The invention discloses a preparation method of a
perylene-3, 4, 9, 10-tetracarboxylic dianhydride grafted modified
polypropylene film, and the method comprises the following steps: weighing a first predetermined
mass fraction of
perylene-3, 4, 9, 10-tetracarboxylic dianhydride, and dissolving the
perylene-3, 4, 9, 10-tetracarboxylic dianhydride in a non-polar
organic solvent under a continuous first stirring condition to obtain a long-term stable PPDI solution at
room temperature; weighing a second predetermined
mass fraction of 2-methylallylamine, and dissolving the 2-methylallylamine in the PPDI solution under a continuous second stirring condition to react to obtain a PPDI alkenylation solution; weighing the alkenylated PPDI
powder, an initiator and
polypropylene in a third predetermined
mass fraction, and dissolving in a non-polar
organic solvent; adding a predetermined amount of
acetone solution into the perylene-3, 4, 9, 10-tetracarboxylic dianhydride grafted
polypropylene solution under the condition of ice-water bath to separate out
solid product crystals; and carrying out
hot pressing on the powdery
solid PP-g-PPDI to obtain a film-shaped sample so as to obtain the N-type
molecular semiconductor grafted modified polypropylene film.