Alumina composite oxide and preparation method thereof
A composite oxide and alumina technology, applied in chemical instruments and methods, chemical/physical processes, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problem of high cost of material preparation, complicated preparation process, and environmental pollution and other problems, to achieve the effects of preventing hard agglomeration during drying, easy control of the process, and simple production process
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Embodiment 1
[0021] The aluminum oxide composite oxide of the present embodiment, the chemical composition of the aluminum oxide composite oxide includes by weight:
[0022] 7 parts of cerium-zirconium mixture, 85 parts of aluminum oxide, 3 parts of lanthanum oxide and 5 parts of silicon oxide; its general chemical formula is: (Ce 0.85 Zr 0.15 ) 7 Si 5 La 3 Al 85 o 2 .
[0023] Its preparation method is:
[0024] 620.4g of Al(NO 3 ) 3 9H 2 O, 7.14gLa(NO 3 ) 3 ·6H 2 O, 15.68gCe(NO 3 ) 3 ·6H 2 O, 1.64gZr(NO 3 ) 4 ·5H 2 O. Add 17.8ml of tetraethyl orthosilicate to 800ml of purified water, add 7.8ml of hydrogen peroxide, stir for 3 hours, then use a constant flow pump at 50ml / min to add 3.3mol / L of ammonia water and ammonium bicarbonate alkali solution, The final pH is 10, and the precipitated slurry is obtained. After stirring for 2 hours, it is statically sealed overnight, aged at a constant temperature of 98°C for 3 hours, filtered and dried in microwave at 120°C, and the...
Embodiment 2
[0026] The aluminum oxide composite oxide of the present embodiment, the chemical composition of the aluminum oxide composite oxide includes by weight:
[0027] 8 parts of cerium-zirconium mixture, 85 parts of aluminum oxide, 3 parts of lanthanum oxide and 5 parts of nickel oxide; its general chemical formula is: (Ce 0.85 Zr 0.15 ) 8 Ni 4 La 3 Al 85 o 2 .
[0028] Its preparation method is:
[0029] 620.4g of Al(NO 3 ) 3 9H 2 O, 7.14gLa(NO 3 ) 3 ·6H 2 O, 15.68gCe(NO 3 ) 3 ·6H 2 O, 1.64gZr(NO 3 ) 4 ·5H 2 O, 15.7gNi(NO 3 ) 2 ·6H 2 O was added to 1000ml of purified water, 7.8ml of hydrogen peroxide was added, and after stirring for 3 hours, a constant flow pump was used at 50ml / min to add 3.8mol / L of ammonia and ammonium bicarbonate alkali solution, and the final pH was 9 to obtain a precipitated slurry After stirring for 2 hours, it was sealed overnight, aged at a constant temperature of 105°C for 3 hours, filtered and dried at 80°C by microwave, and the po...
Embodiment 3
[0031] The aluminum oxide composite oxide of the present embodiment, the chemical composition of the aluminum oxide composite oxide includes by weight:
[0032] 8 parts of cerium-zirconium mixture, 87 parts of aluminum oxide, 3 parts of lanthanum oxide and 2 parts of iron oxide; its general chemical formula is: (Ce 0.85 Zr 0.15 ) 8 Fe 2 La 3 Al 87 o 2 .
[0033] Its preparation method is:
[0034] 635g of Al(NO 3 ) 3 9H 2 O, 7.14gLa(NO 3 )3 ·6H 2 O, 18gCe(NO 3 ) 3 ·6H 2 O, 1.87gZr(NO 3 ) 4 ·5H 2 O, 10.1gFe(NO 3 ) 3 9H 2 O was added to 1000ml of purified water, and 9ml of hydrogen peroxide was added. After stirring for 3 hours, use a constant flow pump at 50ml / min to add 3mol / L of ammonia and ammonium bicarbonate alkali solution. The final pH was 9.5, and the precipitated slurry was obtained and stirred. After 2 hours, it was sealed overnight, aged at a constant temperature of 105°C for 3 hours, filtered and dried in a microwave oven at 140°C, and the powde...
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