve electrode coating, and relates to the field of implantable medical device. Polyethylene glycol, medicinal dexamethasone and polylactic acid-glycolic acid copolymer loaded medicinal dexamethasone nanoparticles are mixed in a beaker to form a mixture, and a composite coating is prepared in a specific mold and is connected with the flexible brain nerve electrode through polyvinyl alcohol. The flexible brain nerve electrode composite coating which has relatively high mechanical hardness and strength and can continuously release anti-inflammatory drugs can be rapidly, simply and conveniently prepared, and implantation of the flexible brain nerve electrode is assisted. Polyvinyl alcohol can be completely hydrolyzed within 1 min, the composite coating can be rapidly separated from the neural electrode after implantation, no polymer adheres to the metal electrode site of the neural electrode, normal recording of the electrode on the bio-electricity signal is not affected, and the slow-release anti-inflammatory drug can relieve the inflammatory response of tissue.

The invention relates to active nano silicon dioxide microspheres, a solution and a preparation method and application thereof, and mainly solves the problem that the nano silicon dioxide microspheresprepared by using an existing method cannot be directly subjected to chemical reaction with the surfaces of modified glass, ceramic and silicon, so that a coating with a micro-nano characteristic structure is difficult to prepare. According to the technical scheme, the active nano silicon dioxide microspheres are adopted; the active nano silicon dioxide microspheres comprise nano silicon dioxidemicrospheres and an active layer on the surfaces of the nano silicon dioxide microspheres, and the active layer contains condensable siloxane, so that the problem is better solved, and preparation ofcoatings with micron or nano structure characteristics on the surfaces of glass, ceramics and silicon can be realized.

The invention provides a portable charger. An electric appliance box is arranged in a housing. An upper end head of the electric appliance box is connected to the central position of a housing top plate. A certain interval exists between the outer wall of the housing and the outer wall of the electric appliance box. An external thread is formed in the outer wall of the electric appliance box. A plurality of electric plugs are connected to the lower end of the electric appliance box. A telescopic cylinder is arranged in a storage box. A lower end port of the telescopic cylinder is in abutted connection with a central hole in a bottom plate of the storage box. An internal thread is formed in the inner wall of the telescopic cylinder. The storage box is connected with the thread of the electric appliance box in the housing through the telescopic cylinder. A power supply wire is arranged in the storage box and is wound on the telescopic cylinder. One end of the power supply wire penetrates through the interval to be connected with the electric appliance box, and the other end of the power supply wire penetrates out through a through hole in the outer wall of the storage box to be connected with a charging head. A hand holds the storage box and pulls the power supply wire out from the storage box, and the power supply wire can drive the electric appliance box to rotate around the telescopic cylinder. When the electric appliance box moves downwards with the rotation along the thread, the electric plugs on the electric appliance box are enabled to extend out from the central hole in the storage box.

Disclosed is a method for production of a mesoporous silica under electrolyte-free conditions by using a surfactant aggregate structure as a template. Also disclosed is a mesoporous silica having a novel geometrical structure which has not been produced heretofore. A mesoporous silica can be produced under electrolyte-free conditions by reacting a nonionic surfactant with a water-soluble silicate monomer having a specific structure under neutral conditions. A nonionic surfactant may be used which can form a ribbon phase or nematic phase at appropriate temperature range and concentration range when dissolved in water. By using the nonionic surfactant, a sheet-like mesoporous silica can be prepared.

The invention provides an organic compound based on a nitrogen-containing heterocyclic ring and a preparation method and application of the organic compound and relates to the field of OLED (organic light emitting diode) materials. The organic compound has a structural formula shown in the description. The organic compound provided by the invention has a high neat degree, high luminous efficiencyand heat stability, enables carrier transmission to be balanced, is applied to organic light emitting devices, especially used as a blue light emitting material in an OLDE light emitting layer, has high luminous efficiency, has a good application effect in OLED devices, has a good industrialization prospect.

The invention relates to porous soft polyester fiber POY and a preparation method thereof. Modified polyester undergoes spinning by a porous spinneret plate to prepare porous soft polyester fiber POY. The arrangement mode of spinneret orifices on the porous spinneret plate is elliptical arrangement. That is to say, the centers of the spinneret orifices are positioned at concentric ellipses which are series ellipses. Long axis of all the ellipses is collinear, and minor axis is collinear. According to the porous soft polyester fiber POY, modified polyester undergoes grain-sized dicing to obtain modified polyester chip; and the modified polyester chip undergoes metering, extrusion, cooling, oiling and winding so as to prepare the product. A preparation method of the modified polyester comprises the following steps: letting terephthalic acid and glycol react to prepare ethylene glycol terephthalate, adding terephthalic acid and dihydric alcohol containing branched chain and reacting to prepare terephthalic dibasic alcohol ester, and continuously reacting to the modified polyester. The prepared fiber has excellent properties. Deviation ratio of linear density is less than or equal to 0.2%; breaking strength CV value is less than or equal to 2.5%; and breaking elongation CV value is less than or equal to 5.0%.

The invention discloses an antiskid permeable pavement which comprises a pavement base layer and an adhesive stone surface layer paved on the surface of the pavement base layer, the adhesive stone surface layer is prepared from the following raw materials in parts by weight: 2-5 parts of a component A, 3-7 parts of a component B and 95-105 parts of aggregate; the component A is prepared from the following raw materials: polyester of aliphatic dicarboxylic acids, polyether polyol, dipropylene glycol, neopentyl glycol, linoleic acid, castor oil, 2,2,3,3,4, 4,5,5-octafluoro-1-amyl alcohol, epoxyresin E-44, epoxy resin E-14, diphenyl-methane-diisocyanate, hexamethylene diisocyanate, nano silicon dioxide, nano calcium carbonate, boron carbide and modified lignin; the component B is prepared from the following raw materials: 1,8-diazacyclo[5,4,0]undecene-7 and triethanolamine. The anti-skid permeable pavement provided by the invention has the advantages of good skid resistance and water permeability, excellent aging resistance, short curing time and long service life.