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Concrete moisture evaporation inhibitor and preparation method and application thereof

An evaporation inhibitor and concrete technology, applied in the field of concrete, can solve the problems of laborious, troublesome construction, difficult to remove, etc., and achieve the effects of good anti-cracking effect, inhibiting water evaporation, and reducing plastic cracking

Active Publication Date: 2017-06-09
中建西部建设新材料科技有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, grass cover and plastic film are the most common methods, which are usually suitable for horizontal building structures, such as building floors, concrete bridge decks and road surfaces, etc., but for facade walls or other irregular structures, this method cannot Very good application; moreover, due to the cooperation of many people in the construction method, a large amount of waste will be generated, so there are disadvantages of troublesome construction, time-consuming and labor-intensive
The water evaporation inhibitor products with water glass as the main component overcome the above shortcomings to a certain extent by spraying or brushing, but because of their poor film-forming properties on the surface, the 1h water evaporation inhibition rate is only 20%. ~30%
The water evaporation inhibitor products with paraffin wax emulsion as the main component generally require a higher dosage when achieving a higher water evaporation inhibition rate. At this time, the paraffin wax forms a solid hydrophobic layer on the concrete surface, which is not easy to remove, thus affecting post-concrete construction
[0004] Patent CN105503019A discloses a preparation method of coagulation water evaporation inhibitor, which method is to configure long-chain alcohol, emulsifier, water and optional thickener, defoamer and other components, and then long-chain alcohol, emulsified Mixing agent and pre-emulsification with water, high-speed shear emulsification in the state of complete melting of long-chain alcohol, and finally adding the remaining water quickly, the obtained concrete moisture evaporation inhibitor can effectively solve the plasticity of concrete caused by water loss under high heat and high wind conditions However, the preparation process of the water evaporation inhibitor needs to be completed in multiple steps, and it needs to be produced under high temperature conditions of 50-100 °C
Similar to this, patent CN101805145B reports a plastic coagulation water evaporation inhibitor and its preparation method. It is made by mixing amphiphilic compounds, surfactants, thickeners and co-emulsifiers. The product can reduce the plasticity of concrete. In the early stage of the state, the surface water evaporates, but it also needs to be produced at 50-80°C, the temperature is higher, and the energy consumption is larger
Patent CN102731016A has invented a coagulation water evaporation inhibitor and its preparation method, which is made by mixing fatty alcohol, fatty alcohol polyoxyethylene ether, sodium alkylsulfonate and organic solvents such as methanol, ethanol or ethylene glycol. The use of organic solvents can promote the dissolution of raw materials, greatly reduce the amount of surfactants and emulsifiers, and can also reduce the evaporation of water on the surface of concrete in the plastic stage. However, this product is also produced at 50-80 ° C, and it is also used Toxic and volatile organic solvents, poor environmental protection, not conducive to production and application

Method used

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  • Concrete moisture evaporation inhibitor and preparation method and application thereof
  • Concrete moisture evaporation inhibitor and preparation method and application thereof
  • Concrete moisture evaporation inhibitor and preparation method and application thereof

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Embodiment 1

[0036] A concrete water evaporation inhibitor, the monomers involved are methacrylic acid, acrylamide, N-hydroxyethylacrylamide and ethylene glycol diacrylate, and its material ratio is 1:1.5:0.2:0.01, its The preparation method specifically comprises the following steps:

[0037] (1) Add 43.0g of methacrylic acid, 53.3g of acrylamide, 11.5g of N-hydroxyethylacrylamide, 0.85g of ethylene glycol diacrylate, and 653.0g of deionized water into a 1L four-necked flask, and stir evenly. After all the monomers are dissolved, add 5g of isopropanol and 2g of ammonium persulfate, and stir evenly;

[0038] (2) Adding 80 g of sodium sulfite solution with a mass fraction of 0.1% dropwise in the solution obtained in step (1), controlling the water bath at 35° C., the dropwise addition time is 3 h, and the dropwise addition is completed and incubated for 1 h; after the reaction is completed, add 30 wt % sodium hydroxide The pH of the aqueous solution is adjusted to 7 to obtain the concrete ...

