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Method for treating high-salt-concentration industrial wastewater at different ionic concentrations

A technology for industrial wastewater and treatment methods, applied in ion-exchange water/sewage treatment, energy wastewater treatment, water/sewage treatment, etc., can solve problems such as the inability to effectively separate and crystallize salt, and the inability to achieve zero discharge of wastewater. The effect of emissions

Active Publication Date: 2017-02-22
INNER MONGOLIA JIUKE KANGRUI ENVIRONMENTAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The purpose of the present invention is to provide a treatment method for high-salt industrial wastewater with different ion concentrations, so as to solve the problem that the current high-salt industrial wastewater treatment method does not classify and treat the salt according to the different influent water quality and cannot be effectively separated and crystallized , so that the problem of zero discharge of wastewater in the true sense cannot be realized

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  • Method for treating high-salt-concentration industrial wastewater at different ionic concentrations
  • Method for treating high-salt-concentration industrial wastewater at different ionic concentrations
  • Method for treating high-salt-concentration industrial wastewater at different ionic concentrations

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Effect test

Embodiment 1

[0034] Embodiment 1: when the concentration ratio of chloride ion and sulfate ion in high salinity industrial waste water is less than 1:4, the specific treatment method of high salt content industrial waste water comprises the following steps:

[0035] (1) High-salt industrial wastewater first enters the regulating tank for water quality and water volume adjustment, and then enters the high-density sedimentation tank, and adds one or more of liquid caustic soda, soda ash, lime, magnesium agent, PAC or PFS to the high-density sedimentation tank Several types, stay for 30 seconds to 2 minutes, then add flocculant PAM to the high-density sedimentation tank, stay for 8-20 minutes, then settle for 2-3 hours, and finally add acid to return the pH of high-salt industrial wastewater to Between 6.5 and 7.5, the supernatant in the high-density sedimentation tank enters the precision filter device, and the sediment in the high-density sedimentation tank enters the sludge dewatering room;...

Embodiment 2

[0048] Embodiment 2: when the ratio of chloride ion and sulfate ion in the high-salt industrial waste water is greater than 2:3, the processing method of high-salt industrial waste water comprises the following steps:

[0049] (a): (1) High-salt industrial wastewater first enters the high-salt water adjustment tank for water quality and water volume adjustment, and then enters the high-density sedimentation tank, and at the same time adds liquid caustic soda, soda ash, lime, magnesium, and PAC to the high-density sedimentation tank Or one or more of PFS, stay for 30 seconds to 2 minutes, and then add flocculant PAM to the high-density sedimentation tank, stay for 8-20 minutes, then settle for 2-3 hours, and finally add acid to reduce the high The pH of the saline industrial wastewater is adjusted back to 6.5-7.5, the supernatant in the high-density sedimentation tank enters the precision filter device, and the sediment in the high-density sedimentation tank enters the sludge de...

Embodiment 3

[0058] Embodiment 3: when the ratio of chloride ion and sulfate ion in the high-salt industrial waste water is between 1:4-2:3, the treatment method of high-salt industrial waste water comprises the following steps:

[0059] (A) judge whether the alkalinity in the high-salt industrial wastewater is greater than 3000mg / L;

[0060] (B) When alkalinity is less than 3000mg / L in the high-salt industrial wastewater, and in the whole process of processing high-salt industrial wastewater, the step of adding acid is all selected sulfuric acid to ensure that the sulfate ion concentration is far greater than the chloride ion concentration; In this case, the method for processing the high-salt industrial wastewater is the same as the treatment method when the concentration ratio of chloride ion and sulfate ion is less than 1:4 in the high-salt industrial wastewater; When the concentration is 3000mg / L, hydrochloric acid is selected in the steps that need to add acid in the whole process of...

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Abstract

The invention discloses a method for treating high-salt-concentration industrial wastewater at different ionic concentrations. When the concentration ratio of the chloridion to the sulfate ion in the wastewater is less than 1:4, the wastewater is sequentially subjected to the corresponding process treatment through a high-salt-concentration water regulating reservoir, a high-density sedimentation tank, a submerged ultrafiltration membrane, an advanced oxidation device, a reverse osmosis system, a high pressure flat sheet membrane and salt separation crystallizer equipment; when the concentration ratio is more than 1:4, the wastewater is sequentially subjected to the corresponding process treatment through the high-salt water regulating reservoir, the high-density sedimentation tank, the submerged ultrafiltration membrane, the advanced oxidation device, the reverse osmosis system, a nanofiltration device,the high pressure flat sheet membrane and the salt separation crystallizer equipment; when the concentration ratio is between 1:4 and 2:3 and the alkalinity of the wastewater is less than 3,000 mg / L, the sulfuric acid is used in the process, the treatment method same as the method used when the concentration ratio is less than 1:4 is used; and when the alkalinity of the wastewater is more than 3,000 mg / L, the hydrochloric acid is used in the process, and the treatment method same as the method used when the concentration ratio is more than 1:4 is used. The salt in the wastewater is sufficiently recovered, and the zero release of the wastewater is realized in the true sense.

Description

[0001] Technical field: [0002] The invention relates to a method for treating waste water, in particular to a method for treating high-salt industrial waste water with different ion concentrations. [0003] Background technique: [0004] High-salt industrial wastewater is usually washing wastewater, process system condensate, chemical water station drainage, circulating water sewage, etc. produced in the production process of coal chemical industry and petrochemical industry. Due to the different production processes adopted by various enterprises, coal The different types of coal and the continuous mixing of other types of wastewater in the subsequent discharge process lead to the characteristics of the final wastewater to be treated, such as large water volume, complex composition, high pollutant concentration, high hardness, high alkalinity, and large fluctuations in overall water quality. [0005] At present, the research on the comprehensive utilization of high-salt indu...

Claims

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Application Information

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IPC IPC(8): C02F9/10
CPCC02F1/001C02F1/048C02F1/42C02F1/441C02F1/444C02F1/4693C02F1/52C02F1/66C02F1/78C02F9/00Y02A20/131Y02W10/37
Inventor 赛世杰张娜高贵和党平刘慧李战胜王俊辉薛源刘丹茹李思序杭天浜郭默然
Owner INNER MONGOLIA JIUKE KANGRUI ENVIRONMENTAL TECH