Carbon fiber reinforced nylon 6 resin composite material and preparation method thereof

A resin composite material and composite material technology, applied in the field of carbon fiber composite materials, can solve the problems of corrosive nylon 6, high density, high price, etc., and achieve the effects of expanding application fields, simple preparation process, and low raw material cost

Inactive Publication Date: 2014-12-03
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, metal thermally conductive fillers have the disadvantages of high density, corrosion, and the decline in the mechanical properties of nylon 6 materials; inorganic non-metallic fillers are not very effective in improving the thermal conductivity of nylon 6 resins, and often also reduce the mechanical properties of nylon 6 resins.
Although the methods of using graphene, carbon nanotubes and nano-carbon fibers in carbon materials can significantly improve the thermal conductivity of nylon 6 resin, these materials cannot be industrialized and mass-produced, and the price is expensive, and the technology involved is only limited. in the laboratory research stage
High-performance pitch-based carbon fiber is a rare carbon material with a graphite structure that has achieved large-scale industrial production. Japan’s Teijin Corporation (such as Chinese patent CN101935919B, etc.) uses pitch-based carbon fiber with high thermal conductivity to improve polycarbonate and polyphenylene sulfide. , polypropylene, polylactic acid and silicone and other resins, but there are no reports of using this method to improve the thermal conductivity and / or mechanical properties of nylon 6

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Take by weight 100 parts of nylon 6 resin, 20 parts of carbon fiber, 10 parts of inorganic filler (talcum powder, magnesium oxide and silicon carbide, weight ratio 1:2:4), coupling agent (KH-550 and KR38S, weight ratio 0.5 part of 1:1), 0.2 part of antioxidant (1010) and 0 part of lubricant; mix nylon 6 resin, maleic anhydride grafted nylon 6 resin, inorganic filler, coupling agent, antioxidant and lubricant, etc. Put it into the high-speed mixer and mix evenly at high speed, and then feed the material to the hopper of the extruder, add carbon fiber at the fiber feeding port of the extruder, and control the temperature of each zone from the feeding port to the die head of the extruder to be 210, 230°C, and 245°C respectively , 245°C, 245°C, 240°C, the speed of the main machine is 50 Hz, and the composite material can be obtained by extruding and granulating through a twin-screw extruder.

[0028]The average length of the carbon fiber in the sample of this embodiment is ...

Embodiment 2

[0030] Take by weight 100 parts of nylon 6 resin, 80 parts of carbon fiber, 10 parts of inorganic filler (talcum powder, magnesium oxide and silicon carbide, weight ratio 1:2:4), coupling agent (KH-550 and KR38S, weight ratio 1:1) 5 parts, antioxidant (1010) 1 part and lubricant (silicone powder) 3 parts. Then the composite material was prepared by the same method as in Example 1.

[0031] The average length of the carbon fiber in the sample of this embodiment is 86 μm, and the properties of the composite material are respectively: bending strength 523 MPa, bending modulus 54.2 GPa, thermal conductivity 4.6 W / (mK). The flexural strength, modulus and thermal conductivity are 5.4 times, 21.7 times and 15.3 times that of pure nylon 6 resin, respectively, and the rigidity and thermal conductivity are significantly improved, which meets the requirements of thin-walled and lightweight auto parts and electronic / electrical product molding processing requirements, can greatly expand t...

Embodiment 3

[0033] Take by weight 100 parts of nylon 6 resin, 40 parts of carbon fiber, 10 parts of inorganic filler (talcum powder, magnesium oxide and silicon carbide, weight ratio 1:2:4), coupling agent (KH-550 and KR38S, weight ratio 1:1) 2 parts, 0.6 part of antioxidant (1010) and 1 part of lubricant (silicone powder). Then the composite material was prepared by the same method as in Example 1.

[0034] The average length of the carbon fiber in the sample of this embodiment is 320 μm, and the properties of the composite material are respectively: bending strength 362 MPa, bending modulus 20.6 GPa, thermal conductivity 2.6 W / (mK). The flexural strength, modulus and thermal conductivity are 3.8 times, 8.2 times and 8.7 times that of pure nylon 6 resin, respectively, and the rigidity and thermal conductivity are significantly improved, which meets the requirements of thin-walled and lightweight auto parts and electronic / electrical product molding processing requirements, can greatly ex...

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Abstract

The invention relates to a carbon fiber reinforced nylon 6 resin composite material with excellent heat conducting performance and a preparation method thereof. The composite material consists of the following materials in parts by weight: 100 parts of nylon 6 resin, 20-80 parts of carbon fiber, 10-20 parts of inorganic filling material, 0.5-5 parts of coupling agent, 0.2-1 part of antioxidant and 0-3 parts of lubricating agent. The preparation method comprises the following steps: weighing each component raw material in proportion; mixing each component raw material except for the carbon fiber at a high speed; adding an obtained mixed material into a double-screw extruder hopper, adding the carbon fiber from a fiber charging opening of the extruder, and then extruding and pelletizing. Compared with the prior art, the composite material provided by the invention is high in rigidity and good in heat conducting performance, is suitable for production and processing of thin-walled and light-weight automobile parts and electronic/electrical products; meanwhile, the composite material is low in raw material cost and simple in manufacturing process, and is suitable for industrial continuous production.

Description

technical field [0001] The invention belongs to the technical field of carbon fiber composite materials, and in particular relates to a carbon fiber reinforced poly-nylon 6 composite material with excellent thermal conductivity and a preparation method thereof. Background technique [0002] Nylon 6 is widely used in the fields of electronic appliances, automobile industry and machinery, instruments and household appliances, etc. widely used. Improving the mechanical properties and thermal conductivity of nylon 6 plays an increasingly important role in the manufacture of lightweight auto parts and miniaturized electronic and electrical components, promoting their heat dissipation, improving precision, and extending life. [0003] Composite modification methods can be used to improve the strength and thermal conductivity of polymer materials. In order to improve the strength of nylon 6 resin, glass fiber, carbon fiber, etc. can generally be used to enhance the composite meth...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L51/08C08K13/04C08K7/06C08K3/34C08K3/22C08K5/134B29C47/92B29C48/92
CPCC08L77/02B29C48/92B29C2948/9258B29C2948/92704C08K3/22C08K3/34C08K7/06C08K13/04C08K2003/222C08K2201/004C08K2201/014C08L51/08C08L83/04
Inventor 杨斌王新灵刘媛宋晨晨张媛媛
Owner SHANGHAI JIAO TONG UNIV
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