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Anhydrous graphene oxide cooling liquid for engine and preparation method thereof

A graphene and water cooling technology, applied in the direction of chemical instruments and methods, heat exchange materials, etc., can solve the problems of engine overheating performance, easy cavitation, cooling system corrosion, etc., to ease the lateral temperature gradient, improve thermal conductivity, The effect of strong thermal conductivity

Active Publication Date: 2014-09-24
四川力森特节能环保材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the coolants on the market are basically water-containing coolants (water, ethylene glycol), which have low boiling points, high freezing points, easy cavitation, and poor thermal conductivity, which are no longer sufficient to meet market demand. For example, a large amount of water-containing coolants produce The water vapor forms a steam insulation layer on the metal surface around the cylinder, which makes it impossible to conduct the heat of the engine in a timely manner, and eventually causes the engine to overheat and cause its performance to decline, and the long-term use of water-containing coolant will also cause the cooling system to appear. A series of problems such as corrosion, scale, boiling, etc., cause the cooling system to be replaced every 2 years
[0004] Foreign companies believe that traditional engine coolants (water, ethylene glycol, etc.) are difficult to meet higher cooling requirements, and efficient cooling technology needs to make breakthroughs in the development of new heat transfer media with high thermal conductivity and large specific heat capacity

Method used

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  • Anhydrous graphene oxide cooling liquid for engine and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Weigh 45Kg of ethylene glycol and 48Kg of propylene glycol and stir evenly; then add 1.2Kg of silicone defoamer into it, heat and stir fully with a magnetic stirrer for about 1 hour until uniform; then add 0.5kg of tolyltriazole, 0.5kg of Benzotriazole, 0.8kg sebacic acid, 0.3kg citric acid, 0.8kg sodium hydroxide, 0.7kg phosphoric acid, 0.7kg ammonium molybdate, heated to 178°C under reflux and stirred until completely dissolved; finally added 1.5kg of graphene oxide is ultrasonically dissolved in the obtained mixed solution by an ultrasonic instrument with a frequency of 60KHZ until it is completely dissolved, and then the finished anhydrous cooling liquid of the present invention is obtained, with a freezing point of -50°C and a boiling point of 186°C.

Embodiment 2

[0023] Weigh 45Kg of ethylene glycol and 47Kg of propylene glycol and stir evenly; then add 1.2Kg of organosilicon defoamer into it, and stir fully with a magnetic stirrer for about 1 hour until uniform; then add 0.5kg of tolyltriazole, 0.5kg of benzene Triazole, 0.8kg sebacic acid, 0.6kg citric acid, 0.8kg sodium hydroxide, 0.7kg phosphoric acid, 0.7kg ammonium molybdate, heated to 180°C under reflux and stirred until completely dissolved; finally added 2.2 kg graphene oxide, ultrasonically dissolve the obtained mixed solution by an ultrasonic instrument with a frequency of 60KHZ until it is completely dissolved, and then the finished anhydrous cooling liquid of the present invention is obtained, with a freezing point of -50°C and a boiling point of 187.4°C.

Embodiment 3

[0025] Weigh 45Kg of ethylene glycol and 45Kg of propylene glycol and stir evenly; then add 1.2Kg of organosilicon defoamer to it, and stir fully with a magnetic stirrer for about 1 hour until uniform; then add 1.5kg of tolyltriazole, 0.5kg of benzene Triazole, 0.8kg sebacic acid, 0.8kg citric acid, 0.8kg sodium hydroxide, 0.7kg phosphoric acid, 0.7kg ammonium molybdate, heated to 183°C under reflux and stirred until completely dissolved; finally added 3kg Graphene oxide is ultrasonically dissolved in the obtained mixed solution by an ultrasonic instrument with a frequency of 60KHZ until it is completely dissolved, and the finished anhydrous cooling liquid of the present invention is obtained, with a freezing point of -50°C and a boiling point of 188.5°C.

[0026] After the product of the present invention is sent to the Chinese People's Liberation Army Oil Plant and Oil Plant Equipment Inspection and Test Center for inspection, the inspection report is as follows, and part of ...

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Abstract

The invention relates to anhydrous graphene oxide cooling liquid for an engine. The preparation method of the anhydrous graphene oxide cooling liquid comprises the following steps: mixing the following materials in percentage by weight: 30%-65% of ethylene glycol, 30%-65% of propylene glycol, 0.2%-3% of graphene oxide, 0.2%-2% of organic silicon defoaming agents and 0.7%-8% of composite corrosion inhibitor, and uniformly stirring till all the materials are dissolved. The anhydrous graphene oxide cooling liquid disclosed by the invention achieves high heat conductivity, has a freezing point being lower than -50 DEG C and a boiling point being as high as 188.5 DEG C and also has good corrosion resistance. According to the anhydrous graphene oxide cooling liquid, the heat conduction coefficient of a cooling system is enhanced by adopting graphene oxide with high heat conductivity; the cooling system can be better prevented from generating spot corrosion and the like through use of the organic silicon defoaming agents; copper structural components inside the engine can be well protected by tolyl triazole and benzotriazole; the pH of the cooling liquid can be effectively regulated and controlled between 7.5 and 10.0 through a neutral buffer system formed by an organic acid and the salts of the organic acid; and the cooling system can be efficiently prevented from generating precipitation, corrosion and water pump leakage by phosphoric acid-ammonium molybdate.

Description

technical field [0001] The invention relates to a graphene oxide water-free coolant for an engine and a preparation method thereof. Background technique [0002] The engine is the core component of the car. The power of the car and the driving of the car air conditioner are all borne by the engine. However, the efficiency of the engine with too high temperature will be reduced or even damaged, and the engine with too low temperature will increase fuel consumption. Therefore, the cooling system is the most effective guarantee to ensure the normal operation of the engine at normal operating temperature. [0003] With the continuous expansion of the engine market, the coolant used in conjunction with it has also been greatly developed. At present, the coolants on the market are basically water-containing coolants (water, ethylene glycol), which have low boiling points, high freezing points, easy cavitation, and poor thermal conductivity, which are no longer sufficient to meet ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/20
Inventor 黄方志张燕杨伟
Owner 四川力森特节能环保材料有限公司
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