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Multifunctional polypropylene material

A polypropylene material and polypropylene technology, applied in the field of multi-performance polypropylene materials, can solve the problems of expensive ultraviolet absorbers and hindered amine light stabilizers, can not meet the actual safe use, degradation and other side reactions, and reach a wide range of markets The effect of application prospect, easy processing and cheap materials

Inactive Publication Date: 2015-03-25
QINGDAO BOYANDA IND TECH RES INST GENERAL PARTNERSHIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The currently disclosed halogen-based flame-retardant and weather-resistant technologies all use ultraviolet absorbers and / or hindered amine light stabilizers, and have not yet solved the problem of using only carbon black as a weather-resistant modifier, that is, high carbon black content (>1wt%) ), how to prepare flame-retardant and weather-resistant polypropylene; and there are the following common deficiencies, which affect its use in various fields:
[0005] ① Ultraviolet absorbers and hindered amine light stabilizers are organic polar small molecules, which have problems of saturation and volatilization with non-polar polypropylene resins, and under long-term ultraviolet rays, there are side reactions such as degradation and even failure problems.
[0006] ② Commonly used hindered amine light stabilizers will react with brominated flame retardants due to their high alkalinity, and there is a problem of confrontation between weathering agents and flame retardants
[0007] ③ Compared with carbon black, UV absorbers and hindered amine light stabilizers are much more expensive
After searching, it is found that although there are some high temperature resistant and non-slip polypropylene materials, they lack antistatic function and cannot meet the actual safe use, causing potential accident hazards

Method used

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Examples

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Embodiment Construction

[0033] A multi-performance polypropylene material, characterized in that the composition of the raw materials is as follows in terms of weight percentage: 75-90% of polypropylene with an ethylene content of less than 1% and a melt flow rate of 50-100g / 10min; : sepiolite powder 5-10%; main flame retardant: TTBNP 1-2%; synergistic flame retardant with particle size <10μm: antimony trioxide 0.2-0.5%; channel carbon with particle size 15-25nm Black: 1.5-2.5%; Talc powder: 5-6%; Chain breaker: 3,4-dimethyl-3,4-diphenylhexane 0.2-0.5%; Foaming agent: 5-phenyl tetra Azole 0.2-0.5%; Static Agent: Ethylene Oxide 2-3%; Antioxidant: Sodium Phosphite 0.2-0.3%; Heat Stabilizer DSTP0.2-0.3%; Penetrant: Sodium α-Alkenyl Sulfonate 0.2-0.3%; Dispersant: sodium lignosulfonate 0.2-0.3%.

[0034] The component contents of the formulations of Examples 1-9 and two comparative examples of the polypropylene composite material are shown in Table 1.

[0035] The component content table of the formula...

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Abstract

The invention discloses a multifunctional polypropylene material which is characterized by comprising the following raw materials in percentage by weight: 75-90% of polypropylene, 5-10% of hormites clay meerschaum powder, 1-2% of main flame retardant TTBNP, 0.2-0.5% of synergistic flame retardant antimony trioxide, 1.5-2.5% of carbon black, 5-6% of talcum powder, 0.2-0.5% of chain-cutting agent 3,4-dimethyl-3,4-diphenylhexane, 0.2-0.5% of foaming agent 5-phenyltetrazole, 2-3% of electrostatic agent epoxyethane, 0.2-0.3% of antioxidant sodium phosphite, 0.2-0.3% of heat stabilizer DSTP, 0.2-0.3% of penetrant sodium alpha-alkenyl sulfonate and 0.2-0.3% of dispersing agent sodium lignosulfonate. The polypropylene material produced by the invention has excellent weather resistance, flame retardancy, electrical resistance, temperature impact resistance and mechanical property, and is cheap in the materials, simple and easy to process and suitable for industrial production.

Description

technical field [0001] The invention relates to the technical field of composite materials, in particular to a multi-performance polypropylene material. Background technique [0002] Polypropylene has excellent mechanical properties, good heat resistance, high chemical stability, excellent electrical insulation, and good processability. It is a general-purpose plastic with excellent comprehensive properties. However, due to its saturated hydrocarbon structure and the existence of tertiary carbon atoms, polypropylene is extremely flammable and has poor weather resistance. [0003] Halogenated flame retardants are the most effective flame retardant additives for polyolefin materials with less addition, high flame retardant efficiency, and minimal impact on polymer properties. The commonly used varieties mainly include decabromodiphenylethane, hexabromocyclic Dodecane, octabromoether, octabromo-S ether, tris (2,3-dibromopropyl) isocyanate (TBC), tris (2,2-dibromomethyl-3-bromo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08K13/02C08K5/02C08K5/11C08K5/3417C08K3/22C08K3/04C08K3/34C08K5/01C08K5/1515C08J9/10
CPCC08L23/12C08J9/108C08J2203/04C08J2323/12C08K2201/003C08K2201/017C08L2201/02C08L2201/04C08L2201/08
Inventor 于桂菊
Owner QINGDAO BOYANDA IND TECH RES INST GENERAL PARTNERSHIP
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