Periclase-pleonaste and hercynite/forsterite composite brick

A technology of iron-aluminum spinel and forsterite, which is applied in the field of refractory materials, can solve the problems that the thermal conductivity of materials cannot be effectively reduced, the energy-saving effect of the firing zone is not significant, and the heat insulation effect of composite bricks is poor, so as to solve the problems of high-strength With low thermal conductivity, increase the strength/thermal conductivity ratio, and the effect of being easy to stick to the kiln skin

Active Publication Date: 2015-06-24
河南瑞泰耐火材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the refractory bricks used in the firing zone of cement kilns are mainly periclase-magnesia-iron/aluminum-spinel bricks (magnesia-iron bricks for short), and their thermal conductivity is about 3.0W/mk; there are still a small amount of use in the transition zone. The thermal conductivity of magnesia-magnesia-alumina spinel bricks (referred to as magnesia-alumina bricks) is about 3.5W/mk; from the perspective of thermal conductivity, whether it is magnesia-iron bricks or magnesia-alumina bricks, the thermal conductivity is relatively high, and the actual use The energy saving effect in the process is not significant
The application number is 201210183879.9, and the patent named "magnesia-iron spinel thermal insulation composite brick" discloses a magnesia-iron spinel thermal insulation composite brick. The composite brick mainly uses high-purity magnesia/fused magnesia and synthetic magnesia-iron Aluminum spine...

Method used

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  • Periclase-pleonaste and hercynite/forsterite composite brick

Examples

Experimental program
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Effect test

Embodiment 1~6

[0032] Table 2 The raw material composition of the working layer and the thermal insulation layer of the periclase-mafic iron aluminum spinel / forsterite composite bricks in Examples 1 to 6

[0033]

[0034] Note: 1) The concentration of the magnesium lignosulfonate solution described in Examples 1 and 2 is 1.05g / cm 3 , The chemical composition of the magnesium iron sand is: MgO 85wt%, Fe 2 O 3 14wt%, the balance being impurities, the medium-weight synthetic forsterite sand refers to medium-heavy synthetic forsterite sand; 2) The concentration of the magnesium lignosulfonate solution in Example 3 is 1.25 g / cm 3 , The chemical composition of the magnesite sand is: MgO 90wt%, Fe 2 O 3 8wt%, the balance is impurities. The medium-weight synthetic forsterite sand refers to medium-light synthetic forsterite sand; 3) The concentration of the magnesium lignosulfonate solution in Examples 4 and 5 is 1.15 g / cm 3 , The chemical composition of the magnesium iron sand is: MgO 85wt%, Fe 2 O 3 10wt...

Embodiment 7

[0036] One of the preparation methods of periclase-mafic iron aluminum spinel / forsterite composite bricks described in any one of the foregoing embodiments 1 to 6 includes the following steps: (1) Preparation of working layer brick materials: press The raw material composition of the working layer prepares the raw materials, after they are evenly mixed, the water reducing agent and the binder are added, and the wet mill is used for mixing until uniform; (2) Preparation of insulation layer brick materials: prepare each raw material according to the raw material composition of the insulation layer After mixing uniformly, add polystyrene balls and binder, and mix with wet mill until uniform; (3) Forming and firing: divide the brick mold into two parts, the hot end and the cold end, with a partition plate , Add the working layer to make bricks at the hot end, add the insulation layer to make bricks at the cold end, then pull out the partition plate, press the bricks into bricks with...

Embodiment 8

[0038] The second preparation method of the periclase-mafic iron aluminum spinel / forsterite composite brick described in any one of the foregoing Examples 1 to 6 is basically the same as that of Example 7, and the difference is that the brick is made Afterwards, the bricks were dried at 120°C for 20 hours in a drying kiln, and then fired at 1500°C for 8 hours before being discharged from the kiln.

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Abstract

The invention discloses a periclase-pleonaste and hercynite/forsterite composite brick prepared by compounding a working layer and a heat insulation layer, wherein the working layer is prepared from magnesium-iron sand, hercynite sand and fused magnesite which serve as main raw materials; the heat insulation layer is prepared from medium-heavy synthetic olivine sand, medium-light synthetic boltonite sand, magnesite particles, fine magnesia powder and rice hull ash which serve as main raw materials; and the periclase-pleonaste and hercynite/forsterite composite brick is prepared through the steps of proportioning; mixing; molding; drying; sintering and the like. The working layer of the composite brick disclosed by the invention is strong in erosion resistance, good in thermal shock resistance and low in heat conductivity coefficient and is easily adhered to a kiln coating; the heat insulation layer is favorable in high-temperature volume stability, relatively high in mechanical strength and relatively low in heat conductivity coefficient. Therefore, the composite brick can be used for a high-temperature zone of a rotary cement kiln and is long in service life and capable of remarkably reducing the heat loss of a kiln body and has favorable energy-saving and emission reduction effects.

Description

Technical field [0001] The invention relates to the field of refractory materials, in particular to a periclase-mafic aluminum spinel / forsterite composite brick. Background technique [0002] The cement production industry is a famous energy consumer and a major carbon dioxide emitter. At present, my country is planning to develop the second generation of new dry-process cement production technology to reduce the heat consumption of the clinker production process from 700-750kcal / kg to 650kcal / kg, that is, to reduce the heat consumption by 50-100kcal / kg. In the cement production process, the heat consumption caused by surface heat dissipation accounts for about 10% of the total production process heat consumption, which is 70kcal / kg; and in the surface heat dissipation heat consumption, the heat consumption caused by kiln body heat dissipation accounts for about 50%. Heater and decomposition furnace account for about 35%, and tertiary air duct and cooler account for about 15%. ...

Claims

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Application Information

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IPC IPC(8): C04B35/66C04B35/622
Inventor 刘锡俊王杰曾翟耀杰徐琳琳刘昭李顺清刘晓磊叶亚红胡世平
Owner 河南瑞泰耐火材料科技有限公司
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