The invention is a new catalyst for synthesizing tert-butyl to replace phenol and the process, belongs to the synthesizing method for tert-butyl to replace phenol and relative solid acid catalyst, which refers to crystal silicon aluminum acid salt catalyst and the process. the catalyst is made up mainly by micropore aluminosilicate, and loads one to three kinds of elements of boracium, magnesium, aluminum, phosphorus, calcium, titanium, zinc, molybdenum as active components, the process is convenient, the activity and the selectivity are high, can be sued repeatedly; the reaction uses moderate operation condition and continuous flow method, the tert-butyl replaced phenol can be produced by putting phenols and alkylation agent through the catalyst bed; the environment of the process is friendly, the side product is little, the process is simple.