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Preparation method of ferronickel residue sintered water-permeable bricks

A technology for nickel-iron slag and permeable bricks is applied in the field of preparation of nickel-iron slag sintered permeable bricks, which can solve the problems of complex process, long production cycle, complex process, etc., and achieves simple process, reduced energy consumption and low sintering temperature Effect

Inactive Publication Date: 2016-10-26
SHANDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN104193300A discloses steel slag sintered permeable bricks and their production methods, which are composed of base materials and fabrics. Both base materials and fabrics are added with high-temperature binders. The high-temperature binders are composed of 6 raw materials such as feldspar and porcelain stone powder. Permeable bricks are prepared by sintering process, which uses more raw materials and complicated process
Research on the use of ferronickel slag as raw material to prepare permeable bricks has also been carried out. Among them, Chinese patent CN105418140A discloses a self-cleaning permeable brick with ferronickel slag and its preparation method, that is, using 12 kinds of ferronickel slag, raw clay and cement. Raw materials, permeable bricks were prepared by sintering, the compressive strength of the product can reach 34.8MPa, the flexural strength can reach 3.48MPa, and the water permeability coefficient is 0.48cm / s. This method also uses too many raw materials and the process is too complicated; Chinese patent CN104163596A discloses a nickel-iron slag pavement permeable brick and its preparation method, that is, the nickel-iron slag, active micropowder and cement are used to prepare the permeable brick through standard maintenance for 28 days, and the compressive strength of the product can reach 34.6MPa. The water permeability coefficient is 0.005cm / s, the production cycle of this method is long, the active micro powder needs to be ground to 300-500 mesh, and the energy consumption of grinding process is relatively high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] (1) Crushing and screening the ferronickel slag first, and taking particles with a particle size of 1~3mm as the raw material of ferronickel slag;

[0016] (2) According to mass percentage, take ferronickel slag raw material, halloysite clay and sodium water glass and carry out batching, wherein contain 80% ferronickel slag raw material, 10% halloysite clay and 10% sodium water glass, After mixing, add water and stir evenly, and press the evenly stirred mixture with a pressure of 50 MPa in a brick press to make bricks;

[0017] (3) Dry the adobe and sinter it at a temperature of 1200°C for 3 hours to make nickel-iron slag sintered permeable brick.

[0018] After testing, the flexural strength of nickel-iron slag sintered permeable brick is 3.8MPa, and the water permeability coefficient is 0.021cm / s.

Embodiment 2

[0020] (1) Crushing and screening the ferronickel slag first, and taking particles with a particle size of 1~3mm as the raw material of ferronickel slag;

[0021] (2) According to the mass percentage, weigh the ferronickel slag raw material, illite clay and potassium water glass for batching, which contains 75% of the ferronickel slag raw material, 15% illite clay and 10% potassium water glass, after mixing Add water and stir evenly, pressurize the evenly stirred mixture with 40MPa pressure in a brick press to make bricks;

[0022] (3) Dry the adobe and sinter it at a temperature of 1150°C for 4 hours to make nickel-iron slag sintered permeable brick.

[0023] After testing, the flexural strength of nickel-iron slag sintered permeable brick is 4.0MPa, and the water permeability coefficient is 0.017cm / s.

Embodiment 3

[0025] (1) Crushing and screening the ferronickel slag first, and taking particles with a particle size of 1~3mm as the raw material of ferronickel slag;

[0026] (2) According to mass percentage, weigh ferronickel slag raw material, halloysite clay, montmorillonite clay, sodium silicate and potassium silicate for batching, which contains 70% ferronickel slag raw material and 10% halloysite Clay, 5% montmorillonite clay, 10% sodium water glass and 5% potassium water glass, after mixing, add water and stir evenly, press the uniformly stirred mixture in a brick press with a pressure of 30MPa to make bricks;

[0027] (3) Dry the adobe and sinter it at a temperature of 1050°C for 6 hours to make nickel-iron slag sintered permeable brick.

[0028] After testing, the flexural strength of nickel-iron slag sintered permeable brick is 4.2MPa, and the water permeability coefficient is 0.012cm / s.

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Abstract

The invention provides a preparation method of ferronickel residue sintered water-permeable bricks, and belongs to the technical field of building materials. The preparation method is characterized by adopting the following steps that firstly, ferronickel residues are smashed and sieved, and particles with the particle size of 1 mm-3 mm are taken as ferronickel residue raw materials; secondly, 70%-80% of the ferronickel residue raw materials, 10%-15% of clay and 10%-15% of a bonding agent are weighed by mass for batching, mixed and then stirred to be uniform by adding water, and a uniformly-stirred mixture is subjected to pressurization molding under the pressure of 30 MPa-50 MPa in a brick press to prepare green bricks; finally, the green bricks are dried and then sintered at the temperature of 1,050 DEG C-1,200 DEG C, heat preservation is conducted for 3-6 h, and then the ferronickel residue sintered water-permeable bricks are prepared. According to the preparation method, the industrial waste residues-ferronickel residues are maximumly utilized, the waste materials are changed into things of value, environmental pollution is reduced, and the performances of the ferronickel residue sintered water-permeable bricks meet the relevant requirements of the national standard.

Description

technical field [0001] The invention relates to a preparation method of nickel-iron slag sintered permeable bricks, belonging to the technical field of building materials. Background technique [0002] Ferronickel slag is a solid by-product produced during pyrometallurgy of ferronickel with laterite nickel ore as raw material. For every ton of ferronickel alloy produced, 4 to 6 tons of ferronickel slag are produced. Compared with metallurgical slags such as slag and steel slag, ferronickel slag has high magnesium oxide content and low calcium oxide content; therefore, it has its particularity and difficulty in the preparation of building materials, and has not been fully utilized yet. [0003] Paving sidewalks, parking lots, and city squares with permeable bricks can quickly infiltrate rainwater into the ground, which can reduce urban drainage and flood control pressure, replenish soil water and groundwater, maintain soil moisture, improve urban microclimate, and alleviate u...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B33/138
CPCC04B33/138C04B2235/3427C04B2235/96Y02P40/60
Inventor 李国昌李思毛黄英姿李成峰王萍
Owner SHANDONG UNIV OF TECH
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