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Method for firing Bayer process alkali red mud with dry method

A Bayer method of alkali and red mud technology, which is applied in the preparation of alkali metal aluminate/alumina/aluminum hydroxide, alumina/aluminum hydroxide, etc., and can solve problems such as poor product quality, increased infrastructure investment, and difficult control , to achieve the effect of reducing equipment and personnel investment, reducing energy consumption, and reducing operational difficulty

Active Publication Date: 2016-07-20
开曼铝业(三门峡)有限公司
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  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although over the years, some scientific research institutes and enterprises in our country have developed technologies such as series method and mixed method to utilize alkali red mud and improve the recovery rate of alumina and sodium oxide, but these two methods need to use the traditional sintering method. Wet sintering, which causes a series of problems such as complex and huge production system, increased infrastructure investment, high energy consumption, difficulty in control, poor product quality, etc., and the economy is not good, so it is gradually reduced or stopped.

Method used

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  • Method for firing Bayer process alkali red mud with dry method
  • Method for firing Bayer process alkali red mud with dry method
  • Method for firing Bayer process alkali red mud with dry method

Examples

Experimental program
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Effect test

Embodiment 1

[0030] see process figure 1 . The alkaline red mud in the raw material is Bayer process red mud from a factory in Xiaoyi, Shanxi. The raw material limestone and bauxite are mines in Xiaoyi, Shanxi. The composition is shown in Tables 1, 2, and 3.

[0031] Table 1: Components of Alkaline Red Mud

[0032]

[0033] Table 2: Limestone Composition

[0034]

[0035] Table 3: Bauxite composition

[0036]

[0037] Firstly, the limestone (composition as shown in Table 2) is crushed to 2-5 mm respectively, and then ground until the particle size is -0.074 mm, accounting for more than 85%. Then, filter the underflow of the last wash of the Bayer process with a plate and frame filter press to obtain an alkali red mud filter cake, and mix the alkali red mud (composition as shown in Table 1) filter cake, limestone powder, and soda ash powder according to the proportion of ingredients in the red mud filter cake 60 Parts by mass, 30 parts by mass of limestone, 5 parts by mass of b...

Embodiment 2

[0049] Firstly, bauxite (composition as shown in Table 1) and limestone (composition as in Table 2) are respectively crushed to 2-5mm, and then they are respectively ground until the particle size is -0.074mm, accounting for more than 85%. Then alkali red mud (composition as shown in Table 1), bauxite powder, limestone powder, and soda ash powder are fully mixed according to the proportions of 60 parts by mass of red mud filter cake, 35 parts by mass of limestone, and 15 parts by mass of soda ash. Control: the alkali ratio is 1, the calcium ratio is 2, the A / S is greater than 1.6, and the water content is 15%.

[0050] Put the prepared materials into the powerful mixer for full mixing, and the mixing uniformity is required to be greater than 98%.

[0051] Put the mixed material into the dryer for drying, the flue gas used for drying is the flue gas of the sintering kiln, the temperature is 1000-1100°C, the dried material enters the rotary kiln for sintering, the sintering temper...

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Abstract

The invention provides a method for firing Bayer process alkali red mud with a dry method.The method includes the following steps that alkali red mud, limestone powder, bauxite powder and sodium carbonate are prepared and fully mixed, the mixture is dried and enters a rotary kiln to be sintered, and then the mixture is levigated; regulation liquor is added into the levigated clinker powder for digestion, slag obtained after digestion is subjected to sufficient back washing 5-7 times, and then the slag is stacked; a solution obtained after digestion of the clinker powder and sodium aluminate crystals are mixed, desilicication is carried out after dissolution, aluminum hydroxide seed crystals are added into a solution obtained after desilicication for seed decomposition, and seed decomposition mother liquor is subjected to evaporation and salt elimination in two steps.For solving the problem that a large amount of alkali red mud is difficult to dispose, the alkali red mud dry method firing technology is proposed based on a traditional aluminum oxide sintering method; the whole seed decomposition technology is adopted, the technological process of the sintering method is shortened by 2 / 3 or above, the seed decomposition rate is increased to 90% or above through comprehensive calculation, operation difficulty is lowered, equipment and personnel input is reduced, and energy consumption is reduced.

Description

technical field [0001] The invention belongs to the field of industrial waste treatment, and in particular relates to a dry burning method of alkali red mud. Background technique [0002] The aluminum industry is the basic industry of our country, and the demand for bauxite in economic construction is very large, and most of our country is medium and low-grade bauxite. At present, more than 99% of my country's alumina production is produced by the Bayer process. With the declining trend of bauxite supply grade, the amount of alumina and sodium oxide abandoned in the red mud of the Bayer process is also increasing, resulting in Great waste of resources. On the other hand, because the quality of domestic bauxite is getting worse and higher, the price is getting higher and higher, and the cost of the Bayer process is also rising. In recent years, some enterprises have to import a large amount of bauxite from abroad. The foreign dependence of my country's bauxite aluminum resour...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/02C01F7/14
CPCC01F7/02C01F7/14
Inventor 张广麻树春
Owner 开曼铝业(三门峡)有限公司
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