The invention discloses a halidesolidelectrolyte with electrochemical activity and a preparation method and application thereof, the solidelectrolyte is a zirconium-doped ferriclithiumchloridesolidelectrolyte, the chemical general formula of the solid electrolyte is LiFe1-4x / 3MxCl4, M is a metal element with the valence state higher than + 3, 0 lt; xlt; 1. According to the halide solid-state electrolyte with the electrochemical activity, the ionic conductivityorder of magnitude is improved, the room-temperature ionic conductivity is improved to 10 <-3 > S / cm from 10 <-6 > S / cm by three orders of magnitude, so that the material is changed from'unavailability 'to'high performance', and the application requirement of an all-solid-state battery is met.