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Anisotropic heat conduction material, and preparation method thereof

A thermally conductive material and anisotropic technology, applied in the field of anisotropic thermally conductive materials and their preparation, can solve the problem of low practicability and applicability of high thermal conductivity resins, it is difficult to ensure the directionality of thermal conductivity of materials, and thin carbon fibers are prone to occur. Coagulation and other problems, to achieve the effect of controlling heat transfer, easy control, and good fluidity

Active Publication Date: 2015-11-11
TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the process of adding high thermal conductivity materials to polymer materials, there are many problems, such as agglomeration of additives, uneven dispersion, etc.
The thermal conductivity of the new material obtained by this production method is not strictly anisotropic, and it is even difficult to guarantee the directionality of the thermal conductivity of the obtained material
Taking the addition of carbon fiber into the resin as an example, the fine carbon fiber used as a filler is extremely prone to agglomeration, so it is difficult to disperse the carbon fiber into the resin, resulting in the problem that heat conduction can only be obtained when a large amount of fiber is added. sex improvement effect
The problem caused by carbon fiber mixing as a large mixing ratio is that the melt viscosity of the resin is significantly increased, so injection molding, which is widely used in thermoplastic resins, cannot be performed
The fact that forming can only be performed with a specific forming method constitutes a factor that reduces the practicality and applicability of high thermal conductivity resins

Method used

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  • Anisotropic heat conduction material, and preparation method thereof
  • Anisotropic heat conduction material, and preparation method thereof
  • Anisotropic heat conduction material, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] Use drawing software to design several parallel flow channels in a square frame. The flow channel layout is as follows: figure 1 . The designed flow channels will be filled with liquid metal material with high thermal conductivity. Print the film according to the above design graphics. Then use the photolithography method to use the film obtained in the above steps as a mask to produce a silicon wafer with the flow channel designed above, which is equivalent to duplicating the flow channel designed above on the silicon chip. Place the manufactured silicon wafer with flow channels in a petri dish of appropriate size, and make the side of the silicon wafer with flow channels face up. The pre-prepared liquid polymer polydimethylsiloxane is poured onto the silicon wafer. After the liquid polydimethylsiloxane is solidified, it is peeled off from the silicon wafer, and holes are punched at the entrance and exit of the flow channel, so that the liquid polymer polydimethylsi...

Embodiment 2

[0051] According to different application occasions, change the shape and layout of the flow channel. When it is necessary to control the heat transfer in the axial direction and insulate the heat in the radial direction, different liquid metal runner arrangements are required. Such as Figure 4 As shown, the liquid metal flow channels are arranged in concentric rings, and the axial and tangential thermal conductivity of the film are higher than the radial thermal conductivity, so the axial and radial anisotropic thermal conductivity film can be obtained, which can meet the heat Rapid transmission in the axial and tangential directions, and heat insulation effect in the radial direction. The height of the flow channel is 5mm, the width is 5mm, and it is filled with Ga 67 In 20.5 sn 12.5 , the liquid alloy is formulated at a heating temperature of 240°C.

Embodiment 3

[0053] Prepare as in Example 1. According to different application occasions, change the shape and layout of the flow channel. Such as Figure 5 As shown, the liquid metal flow channel is arranged in such a way that multiple straight lines radiate from one point, and the thermal conductivity in the radial direction shown in the figure is higher than that in other directions, so that the purpose of heat transfer in the radial direction can be realized.

[0054] In this embodiment, the flow channel is 3mm high and 3mm wide, and filled with GaIn 24.5 , The liquid alloy is prepared at a heating temperature of 80°C and poured at room temperature.

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Abstract

The invention discloses an anisotropic heat conduction material. The anisotropic heat conduction material is a composite material of liquid metal materials and a high-molecular polymer, wherein the high-molecular polymer possesses embedded runners, and the runners are filled with the liquid metal materials. According to the preparation method, the anisotropic heat conduction material is obtained via injecting and sealing room temperature liquid metals, including gallium, indium, mercury, sodium, potassium, caesium, or binary alloys and multicomponent alloys thereof, into the high-molecular polymer; anisotropism of heat conductivity of a composite material prepared via adding high thermal conductivity materials into a base material is increased greatly; and heat energy transmission direction can be controlled artificially based on practical requirements. Preparation is convenient; mixing process and mixing results of the high thermal conductivity additives with the high-molecular polymer can be controlled easily; material heat conductivity anisotropy rate range can be adjusted in a relatively range artificially; and the anisotropic heat conduction material possesses significant importance in the fields of micro-fluidic chips, biological medical testing equipment, cryogenic engineering, and electronic integration equipment.

Description

technical field [0001] The invention belongs to the field of heat-conducting materials, and in particular relates to an anisotropic heat-conducting material and a preparation method thereof. Background technique [0002] With the high integration of devices in the field of electronic appliances and the miniaturization and multi-functionalization of products in recent years, the heat generation density has also increased, and the heat release of electronic equipment and electronic components has become a serious problem. Materials with higher thermal conductivity With the rapid development of integrated circuits, it becomes more and more important. In particular, a problem has arisen in rapidly developing mobile information terminals that the heat generated by components is sufficient to cause low-temperature combustion. Therefore, materials are required not only to directly transfer heat to the chassis, but also to control electronic equipment and electronic components. In ...

Claims

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Application Information

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IPC IPC(8): C09K5/08C08L83/04C08L69/00C08L33/12C08K3/08
Inventor 桂林牛波
Owner TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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