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Reinforced and modified PBT (polybutylene terephthalate) material with epoxy resin bonding performance and preparation method for reinforced and modified PBT material

A technology of epoxy resin and adhesion, which is applied in the field of reinforced modified PBT materials and its preparation, can solve the problems of reduced packaging efficiency, difficulty in controlling the curing process of epoxy resin viscosity changes, etc., and achieve improved adhesion and excellent interface bonding effect

Inactive Publication Date: 2016-08-24
BENGBU ZHENGYUAN ELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Chinese patent CN 104610711 B discloses a PBT material with good epoxy resin adhesion and its preparation method. The invention uses antioxidant 24-44, antioxidant 168, antioxidant 1010 and carbon free scavenger HP136 The compounding, through the synergistic effect of each component, makes the material have excellent anti-aging performance, introduces reactive functional groups that have the ability to react with epoxy resin, and improves the interfacial adhesion with epoxy resin, but when using epoxy resin Rapid viscosity changes make it difficult to control the curing process, and rapid curing results in reduced encapsulation efficiency

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Weighing: 70 kg of PBT, 18 kg of cardanolamine, 18 kg of polyvinyl alcohol microspheres, 6 kg of sodium dodecyl sulfonate, 6 kg of gelatin, 8 kg of reinforcing agent, 2 kg of calcium stearate, and toughening agent AX8900 2 kg;

[0030] The reinforcing agent comprises the following components in parts by weight: 2 parts of nano-zirconium carbide, 2 parts of aluminum titanate fiber, and 4 parts of halloysite nanotubes pretreated with a silane coupling agent.

[0031] Specific steps are as follows:

[0032] (1), preparation of microcapsule curing agent:

[0033] ①. Under stirring conditions, add 0.5wt% gelatin aqueous solution and 0.5wt% sodium dodecylsulfonate aqueous solution, and disperse for 40 minutes under mechanical stirring at 800 rpm to obtain an aqueous phase;

[0034] 2. In the dichloromethane solvent, add cardanolamine and polyvinyl alcohol microspheres, and disperse evenly in an ultrasonic instrument to obtain an oil phase, and gradually add the water phase ...

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PUM

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Abstract

The invention discloses a reinforced and modified PBT (polybutylene terephthalate) material with epoxy resin bonding performance. The reinforced and modified PBT material consists of the following raw materials in parts by weight: 60 to 80 parts of PBT, 15 to 20 parts of cardanol amine, 15 to 20 parts of polyvinyl alcohol microspheres, 5 to 8 parts of sodium dodecyl sulfate, 5 to 10 parts of gelatin, 5 to 10 parts of a reinforcing agent, 1 to 3 parts of calcium stearate and 1 to 3 parts of a toughening agent AX8900. According to the reinforced and modified PBT material, a coated curing agent is introduced to increase the content of functional groups capable of being reacted with epoxy resin in the material, and meanwhile, a microcapsule of the microcapsule curing agent can be broken to be slowly released under a certain condition to implement curing, so that the aim of controlling a material and epoxy resin pouring sealant curing process is fulfilled, and the interface bonding performance between the material and the epoxy resin is improved; in addition, indianite is a natural multi-walled nanometer tubular material, has a nanometer tubular structure and the property of high dispersion rate, and can be combined with nanometer zirconium carbide and aluminum titanate fibers to achieve good synergistic toughening and reinforcing effects on the PBT.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a reinforced modified PBT material with epoxy resin adhesion and a preparation method thereof. Background technique [0002] Polybutylene terephthalate (English name Polybutylene Terephthalate, referred to as PBT) is milky white [0003] Color Translucent to opaque, crystalline thermoplastic polyester. It has excellent electrical properties, high heat resistance, toughness, fatigue resistance, self-lubrication, low coefficient of friction, weather resistance, low water absorption, and maintains various physical properties (including electrical properties) in a humid environment. Good, so it is widely used as engineering plastics in automobiles, electronic and electrical components. [0004] The engine ignition coil is the main component of the engine ignition system. Its function is to increase the low voltage of the car battery to a high voltage of 20kv to 40kv that ...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08L29/04C08L89/00C08L23/08C08K13/06C08K9/06C08K7/26C08K7/08C08K3/14C08G59/62
CPCC08G59/62C08G59/623C08K2201/011C08L67/02C08L2205/035C08L2205/06C08L29/04C08L89/00C08L23/0884C08K13/06C08K9/06C08K7/26C08K7/08C08K3/14
Inventor 夏云夏建生
Owner BENGBU ZHENGYUAN ELECTRONICS TECH
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