Flame-retardant polyolefin resin composition and preparation method thereof, and flame-retardant tubular product

A polyolefin resin and composition technology, which is applied in the field of fire protection, can solve the problems of poor flame retardant effect, difficult oxygen index, and large smoke generation, and achieves the advantages of increasing heat resistance, good flame retardant effect and reducing smoke density grade. Effect

Active Publication Date: 2014-05-07
应急管理部四川消防研究所
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims at providing a flame retardant polyolefin resin composition aimed at the technical problems that the flame retardant used in the patent document CN200610144023.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Raw material for flame retardant polyolefin resin composition

[0020] 90 parts of high-density polyethylene (PE-RT), 10 parts of polypropylene, 30 parts of bromine antimony composite flame retardant, 2 parts of EVA resin modifier, 0.3 part of EBS processing aid, 0.1 part of 1010 antioxidant and 0.1 Part polyol fatty acid ester antistatic agent.

[0021] Among them, bromine-antimony composite flame retardants are:

[0022] Basic flame retardant (decabromodiphenylethane: antimony trioxide: phenolic resin = 15 parts: 5 parts: 5 parts) 25 parts of flame retardant and smoke suppressant (1 part of zinc aluminate, 1 part of organic ferrocene, 3 parts of nano-montmorillonite) 5 parts

[0023] After weighing the above raw materials, mix them in a mixer for 15 minutes. Then, pour it into a twin-screw extruder, control the screw speed of the extruder to 100r / min, and control the temperatures of the first zone to the ninth zone on the extruder to be 160°C, 170°C, 170°C, 175°C, ...

Embodiment 2

[0027] Flame-retardant polyolefin resin composition raw material

[0028] 100 parts of high temperature resistant non-crosslinked polyethylene (PE-RT) for hot and cold water, 56 parts of bromine antimony composite flame retardant, 10 parts of maleic anhydride grafted polyethylene resin modifier, 1.0 part of PE wax processing aid , 0.5 part of 168 antioxidant and 0.5 part of hydroxyethyl fatty amine antistatic agent.

[0029] Among them, bromine-antimony composite flame retardants are:

[0030] Basic flame retardant (decabromodiphenylethane: antimony trioxide: phenolic resin = 30 parts: 10 parts: 15 parts) 55 parts flame retardant synergist (zinc aluminate 0.2 parts, zinc stannate 0.3 parts, nano Montmorillonite 0.5 part) 1 part

[0031] After weighing the above raw materials, mix them in a mixer for 15 minutes. Then pour it into a twin-screw extruder, control the screw speed of the extruder to 90r / min, and control the temperatures of the first zone to the ninth zone of the ex...

Embodiment 3

[0035] Flame-retardant polyolefin resin composition raw material of the present invention

[0036] 80 parts of high temperature resistant non-crosslinked polyethylene (PE-RT) for hot and cold water, 20 parts of polypropylene, 85 parts of bromine-antimony composite flame retardant, 20 parts of maleic anhydride grafted polypropylene resin modifier, 1.5 parts (1.0 parts of polypropylene wax, 0.5 parts of magnesium stearate) processing aids, 1.5 parts of DLTP antioxidant and 1.5 parts of ethylene oxide adduct antistatic agent.

[0037] Among them, bromine-antimony composite flame retardants are:

[0038] Basic flame retardant (decabromodiphenylethane: antimony trioxide: phenolic resin = 40 parts: 10 parts: 15 parts) 65 parts of flame retardant synergist (5 parts of organic ferrocene, 4 parts of nano hydrotalcite, 6 parts of nano-copper oxide, 5 parts of zinc aluminate) 20 parts

[0039] After weighing the above raw materials, mix them in a mixer for 15 minutes. Then, pour it in...

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PUM

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Abstract

The invention discloses a flame-retardant polyolefin resin composition and a preparation method thereof, and a flame-retardant tubular product prepared from the flame-retardant polyolefin resin composition. The flame-retardant polyolefin resin composition disclosed by the invention comprises the following components in parts by weight: 100 parts of polyolefin resin, 30-85 parts of antimony bromine composite flame retardants, 2-20 parts of resin modifiers and 0.3-1.5 parts of processing agents. The tubular product prepared from the flame-retardant polyolefin resin composition disclosed by the invention has the advantages of being high in heat resistance (the vicat softening temperature of the material can be up to over 140 DEG C), high in flame retardant property (the oxygen index is greater than over 32), good in hot water resistance, low temperature resistance and long-term static hydraulic performance, long in service life, free of scaling and the like, the vertical combustion can be up to V0 grade, the smoke density SDR is smaller than 75, the damaged tubular product caused by external force can be connected in a hot melting manner, and the flame-retardant tubular product can be applied to products such as a central air conditioning pipe system, industrial water supply and drainage pipelines and the like.

Description

technical field [0001] The invention belongs to the technical field of fire protection, and in particular relates to a flame-retardant polyolefin resin composition, a preparation method thereof, and a flame-retardant pipe. Background technique [0002] Due to the improvement of the quality of life of modern people, the requirements for their living environment are also increasing day by day. The living environment that is most often close to it is the office and your own home. There are decorations and landscaping in offices and homes, and central air-conditioning pipes, water supply and drainage pipes, etc. are installed behind these decorations and landscaping. The rules and types of these central air-conditioning pipes and water supply and drainage pipes are very diverse, including metal pipes, non-metal pipes and composite pipes. However, the disadvantages of metal pipes such as easy rust and corrosion, inconvenient installation, and high cost are not popular. At pres...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/12C08L51/06C08L23/08C08K13/02C08K5/03C08K3/22C08K3/24C08K3/34C08K3/26C08K5/098B29C47/92B29C48/92
CPCB29B9/06B29C48/92B29C2948/92704C08K2201/011C08K2201/014C08L23/06C08L23/12C08L2201/02C08L2203/18C08L2205/025C08L2205/03C08L2207/062C08L23/0853C08L61/06C08K13/02C08K5/03C08K3/2279C08K3/24C08K3/346C08K5/103C08L51/06C08K5/17C08K2003/2248B29C48/04B29C48/09B29C48/40B29C48/875B29C48/919B29C2948/9258B29C2948/9259B29C2948/92885B29C2948/92895
Inventor 李碧英张泽江兰彬卢国建张玉才刘松林
Owner 应急管理部四川消防研究所
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