Production method for preparing ammonium dihydrogen phosphate with special astragalus membranaceus fertilizer as byproduct

A technology of ammonium dihydrogen phosphate and ammonium dihydrogen phosphate, which is applied in the direction of phosphate, phosphorus oxyacids, applications, etc., can solve the problems of increasing planting costs for growers, changes in soil structure layers, and difficulty in meeting industrial needs, etc., to achieve Significant environmental protection value and economic benefits, reduce waste liquid discharge, and increase the effect of product added value

Inactive Publication Date: 2015-01-07
GUIZHOU KAILIN GRP CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, in the prior art, there are few research techniques for special fertilizers for Astragalus, and they are all prepared by mixing traditional chemical fertilizers, compound fertilizers and other raw material fertilizers, such as the patent No. CN201010263167. "Fertilizer" is made by mixing astragalus dregs, urea, diammonium phosphate, and potassium sulfate in proportion; another example is "A kind of astragalus yield increasing agent and its preparation method" with the patent number of CN201310583089.4, which uses ammonium sulfate, potassium dihydrogen phosphate , ammonium molybdate, boric acid, sodium citrate, sodium biselenite, etc. are used as raw materials to meet the growth needs of Astragalus. The fertilizer prepared by this method can meet the needs of Astragalus planting and increase the yield of Astragalus. However, if a large amount of this fertilizer is put into the soil for a long time, it will change the soil structure layer and cause compaction. The main reason for the loss of utilization rate is that although this fertilizer can meet the needs of Astragalus crops, it is difficult for Astragalus to absorb a large amount of nitrogen, phosphorus and potassium elements, so that there is still a large amount of nitrogen, phosphorus and potassium elements in the applied fertilizer. It is not completely absorbed, and then remains in the soil, causing soil pollution. Not only that, it will also make the soil eat more and more, thereby increasing the planting cost of growe

Method used

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  • Production method for preparing ammonium dihydrogen phosphate with special astragalus membranaceus fertilizer as byproduct
  • Production method for preparing ammonium dihydrogen phosphate with special astragalus membranaceus fertilizer as byproduct
  • Production method for preparing ammonium dihydrogen phosphate with special astragalus membranaceus fertilizer as byproduct

Examples

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Effect test

Embodiment 1

[0046] A production method for preparing ammonium dihydrogen phosphate by-product Astragalus special fertilizer, comprising the following steps:

[0047] (1) Preparation and mixing of raw materials: Put phosphoric acid and urea in a stirred reactor at a molar ratio of 1.6:1, at a temperature of 97°C, and control the stirring speed of the stirred tank at 175r / min to stir and mix for 0.9h to obtain an intermediate slurry;

[0048] (2) Preparation of ammonium dihydrogen phosphate: Ammonia gas is passed into the intermediate slurry obtained in step 1), and the temperature in the reactor is controlled to be 65°C. According to the stirring speed of 75r / min, the stirring reaction is 30min, and the reaction ends PH value is 4.2, obtains the slurry containing ammonium dihydrogen phosphate product;

[0049] (3) Cyclic crystallization and filtration: place the slurry containing ammonium dihydrogen phosphate obtained in step 2) in a cooling crystallizer to cool down to a temperature of 3...

Embodiment 2

[0055] A production method for preparing ammonium dihydrogen phosphate by-product Astragalus special fertilizer, comprising the following steps:

[0056] (1) Preparation and mixing of raw materials: Put phosphoric acid and urea in a stirred reactor at a molar ratio of 1.7:1, at a temperature of 111°C, and control the stirring speed of the stirred tank at 205r / min to stir and mix for 1.4 hours to obtain an intermediate slurry;

[0057] (2) Preparation of ammonium dihydrogen phosphate: pass ammonia gas into the intermediate slurry obtained in step 1), and control the temperature in the reactor to 75° C., according to the stirring speed of 65 r / min, stirring for 30 minutes, and the end of the reaction PH value is 4.4, obtains the slurry containing ammonium dihydrogen phosphate product;

[0058] (3) Cyclic crystallization and filtration: place the slurry containing ammonium dihydrogen phosphate obtained in step 2) in a cooling crystallizer to cool down to a temperature of 28°C wi...

Embodiment 3

[0064] A production method for preparing ammonium dihydrogen phosphate by-product Astragalus special fertilizer, comprising the following steps:

[0065] (1) Preparation and mixing of raw materials: Put phosphoric acid and urea in a stirred reactor at a molar ratio of 1.65:1, at a temperature of 105°C, and control the stirring speed of the stirred tank at 185r / min to stir and mix for 1.2 hours to obtain an intermediate slurry;

[0066] (2) Preparation of ammonium dihydrogen phosphate: Ammonia gas is passed into the intermediate slurry obtained in step 1), and the temperature in the reactor is controlled to be 70°C. According to the stirring speed of 70r / min, the stirring reaction is 30min, and the reaction ends PH value is 4.3, obtains the slurry containing ammonium dihydrogen phosphate product;

[0067] (3) Cyclic crystallization and filtration: place the slurry containing ammonium dihydrogen phosphate obtained in step 2) in a cooling crystallizer to cool down to a temperatu...

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Abstract

The invention relates to the technical field of chemical engineering, and particularly relates to a production method for preparing ammonium dihydrogen phosphate with a special astragalus membranaceus fertilizer as a byproduct. Through analysis on requirements on nutritional elements in the astragalus membranaceus growth process, analysis and realization of fertilization conditions of traditional astragalus membranaceus planting, research and discussion of the absorption conditions of crops on nitrogen, phosphorus and potassium, and analysis by combining with the defects in the preparation process of an ammonium dihydrogen phosphate product, a production process of the special fertilizer for astragalus membranaceus is combined with a preparation process of the ammonium dihydrogen phosphate product, so that the preparation process of the ammonium dihydrogen phosphate product and the preparation process of the special fertilizer for the astragalus membranaceus are complementary; production of the special fertilizer for the astragalus membranaceus is carried out by using liquid waste generated in the preparation process of the ammonium dihydrogen phosphate product; the added value of the product in the preparation process of the ammonium dihydrogen phosphate product is increased; the discharge of the liquid waste is lowered; and meanwhile, waste of nitrogen and phosphorus resources also can be avoided by the unnecessary deep crystal ammonium dihydrogen phosphate product in the ammonium dihydrogen phosphate process.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a production method for preparing ammonium dihydrogen phosphate by-product astragalus special fertilizer. Background technique [0002] Astragalus is a leguminous plant, and its root is a well-known nourishing traditional Chinese medicine in my country. Modern pharmacological research shows that Astragalus has the functions of regulating immunity, anti-aging and anti-stress, anti-myocardial ischemia, anti-nephritis, anti-hepatitis and anti-osteoporosis. At present, among the cultivation techniques of Astragalus membranaceus, there are few researches on special fertilizers for Astragalus membranaceus, but fertilizer is the most critical factor for high-yield and high-quality cultivation techniques of Astragalus membranaceus. However, in the prior art, there are few research techniques for special fertilizers for Astragalus, and they are all prepared by mixing traditional ...

Claims

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Application Information

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IPC IPC(8): C01B25/28C05G1/06
Inventor 赵先明高贵龙廖吉星陈肖虎石秀明薛涛朱飞武赵伟毅曾舒
Owner GUIZHOU KAILIN GRP CO LTD
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