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Alumina composite oxide and preparation method thereof

A composite oxide and alumina technology, applied in chemical instruments and methods, chemical/physical processes, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problem of high cost of material preparation, complicated preparation process, and environmental pollution and other problems, to achieve the effects of preventing hard agglomeration during drying, easy control of the process, and simple production process

Active Publication Date: 2015-10-21
CHINA COAL TECH ENG GRP CHONGQING RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The research on modified alumina coating materials mainly focuses on the doping of rare earth metals and alkaline earth metals to improve the high temperature stability of alumina, but under the increasingly stringent emission limit requirements, higher performance modified oxides are required. Aluminum coating materials are used to meet the use environment of the catalyst. In the current research, the preparation methods used to improve the performance of the modified alumina use surfactants to help improve the performance of the alumina material, resulting in another It brings pollution to the environment, so there are defects such as high material preparation cost, complicated preparation process, and serious environmental pollution.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The aluminum oxide composite oxide of the present embodiment, the chemical composition of the aluminum oxide composite oxide includes by weight:

[0022] 7 parts of cerium-zirconium mixture, 85 parts of aluminum oxide, 3 parts of lanthanum oxide and 5 parts of silicon oxide; its general chemical formula is: (Ce 0.85 Zr 0.15 ) 7 Si 5 La 3 Al 85 o 2 .

[0023] Its preparation method is:

[0024] 620.4g of Al(NO 3 ) 3 9H 2 O, 7.14gLa(NO 3 ) 3 ·6H 2 O, 15.68gCe(NO 3 ) 3 ·6H 2 O, 1.64gZr(NO 3 ) 4 ·5H 2 O. Add 17.8ml of tetraethyl orthosilicate to 800ml of purified water, add 7.8ml of hydrogen peroxide, stir for 3 hours, then use a constant flow pump at 50ml / min to add 3.3mol / L of ammonia water and ammonium bicarbonate alkali solution, The final pH is 10, and the precipitated slurry is obtained. After stirring for 2 hours, it is statically sealed overnight, aged at a constant temperature of 98°C for 3 hours, filtered and dried in microwave at 120°C, and the...

Embodiment 2

[0026] The aluminum oxide composite oxide of the present embodiment, the chemical composition of the aluminum oxide composite oxide includes by weight:

[0027] 8 parts of cerium-zirconium mixture, 85 parts of aluminum oxide, 3 parts of lanthanum oxide and 5 parts of nickel oxide; its general chemical formula is: (Ce 0.85 Zr 0.15 ) 8 Ni 4 La 3 Al 85 o 2 .

[0028] Its preparation method is:

[0029] 620.4g of Al(NO 3 ) 3 9H 2 O, 7.14gLa(NO 3 ) 3 ·6H 2 O, 15.68gCe(NO 3 ) 3 ·6H 2 O, 1.64gZr(NO 3 ) 4 ·5H 2 O, 15.7gNi(NO 3 ) 2 ·6H 2 O was added to 1000ml of purified water, 7.8ml of hydrogen peroxide was added, and after stirring for 3 hours, a constant flow pump was used at 50ml / min to add 3.8mol / L of ammonia and ammonium bicarbonate alkali solution, and the final pH was 9 to obtain a precipitated slurry After stirring for 2 hours, it was sealed overnight, aged at a constant temperature of 105°C for 3 hours, filtered and dried at 80°C by microwave, and the po...

Embodiment 3

[0031] The aluminum oxide composite oxide of the present embodiment, the chemical composition of the aluminum oxide composite oxide includes by weight:

[0032] 8 parts of cerium-zirconium mixture, 87 parts of aluminum oxide, 3 parts of lanthanum oxide and 2 parts of iron oxide; its general chemical formula is: (Ce 0.85 Zr 0.15 ) 8 Fe 2 La 3 Al 87 o 2 .

[0033] Its preparation method is:

[0034] 635g of Al(NO 3 ) 3 9H 2 O, 7.14gLa(NO 3 )3 ·6H 2 O, 18gCe(NO 3 ) 3 ·6H 2 O, 1.87gZr(NO 3 ) 4 ·5H 2 O, 10.1gFe(NO 3 ) 3 9H 2 O was added to 1000ml of purified water, and 9ml of hydrogen peroxide was added. After stirring for 3 hours, use a constant flow pump at 50ml / min to add 3mol / L of ammonia and ammonium bicarbonate alkali solution. The final pH was 9.5, and the precipitated slurry was obtained and stirred. After 2 hours, it was sealed overnight, aged at a constant temperature of 105°C for 3 hours, filtered and dried in a microwave oven at 140°C, and the powde...

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Abstract

The invention discloses an alumina composite oxide and a preparation method thereof. The alumina composite oxide comprises, by weight, the chemical components of 1 to 15 parts of cerium-zirconium mixture, 70 to 95 parts of alumina, 3 parts of lanthana and 1 to 15 parts oxide of metallic elements in the third period and the fourth period of periodic table of chemical element except aluminum. The high temperature and aging resisting performance of the alumina is improved greatly by adulterating rear earth and oxide of transition metal. According to the preparation method of the alumina composite oxide, the alumina composite oxide is effectively prevented from drying and hard aggregating through an aging reaction and microwave drying under the condition that a surface active agent is not used, so that the dispersity of powder particles is improved; no organic waste gas is generated in the calcinating process, being environmentally friendly is achieved, and grinding is not needed for a finished product after calcinating is conducted; the specific area of the produced material is large by controlling proper temperature in the calcinating process; calcinating is conducted for 4 to 8 h at the temperature of 700 to 850 DEG C, the specific area is 230 to 260 m2 / g, and the aging specific area is 100 to 130 m2 / g after aging is conducted for 10 h at the temperature of 1000 DEG C; the production technology is simple, controlling the process is easy, the price of raw materials is cheap, the production cost is low, and industrial production is easy to achieve.

Description

technical field [0001] The invention relates to a composite oxide material, in particular to a coating material and redox type catalyst carrier which can be widely used in various types of exhaust gas purification catalysts, especially for tail gas treatment catalyst coatings fueled by gasoline, diesel, LPG and natural gas. Alumina composite oxide for layer material application and preparation method thereof. Background technique [0002] With the development of social industry, fuel machinery has replaced manual labor and greatly improved work efficiency, but the harmful gases emitted by fuel machinery exhaust and industrial organic waste gas are also polluting the atmospheric environment on which human beings live, especially in recent years. , the harm of exhaust emissions to human health has been paid more and more attention by human beings. In order to reduce the harm of exhaust emissions to humans, humans have invented catalytic converters that can convert harmful exh...

Claims

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Application Information

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IPC IPC(8): B01J23/10B01J23/83B01J23/34
Inventor 毛小波刘志敏张留明曾少华谭凯蒋波张海鹏郑芳菲周妮廖德林吴奇徽
Owner CHINA COAL TECH ENG GRP CHONGQING RES INST
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