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A low-temperature phase-change material with a phase-change temperature of -26 to -28°C

A low-temperature phase transition and phase transition temperature technology, applied in the field of phase transition energy storage, can solve the problems of small latent heat of phase transition and poor stability, and achieve the effects of low cost, good stability and simple preparation process

Active Publication Date: 2020-09-25
SUZHOU ANTEK INDAL +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Defects in the existing technology: product transportation needs to be maintained in an extremely low temperature environment, but the phase change temperature of the currently used phase change materials is mostly low to medium temperature, and the temperature cannot fluctuate within a small range. The stability is poor. The single inorganic hydrated salt phase change material has general supercooling and phase separation phenomenon. Although the single organic phase change material has no supercooling and phase separation phenomenon, its phase change latent heat is small.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A low-temperature phase-change material with a phase-change temperature of -26 to -28°C is prepared from raw materials in the following weight ratios: 90 parts of a main energy storage agent, 5 parts of a nucleating agent, and 5 parts of a thickener.

[0022] The main energy storage agent is ammonium chloride as inorganic salt, sodium acetate as organic salt, and mixed solution of ethylene glycol and water as alcohol.

[0023] The nucleating agent is sodium tetraborate.

[0024] The thickener is fumed white carbon black.

[0025] A method for preparing a low-temperature phase change material with a phase transition temperature of -26 to -28°C, the steps of the method are as follows: Step 1: Preparation of the main energy storage agent: Ammonium chloride, sodium acetate, ethylene glycol and water are prepared according to 15: The ratio of 5:2:74 is configured, stirred evenly at room temperature to obtain a clear solution; Step 2: Preparation of phase change material: Ad...

Embodiment 2

[0032] A low-temperature phase-change material with a phase-change temperature of -26 to -28°C is prepared from raw materials in the following weight ratios: 97 parts of a main energy storage agent, 1.5 parts of a nucleating agent, and 1.5 parts of a thickener.

[0033] The main energy storage agent is sodium chloride as inorganic salt, sodium acetate as organic salt, and mixed solution of ethanol and water as alcohol.

[0034] The nucleating agent is diatomaceous earth.

[0035] The thickener is guar gum.

[0036] A method for preparing a low-temperature phase change material with a phase change temperature of -26 to -28°C, the method steps are as follows: Step 1: Preparation of the main energy storage agent: sodium chloride, sodium acetate, ethanol and water are mixed in a ratio of 17:5 : The ratio configuration of 4:72, stir evenly at room temperature to obtain a clear solution; Step 2: Preparation of phase change material: add cooling agent and nucleating agent to the mai...

Embodiment 3

[0042] A low-temperature phase-change material with a phase-change temperature of -26 to -28°C is prepared from raw materials in the following weight ratios: 94 parts of a main energy storage agent, 3 parts of a nucleating agent, and 1 part of a thickener.

[0043] The main energy storage agent is calcium chloride as inorganic salt, sodium formate as organic salt, and mixed solution of glycerol and water as alcohols.

[0044] The nucleating agent is barium fluoride.

[0045] The thickener is xanthan gum.

[0046] A method for preparing a low-temperature phase-change material with a phase-change temperature of -26 to -28°C, the method steps are as follows: Step 1: Preparation of a main energy storage agent: calcium chloride, sodium formate, glycerol and water are mixed at a ratio of 18:6 : 3:79 ratio configuration, stir evenly at room temperature to obtain a clear solution; Step 2: Preparation of phase change material: add cooling agent and nucleating agent to the main energy ...

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Abstract

The invention relates to the field of phase change energy accumulation, and particularly relates to a low-temperature phase-change material with the phase change temperature of 26-28 DEG C, and a preparation method thereof. The low-temperature phase-change material is prepared from the following raw materials in parts by weight: 90-98 parts of a main energy accumulation agent, 1-5 parts of a nucleating agent, and 1-5 parts of a thickener. The main energy accumulation agent is an inorganic salt-organic salt-alcohol aqueous solution, the inorganic salt is a chloride, and the organic salt is organic sodium salt. The phase-change material adopts an inorganic-organic multi-composite material and combines the advantages of two types of phase-change materials, thus being good in stability, wide in sources of raw materials, low in cost, non-toxic and tasteless, and safe and reliable; the preparation technique is simple, the phase change temperature of the phase-change material can be adjusted within 26-28 DEG C due to different proportions of the inorganic salt, organic salt and alcohols, the cold insulation time is long, and the cycle life is long; and the phase-change material can be popularized and used in the cold-chain transportation of foods or medical products.

Description

technical field [0001] The invention relates to the field of phase change energy storage, in particular to a low-temperature phase change material with a phase change temperature of -26 to -28°C. Background technique [0002] Phase change energy storage materials are one of the hotspots in the development and research of energy utilization and material science at home and abroad in recent years. Phase change energy storage is also called latent heat energy storage. Its principle is to use phase change materials to absorb / release energy to store / release heat when the phase state changes. Phase-change energy storage materials largely solve the problem of energy mismatch in time and space. [0003] With the increase of people's awareness of environmental protection, the shortage of energy and the problem of environmental pollution in the process of energy use have led to the urgent development and use of new energy sources, such as intermittent clean energy such as solar energ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/06
CPCC09K5/063Y02E60/14
Inventor 丘晓琳包伟强
Owner SUZHOU ANTEK INDAL