High-strength carbon fiber enhanced boron nitride ceramic matrix composite and preparation method thereof

A composite material and carbon fiber technology, applied in the field of ceramic production, can solve the problems of poor sintering performance, reduced high temperature resistance of boron nitride ceramics, thermal conductivity, thermal shock resistance and dielectric, low production efficiency, etc. Improved sintering performance and small expansion coefficient

Inactive Publication Date: 2015-07-29
安徽省含山瓷业股份有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although hexagonal boron nitride has such excellent properties and great application potential, it is a covalent bond compound with low self-diffusion coefficient at high temperature, so its sintering performance is poor.
At present, boron nitride ceramics are mainly prepared by hot-pressing sintering method promoted by sintering aids at home and abroad, but hot-pressing sintering equipment is

Method used

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Embodiment Construction

[0014] specific implementation plan

[0015] The present invention will be described in detail below through specific examples.

[0016] A high-strength carbon fiber reinforced boron nitride ceramic matrix composite material and a preparation method thereof, which are made of the following raw materials in parts by weight (kg): boron nitride 70, iridium trioxide 6, hafnium carbide 7, manganese powder 9, modified high Elastic carbon fiber 12, ammonium persulfate 0.03, acrylic acid 6, dimethylaminopropylamine 0.4, light calcium carbonate 10, chitosan 3, ethanol 30, deionized water 60;

[0017] The preparation method of the modified high-strength carbon fiber is as follows: soak the high-strength carbon fiber in nitric acid for 2 hours, rinse it with distilled water for 3 times after taking it out, and dry it for later use; mix 15 parts by weight of tetrabutyl titanate with 180 parts by weight of ethanol Add to a flask with a magnetic stirrer, fully mix 3 parts by weight of...

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Abstract

The invention discloses high-strength carbon fiber enhanced boron nitride ceramic matrix composite and a preparation method thereof. The high-strength carbon fiber enhanced boron nitride ceramic matrix composite is characterized by being prepared from raw materials in parts by weight as follows: 60-70 parts of boron nitride, 5-8 parts of iridium trioxide, 5-8 parts of hafnium carbide, 8-12 parts of manganese powder, 10-14 parts of modified high-elastic carbon fiber, 0.03-0.05 parts of ammonium persulfate, 5-7 parts of acrylic acid, 0.3-0.5 parts of dimethylaminopropylamine, 10-12 parts of light calcium carbonate, 2-3 parts of chitosan, 20-30 parts of ethanol and 40-60 parts of deionized water. With modified high-strength carbon fiber as an enhancing phase, the high-strength carbon fiber enhanced boron nitride ceramic matrix composite has the advantages of excellent oxidation resistance, improvement of ceramic toughness and strength, high-temperature and low-temperature resistance, good thermal conductivity and small expansion coefficient; the surface of a blank body is coated with the added iridium trioxide and hafnium carbide, and accordingly, the sintering performance is improved.

Description

technical field [0001] The invention relates to a high-strength carbon fiber reinforced boron nitride ceramic-based composite material and a preparation method thereof, belonging to the technical field of ceramic production. Background technique [0002] Fiber-reinforced ceramic matrix composites are a young member of ceramic matrix composites. Fiber-reinforced ceramic matrix composites have the advantages of high temperature resistance, wear resistance, high temperature creep resistance, low thermal conductivity, low thermal expansion coefficient, and good chemical corrosion resistance. , is widely used in the working conditions where resin matrix, metal matrix and even some ceramic matrix composites cannot meet the performance requirements. It is one of the most active research fields in composite materials at present. High-elastic carbon fiber has the advantages of high strength, high elastic modulus, low density, high specific strength, ultra-high and low temperature re...

Claims

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Application Information

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IPC IPC(8): C04B35/80C04B35/583C04B35/622
Inventor 舒小山章建武宫平汤兴友
Owner 安徽省含山瓷业股份有限公司
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