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Preparation method of uniform sodium-doped ammonium paratungstate and/or yellow tungsten oxide

A technology of sodium ammonium paratungstate and ammonium paratungstate, which is applied in the field of tungsten smelting, can solve the problems of uneven particle growth, influence, and uneven distribution of sodium, and achieve uniform distribution of sodium elements, simple process control, and less doping procedures.

Inactive Publication Date: 2015-03-25
CHONGYI ZHANGYUAN TUNGSTEN +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims at the existing doping sodium salt process, the distribution of sodium is uneven, resulting in uneven particle growth, affecting subsequent products and the current sodium-containing WO 3 Due to the shortcomings of the production method, a preparation method of uniform sodium-doped APT and yellow tungsten with a simple process is proposed to solve the defects of the existing process and improve the performance of the powder product.

Method used

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  • Preparation method of uniform sodium-doped ammonium paratungstate and/or yellow tungsten oxide
  • Preparation method of uniform sodium-doped ammonium paratungstate and/or yellow tungsten oxide
  • Preparation method of uniform sodium-doped ammonium paratungstate and/or yellow tungsten oxide

Examples

Experimental program
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Effect test

Embodiment 1

[0027] Ammonium tungstate feed solution produced by alkali decomposition of tungsten concentrate through ion exchange, molybdenum removal and other processes, WO 3 The concentration is 264.80 g / L, Na + The concentration is 20 ppm. Take 189.0 mL of the feed solution in a polytetrafluoroethylene beaker, press Na / WO 3 Add 0.3672 g NaHCO to 0.20% by mass 3 , Evaporated and crystallized to obtain sodium-containing APT powder. Other process conditions are: stirring speed 50 r / min, crystallization temperature 100°C, crystallization endpoint pH=6.7, cooling to 20°C.

[0028] The results of elemental analysis by electron microscope (SEM) and energy dispersive spectrometer (EDS) in this example are shown in figure 2 .

Embodiment 2

[0030] Ammonium tungstate feed solution produced by alkali decomposition of tungsten concentrate through ion exchange, molybdenum removal and other processes, WO 3 The concentration is 208.33 g / L, Na + The concentration is 14 ppm. Take 240.0 mL of the feed solution in a polytetrafluoroethylene beaker, press Na / WO 3 Add 0.2183 g NaOH to 0.25% by mass, evaporate and crystallize to obtain sodium-containing APT powder. Other processing conditions are with example 1.

[0031] Result is comparable with example 1, can refer to example 1.

Embodiment 3

[0033] Ammonium tungstate feed solution produced by alkali decomposition of tungsten concentrate through ion exchange, molybdenum removal and other processes, WO 3 Concentration 285.57g / L, Na + The concentration is 32 ppm. Take 500.0 mL of the feed solution in a polytetrafluoroethylene beaker, press Na / WO 3 Add 1.5426 g Na at 0.15% by mass 2 WO 4 , Evaporated and crystallized to obtain sodium-containing APT powder. Other process conditions are: stirring speed 150 r / min, crystallization temperature 90°C, crystallization endpoint pH=7.0, cooling to 35°C.

[0034] Result is comparable with example 1, can refer to example 1.

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Abstract

The invention belongs to the technical field of tungsten smelting and in particular relates to a preparation method of uniform sodium-doped ammonium paratungstate and / or yellow tungsten oxide, which aims to solve the defect that the subsequent products are influenced by uneven growth of particles caused by the uneven distribution of sodium in the existing sodium doping process and the defects of the exiting sodium-containing WO3 production method. According to the preparation method of uniform sodium-doped ammonium paratungstate and / or yellow tungsten oxide, the sodium is doped under the strong base condition; the ammonia concentration does not need to be adjusted; the content of impurity elements in the raw material which is an ammonium tungstate solution is low; no impurity harmful to the subsequent processes is introduced into the doping raw material; the solution does not need to be washed by other substances, is directly extracted when the solution arrives at a crystallization final point, and does not need to be washed by water; the product is uniformly doped with sodium. The crystallization mother solution is small in quantity and easy to recycle and use; the doping process is few and simple to operate; sodium-containing compounds suitable for the sodium-doping process are various in types; the sodium-doped APT and yellow tungsten oxide powder prepared by the method are high in Fsss particle size; the sodium elements are uniformly distributed; the crystalline form is complete.

Description

technical field [0001] The invention belongs to the technical field of tungsten smelting, and in particular relates to a method for preparing uniformly sodium-doped ammonium paratungstate (APT) and / or yellow tungsten. Background technique [0002] Coarse-grained cemented carbide has a series of advantages such as good toughness, high hardness, high thermal conductivity, and good red hardness. It is widely used in mining tools, stamping dies, oil drilling, hard surface materials and other fields. The main process of preparing coarse-grained cemented carbide in domestic production is to add alkali metal to APT or tungsten trioxide, prepare coarse-grained tungsten (W) powder after hydrogen reduction, and obtain coarse-grained WC powder through high-temperature carbonization, and then wet grinding , forming, and sintering processes to prepare coarse-grained cemented carbide. [0003] At present, the conventional method of doping alkali metal in production is the mechanical mixi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G41/00C01G41/02
CPCC01G41/006C01G41/02C01P2004/01
Inventor 赵立夫黄燕万林生
Owner CHONGYI ZHANGYUAN TUNGSTEN
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