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Device and method for increasing yield of tar by using coke oven gas as raw material through catalytic reforming

A coke oven gas and catalytic reforming technology, which is applied in coking ovens, petroleum industry, and the preparation of liquid hydrocarbon mixtures, etc., can solve the problem of high cost of preparation sources, and achieve the effects of reducing greenhouse effect, production cost, and environmental pollution

Inactive Publication Date: 2017-05-10
TAIYUAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the production cost of carbon dioxide is relatively high

Method used

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  • Device and method for increasing yield of tar by using coke oven gas as raw material through catalytic reforming
  • Device and method for increasing yield of tar by using coke oven gas as raw material through catalytic reforming
  • Device and method for increasing yield of tar by using coke oven gas as raw material through catalytic reforming

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] Pyrolysis under N2 atmosphere

[0053] Coal of a certain size is pyrolyzed within the temperature range of 500°C-1100°C, the pressure is normal pressure, the residence time is 1 hour, and the nitrogen flow rate is 600ml / min. The tar yields at 500°C, 600°C, 700°C, 800°C, and 900°C were 4.17%, 4.14%, 4.46%, 4.63%, and 4.52%, respectively.

Embodiment 2

[0055] Pyrolysis under mixed atmosphere of coke oven gas, combustion waste gas and water vapor

[0056] Coal of a certain size is pyrolyzed within the temperature range of 500°C-1100°C, the pressure is normal pressure, the residence time is 1 hour, and the flow rate of coke oven gas, combustion exhaust gas and water vapor mixture is 600ml / min. The tar yields at 500°C, 600°C, 700°C, 800°C, and 900°C were 4.35%, 4.63%, 5.06%, 4.74%, and 4.63%, respectively.

Embodiment 3

[0058] Ni / Al 2 o 3 Catalytic activation of mixed gas pyrolysis

[0059] The selected catalyst is Ni / Al 2 o 3, Coal of a certain size is pyrolyzed within the temperature range of 500°C-1100°C, the pressure is normal pressure, the residence time is 1 hour, and the mixed gas flow rate is 600ml / min. The tar yields at 500°C, 600°C, 700°C, 800°C, and 900°C were 3.49%, 3.56%, 4.96%, 4.68%, and 4.71%, respectively.

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Abstract

The invention discloses a device and method for increasing yield of tar by using a coke oven gas as a raw material through catalytic reforming. A carbonization chamber is formed inside a coke oven of the device; a reforming reaction device is arranged inside the carbonization chamber; an annular combustion chamber is formed on the outer side of the carbonization chamber. The method comprises the following steps: firstly, introducing the coke oven gas and carbon dioxide and vapor generated from the coke oven combustion chamber into a catalyst layer, performing a catalytic reforming reaction, after the reaction, introducing gas flow into coal, and performing pyrolysis on the coal in the atmosphere. According to the device and the method, carbon dioxide has a reforming reaction with methane, carbon monoxide has a water-gas reaction with water, a generated H intermediate can be acted with large-molecule free radicals generated in the pyrolysis process, and the yield of tar can be increased. By adopting the device and the method, the hydrogenation cost can be lowered, the greenhouse effect can be alleviated, and the environment can be improved; by adjusting the contact mode of the catalyst inside the coke oven and the coal, the reaction contact area can be increased, the utilization rate can be increased, and the reaction time can be shortened; in addition, as the catalyst and the coal can be layered, the catalyst can be easily recycled and reused, and the yield of coal tar can be high.

Description

technical field [0001] The invention relates to a device and method for increasing tar yield through catalytic reforming using coke oven gas as raw material, belonging to the technical field of energy. Background technique [0002] In today's society, the country advocates the development of new energy sources, such as tidal energy, solar energy, etc., but the technology is still immature and cannot completely replace the existing energy structure, so primary energy is still the main energy used in our country. However, as the main energy source, while meeting people's needs, there are also problems such as energy depletion and environmental pollution. Coal already has a fairly mature technical basis in replacing petroleum, so coal-to-oil production has become an important technical solution. Coal pyrolysis is a simple thermal processing process, and the coal pyrolysis process is a process that improves the utilization rate of coal. There are problems such as low tar y...

Claims

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Application Information

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IPC IPC(8): C10G1/06C10B53/00C10B53/04C10B53/08C10B57/12C10B57/00
CPCC10B53/00C10B53/04C10B53/08C10B57/00C10B57/12C10G1/06
Inventor 张国杰侯鹏叶俊岭刘继伟徐英张永发
Owner TAIYUAN UNIV OF TECH
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