Embodiment 2

[0044] A concrete moisture evaporation inhibitor, the monomers involved are methacrylic acid, acrylamide, N-methylolacrylamide and glycidyl methacrylate, and its material ratio is 1:1.5:0.2:0.01, its The preparation method comprises the following steps:

[0045] (1) Add 43.0g of methacrylic acid, 53.3g of acrylamide, 10.1g of N-methylolacrylamide, 0.7g of glycidyl methacrylate, and 720g of deionized water into a 1L four-neck flask, stir well, and wait until After the body is completely dissolved, add 3 g of mercaptoethanol and 1.2 g of ammonium persulfate, and stir evenly;

[0046] (2) in step (1) gained solution, dripping mass fraction is 0.2% sodium thiosulfate solution 60g, controls water bath 35 ℃, and the time of dropping is 3h, and dropwise completes insulation 1h; Reaction completes, adds 30wt% The aqueous sodium hydroxide solution adjusts the pH to 7 to obtain the concrete moisture evaporation inhibitor solution.

[0047] The obtained concrete moisture evaporation in...

Embodiment 3

[0052] A concrete moisture evaporation inhibitor, the monomers involved are acrylic acid, acrylamide, N-hydroxyethylacrylamide and polyethylene glycol diacrylate (average molecular weight 400), and the molar ratio of the substances is 1:1:0.1 :0.05, its preparation method comprises the following steps:

[0053] (1) Add 36g of acrylic acid, 35.5g of acrylamide, 5.2g of N-methylolacrylamide, 10g of polyethylene glycol diacrylate (average molecular weight 400), and 692g of deionized water into a 1L four-necked flask, and stir evenly. After all the monomers are dissolved, add 2 g of thioglycolic acid and 1.5 g of hydrogen peroxide, and stir evenly;

[0054] (2) Adding 40 g of L-ascorbic acid solution with a mass fraction of 0.2% dropwise in the solution obtained in step (1), controlling the water bath to 40° C., the time for dropping is 4 hours, and the dropwise addition is completed and kept for 1 hour; after the reaction is completed, add 30 wt % of hydrogen The pH of the sodiu...

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Abstract

The invention discloses a concrete moisture evaporation inhibitor and a preparation method and application thereof. The concrete moisture evaporation inhibitor is prepared by taking unsaturated acid, unsaturated amide and unsaturated ester as main raw materials and is polymerized by adopting a water solution free radical method with mass ratio of 1:(1-2.5):(0.0-0.1). A moisture evaporation inhibitor solution is introduced into the concrete by an external spraying or internal doping mode, evaporation of surface moisture at the plastic state of the concrete can be obviously inhibited, plastic cracking of the concrete is greatly reduced, and the concrete moisture evaporation inhibitor and the preparation method and application thereof have the advantages of being simple in process, green and environment friendly, convenient in use and good in anti-cracking effect.

Description

technical field [0001] The invention belongs to the field of concrete, and relates to a concrete water evaporation inhibitor, a preparation method and application thereof. Background technique [0002] Cast-in-place concrete usually needs to be cured in time during the plastic stage, otherwise plastic shrinkage cracks will easily appear. This is mainly because the free water in the concrete slurry will evaporate to the surface. With the increase of water loss, the stress generated by capillary negative pressure makes the concrete surface Volume shrinkage occurs, and surface cracks appear, especially in high temperature weather. Severe cracking will cause huge economic losses and hidden dangers to building safety. Therefore, controlling the evaporation of water in the plastic stage of concrete and reducing plastic cracking are of great significance to ensure the safety of concrete structures. [0003] There are many ways to suppress the evaporation of concrete moisture, such...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/56C08F220/06C08F220/58C08F222/14C08F220/32C08F283/06C08F222/02C08F220/28C04B40/04
CPCC04B40/04C08F220/06C08F220/56C08F283/065C08F220/58C08F222/1063C08F222/102C08F220/281C08F220/325
Inventor 刘明吕锐陈景郑广军高育欣
Owner 中建西部建设新材料科技有限公司
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