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A kind of splicable perovskite solar cell and its preparation method

A solar cell and perovskite technology, applied in the field of solar cells, can solve the problems of low photoelectric conversion efficiency of flexible devices, achieve good flexibility and structural stability, and easy series connection

Active Publication Date: 2017-12-22
YANTAI TAYHO ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[3] At present, flexible perovskite solar cells have also been successfully prepared, but the photoelectric conversion efficiency of flexible devices is generally lower than that of rigid substrates. [4,5]

Method used

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  • A kind of splicable perovskite solar cell and its preparation method
  • A kind of splicable perovskite solar cell and its preparation method
  • A kind of splicable perovskite solar cell and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Preparation of aligned carbon nanotube arrays: Spinnable multi-walled carbon nanotube arrays were synthesized by chemical vapor deposition. Catalyst using Fe (2 nm) / Al 2 o 3 (10 nm), the carbon source is ethylene, the gas phase carrier is a mixed gas of argon and hydrogen, and a spinnable carbon nanotube array is obtained by chemical vapor deposition.

[0027] (2) Preparation of self-healing polymer film: 20 g of polydiacid and 7 g of diethylenetriamine were heated and stirred at 160°C for 24 hours under an argon atmosphere. The product was dissolved in 100 mL of chloroform, washed with 100 mL of deionized water and 50 mL of methanol, respectively, and the solvent was removed by rotary evaporation to obtain a self-healing polymer.

[0028] Dissolve 1 g of self-healing polymer in 10 mL of chloroform to obtain a homogeneous solution, add this solution dropwise on a clean glass slide, evaporate the solvent at room temperature for 2 hours, dry at 80°C for 20 minutes...

Embodiment 2

[0034] (1) Preparation of aligned carbon nanotube arrays: Spinnable multi-walled carbon nanotube arrays were synthesized by chemical vapor deposition. Catalyst using Fe (1.5 nm) / Al 2 o 3 (11 nm), the carbon source is ethylene, the gas phase carrier is a mixed gas of argon and hydrogen, and a spinnable carbon nanotube array is obtained by chemical vapor deposition.

[0035] (2) Preparation of self-healing polymer film: 10 g of polydiacid and 4 g of diethylenetriamine were heated and stirred at 150°C for 30 hours under an argon atmosphere. The product was dissolved in 50 mL of chloroform, washed with 50 mL of deionized water and 25 mL of methanol, respectively, and the solvent was removed by rotary evaporation to obtain a self-healing polymer.

[0036] Dissolve 0.5 g of self-healing polymer in 5 mL of chloroform to obtain a homogeneous solution, drop this solution onto a clean glass slide, evaporate the solvent at room temperature for 2.5 hours, dry at 75°C for 30 minutes, a...

Embodiment 3

[0041] (1) Preparation of aligned carbon nanotube arrays: Spinnable multi-walled carbon nanotube arrays were synthesized by chemical vapor deposition. Catalyst using Fe (1 nm) / Al 2 o 3 (10 nm), the carbon source is ethylene, the gas phase carrier is a mixed gas of argon and hydrogen, and a spinnable carbon nanotube array is obtained by chemical vapor deposition.

[0042] (2) Preparation of self-healing polymer film: 5 g of polydiacid and 3 g of diethylenetriamine were heated and stirred at 140°C for 34 hours under an argon atmosphere. The product was dissolved in 30 mL of chloroform, washed with 30 mL of deionized water and 15 mL of methanol, respectively, and the solvent was removed by rotary evaporation to obtain a self-healing polymer.

[0043] Dissolve 0.2 g of self-healing polymer in 3 mL of chloroform to obtain a homogeneous solution, add this solution dropwise on a clean glass slide, evaporate the solvent at room temperature for 3 hours, dry at 70°C for 40 minutes, ...

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Abstract

The invention belongs to the technical field of solar cells, and in particular relates to a splicable perovskite solar cell and a preparation method thereof. The invention is based on a splicable electrode prepared by aligned carbon nanotubes and self-repairing polymers, and prepares a splicable perovskite solar cell with good flexibility and photoelectric conversion efficiency. The self-healing polymer can form a strong hydrogen bond with the indium tin oxide electrode, so that the aligned carbon nanotubes and the indium tin oxide electrode are in contact and spliced ​​together firmly, realizing a simple series connection without any wires or circuits . The solar cells obtained after splicing have good flexibility and structural stability, and can be widely used in fields such as flexible devices, wearable devices, and portable energy devices.

Description

technical field [0001] The invention belongs to the technical field of solar cells, and in particular relates to a splicable perovskite solar cell and a preparation method thereof. Background technique [0002] Energy issues are considered to be one of the most important challenges facing human society in the 21st century. In order to alleviate the energy shortage caused by the depletion of fossil energy, renewable energy such as solar energy, wind energy, and tidal energy have received extensive attention and research. Among them, solar energy has become the most promising energy source among renewable energy due to its inexhaustible characteristics. [1] Although people have conducted extensive and in-depth research on various solar cells, in actual use, solar cells must be connected in series through wires or circuits to increase the output voltage, which greatly increases the production cost and complexity, and may safety issues such as short circuits. Especially when...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/44H01L51/00H10K99/00
CPCH10K71/60H10K30/81Y02E10/549Y02P70/50
Inventor 彭慧胜孙浩丘龙斌杨嘉桦
Owner YANTAI TAYHO ADVANCED MATERIALS CO LTD
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