Efficient copper indium gallium selenide/perovskite series solar cell

A solar cell, copper indium gallium selenide technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve problems such as the reduction of solar cell efficiency, and achieve the effects of improving energy conversion efficiency, optimizing process parameters, and reducing losses

Inactive Publication Date: 2016-11-16
CHONGQING INST OF GREEN & INTELLIGENT TECH CHINESE ACADEMY OF SCI
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The perovskite light-absorbing layer has a band gap of about 1.5eV, which can absorb visible light well, but it is transparent to the near-infrared region, which directly leads to a decrease in the efficiency of perovskite solar cells.

Method used

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Embodiment 1

[0036] A high-efficiency copper indium gallium selenide / perovskite tandem solar cell structure such as figure 1 shown. Perovskite solar cells are as follows from bottom to top: transparent substrate 101, first transparent electrode layer 102, hole transport layer 103, perovskite light-absorbing layer 104, electron transport layer 105, second transparent electrode layer 106, Anti-layer 107 . The second transparent electrode layer 106 is sequentially composed of a lower electron extraction layer, an upper electron extraction layer, and a conductive layer from bottom to top. The transparent substrate 101 is quartz glass, the first transparent electrode layer 102 (anode) is ITO, and the thickness is 110nm; the hole transport layer 103 is PEDOT:PSS AI4083, and the thickness is 60nm; the perovskite light-absorbing layer 104 is CH 3 NH 3 PB 3 , with a thickness of 150nm, the electron transport layer 105 is PCBM, with a thickness of 50nm; the lower electron extraction layer is Rho...

Embodiment 2

[0044] Perovskite solar cells from bottom to top are: transparent substrate, first transparent electrode layer, hole transport layer, perovskite light absorbing layer, electron transport layer, lower electron extraction layer, upper electron extraction layer, conductive layer, AR layer. The transparent substrate is quartz glass, the first transparent electrode layer (anode) is a three-layer graphene film, each layer thickness is 0.34nm; the hole transport layer is PEDOT:PSS AI4083, the thickness is 60nm; the perovskite light absorption layer is CH 3 NH 3 PB 3-X Cl X , the thickness is 160nm; the electron transport layer is PCBM, the thickness is 50nm; the lower electron extraction layer is Rhodamine101, the thickness is 0.5nm; the upper electron extraction layer is LiF, the thickness is 0.5nm; the conductive layer is ultra-thin Ag, the thickness is 8nm; The anti-reflection layer is MoO X , with a thickness of 2 nm.

[0045] Copper indium gallium selenide solar cells from ...

Embodiment 3

[0051] Perovskite solar cells from bottom to top are: transparent substrate, first transparent electrode layer, electron transport layer, perovskite light-absorbing layer, hole transport layer, second transparent electrode layer, and antireflection layer. The transparent substrate is quartz glass, the first transparent electrode layer (cathode) is FTO with a thickness of 100nm; the electron transport layer is ZnO nano film with a thickness of 40nm; the perovskite light-absorbing layer is CH 3 NH 3 PB 3 , the thickness is 160nm; the hole transport layer is PTAA, the film thickness is 50nm; the second transparent electrode layer (anode) is ultra-thin Ag, the thickness is 12nm; the anti-reflection layer is MoO X , with a thickness of 2 nm.

[0052] Copper indium gallium selenide solar cells from bottom to top are: with SiO 2 layer glass substrate; the anode is Mo, the thickness is 800nm; the copper indium gallium selenide absorbing layer, the thickness is 2um; the buffer layer...

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Abstract

The invention provides an efficient copper indium gallium selenide / perovskite series solar cell. The four-terminal series solar cell comprises a semitransparent planar heterojunction perovskite solar cell and a copper indium gallium selenide (CIGS) solar cell which are connected in series. The series solar cell can overcome the shortcoming that the perovskite solar call cannot absorb near-infrared light; the efficient copper indium gallium selenide / perovskite series solar cell can effectively absorb ultraviolet light, visible light and near infrared light, so that the solar cell efficiency can be improved; and a new thought for the final commercialization of perovskite is provided.

Description

technical field [0001] The invention belongs to the field of semiconductor optoelectronic devices, in particular to the field of copper indium gallium selenide / perovskite tandem solar cells. Background technique [0002] With the depletion of non-renewable resources such as coal, oil and natural gas, new energy, especially solar cells, has become a hot spot of research at home and abroad. At present, inorganic silicon solar cells have been industrialized, but their cost is too high, and the efficiency of organic solar cells is too low, so the prospects are not clear. Since the first report in 2009, perovskite solar cells have been favored by researchers for their ultra-low-cost solution preparation process. The energy conversion efficiency has increased from the initial 3.8% to 20.1%. With the deepening of research, The efficiency of the cell is very likely to exceed that of the currently developed monocrystalline silicon solar cells. [0003] The perovskite light-absorbin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L25/16H01L51/42
CPCH01L25/167H10K30/10Y02E10/549
Inventor 冷重钱陆仕荣杨俊汤林龙姬乙雄麻超燕罗伟魏兴战史浩飞
Owner CHONGQING INST OF GREEN & INTELLIGENT TECH CHINESE ACADEMY OF SCI
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