Gel microsphere system and preparation method thereof, gel microsphere dispersion system and gel microsphere reinforced polymer flooding system
A technology of dispersion system and polymer, applied in drilling compositions, chemical instruments and methods, etc., can solve the problems of ineffective plugging and profile control, poor elasticity and deformability of microspheres, and achieve easy large-scale industrialization Production, mild conditions, enhanced oil recovery effects
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Embodiment 1
[0037] The jelly microsphere system of this example is mainly prepared by emulsion polymerization of the following raw materials in mass percentages under the conditions of ultraviolet light triggering and thermal triggering: 5% water-soluble anionic monomer, 35% acrylamide, dispersed 15% agent, 1% crosslinking agent, 10% water, 22% surfactant, 10% oily solvent, 0.85% photoinitiator, 1.15% potassium persulfate; the water-soluble anionic monomer is acrylic acid, and the dispersant is A mixture of N-vinylpyrrolidone and polyvinylpyrrolidone at a mass ratio of 1:1, the crosslinking agent is N,N-methylenebisacrylamide, the surfactant is sodium dodecylsulfonate, and the oily solvent is Rapeseed oil, the photoinitiator is phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide.
[0038] The preparation method of the jelly microsphere system of the present embodiment may further comprise the steps:
[0039]1) Preparation of water phase system: add water-soluble anionic monomer, dispersant,...
Embodiment 2
[0046] The jelly microsphere system of this example is mainly prepared by emulsion polymerization of the following raw materials in mass percentages under the conditions of ultraviolet light triggering and thermal triggering: 15% water-soluble anionic monomer, 15% acrylamide, dispersed 1%, crosslinking agent 0.07%, water 30%, surfactant 15.7%, oily solvent 20%, photoinitiator 0.23%, ammonium persulfate 3%; Described water-soluble anion monomer is acrylic acid and acrylic acid hydroxybutyl A mixture of esters at a ratio of 1:1, the dispersant is N-vinylpyrrolidone, the crosslinking agent is diallyldimethylammonium chloride, the surfactant is cetyltrimethylammonium bromide, and the oily solvent It is industrial white oil, and the photoinitiator is 2-methyl-1-[4-(methylthio)phenyl]-2-(4-morpholino)-1-propanone.
[0047] The preparation method of the jelly microsphere system of the present embodiment may further comprise the steps:
[0048] 1) Preparation of water phase system: a...
Embodiment 3
[0055] The jelly microsphere system of this example is mainly prepared by emulsion polymerization of the following raw materials in mass percentages under the conditions of ultraviolet light initiation and thermal initiation: 8% water-soluble anionic monomer, 16% acrylamide, dispersed 7% agent, 0.5% crosslinking agent, 30% water, 20% surfactant, 17% oily solvent, 0.14% photoinitiator, 1.36% potassium persulfate; the water-soluble anionic monomer is methacrylic acid and acrylic acid A mixture of hydroxybutyl esters at a ratio of 6:4, a dispersant of polyvinylpyrrolidone, and a crosslinking agent of N,N-methylenebisacrylamide and diallyldimethylammonium chloride at a mass ratio of 1:1 Composed mixture, the surfactant is a mixture of sodium dodecylsulfonate and cetyltrimethylammonium bromide in a mass ratio of 1:1, the oily solvent is heat conduction oil, and the photoinitiator is 1-hydroxyl A mixture of cyclohexyl phenyl ketone and 2-hydroxy-2-methyl-1-phenyl-1-propanone accordi...
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Abstract
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