High water system electrolyte with high frequency and low impedance for aluminium electrolytic capacitor and preparation method thereof

Abstract

The invention relates to the electrolyte technical field, and particularly to a high water system electrolyte with high frequency and low impedance for an aluminium electrolytic capacitor and a preparation method thereof. The electrolyte comprises the following raw materials by weight parts: 8-12 parts of ammonium adipate, 8-12 parts of anti-hydrating agents, 1.5-2.5 parts of ammonia water, 1-2 parts of p-nitrobenzoic acid, 0.5-1.5 parts of phosphoric acid, 4-7 parts of glycol, and 60-80 parts of deionized water. Through interaction of the raw materials and strict control of the weight ratio of the various raw materials, the spark voltage of the prepared electrolyte can reach 105V, and the conductivity can reach 50ms / cm. The high water system electrolyte of the invention has good electrochemistry characteristic and high frequency and low impedance, can be applied to the manufacture of the aluminium electrolytic capacitor.

Description

technical field [0001] The invention relates to the technical field of electrolytic solutions, in particular to an electrolytic solution for high-water system high-frequency and low-impedance aluminum electrolytic capacitors and a preparation method thereof. Background technique [0002] Aluminum electrolytic capacitors are one of the basic components of electronic products. With the continuous improvement of the quality of electronic products and the expansion of the application range of aluminum electrolytic capacitors, higher requirements are put forward for their performance. Electronic products such as switching power supplies and energy-saving lamps have high requirements on the safety performance of high-voltage electrolytic capacitors. In the filter circuit, the capacitor is subjected to high voltage and high ripple current. If the power supply is unstable or overvoltage is applied, the capacitor will be damaged, catch fire, burn and other accidents. The electrolyt...

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Problems solved by technology

The working electrolyte prepared in this way has the problem of low conductivity, and boric acid and its salts are easy to undergo esterification reaction with ethylene glycol at high temperature to generate a large amount of condensed water, which causes the moisture content inside the electrolyte to increase, and the electrolyte's The vapor pressure increases, and the internal pressure of the capacitor increases, causing the capacitor to open the valve and fail; 2. Using ethylene glycol as the main solvent, using direct-linked hydrocarbon saturated dicarboxylic acids such as azelaic acid, sebacic acid or dodecanedioic acid and their Salt is the electrolyte of the electrolyte. Although this type of electrolyte avoids a part of the esterification reaction, due to the low solubility of this type of straight-chain alkanes in ethylene glycol, the impedance of the product is large and the ripple is large. It is easy to generate heat under high temperature and make the solvent volatilize, thus creating a vicious cycle, causing the capacitor to dry out and fail. At the same time, linear alkanes are prone to amidation side reactions at high temperatures to generate water, which is also easy to cause early failure of the capacitor; 3. Use some branched chains Acids or their salts, such as reported 1,6-DDA and its salts and 2-butylsuberic acid and its salts, such branched carboxylic acids and their salts have improved solubility in solvents compared to straight-chain alkanes , thus producing effects to a certain extent, but at the same time, this kind of acid or its salt mainly relies on imports, so the cost is high and there are many constraints