Device and method for increasing yield of tar by using coke oven gas as raw material through catalytic reforming
A coke oven gas and catalytic reforming technology, which is applied in coking ovens, petroleum industry, and the preparation of liquid hydrocarbon mixtures, etc., can solve the problem of high cost of preparation sources, and achieve the effects of reducing greenhouse effect, production cost, and environmental pollution
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Embodiment 1
[0052] Pyrolysis under N2 atmosphere
[0053] Coal of a certain size is pyrolyzed within the temperature range of 500°C-1100°C, the pressure is normal pressure, the residence time is 1 hour, and the nitrogen flow rate is 600ml / min. The tar yields at 500°C, 600°C, 700°C, 800°C, and 900°C were 4.17%, 4.14%, 4.46%, 4.63%, and 4.52%, respectively.
Embodiment 2
[0055] Pyrolysis under mixed atmosphere of coke oven gas, combustion waste gas and water vapor
[0056] Coal of a certain size is pyrolyzed within the temperature range of 500°C-1100°C, the pressure is normal pressure, the residence time is 1 hour, and the flow rate of coke oven gas, combustion exhaust gas and water vapor mixture is 600ml / min. The tar yields at 500°C, 600°C, 700°C, 800°C, and 900°C were 4.35%, 4.63%, 5.06%, 4.74%, and 4.63%, respectively.
Embodiment 3
[0058] Ni / Al 2 o 3 Catalytic activation of mixed gas pyrolysis
[0059] The selected catalyst is Ni / Al 2 o 3, Coal of a certain size is pyrolyzed within the temperature range of 500°C-1100°C, the pressure is normal pressure, the residence time is 1 hour, and the mixed gas flow rate is 600ml / min. The tar yields at 500°C, 600°C, 700°C, 800°C, and 900°C were 3.49%, 3.56%, 4.96%, 4.68%, and 4.71%, respectively.
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