Preparation method of structural-color fabric
A structural color and fabric technology, applied in dyeing, textile and papermaking, fiber processing, etc., can solve the problems of weak adhesion between microspheres and fabric surface, affecting the subsequent use of fabrics, and damage to the arrangement of colloidal microspheres. Iridescent effect, fast dyeing rate, the effect of suppressing electrostatic interaction
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Embodiment 1
[0066] A 40mm*50mm cotton fabric was ultrasonically cleaned three times with ethanol and ultrapure water to remove surface impurities, and then dried for later use.
[0067] P(St-MMA-AA) composite microspheres were synthesized by emulsion polymerization, specifically referring to the method in the literature Control over the Wettability of Colloidal Crystal Films by Assembly Temperature, Macromol. Rapid Commun., 2006, 27, 188. Composite microspheres with particle sizes of 217nm, 257nm and 297nm were prepared by adjusting the amount of initiator. The P(St-MMA-AA) composite microspheres were centrifuged and washed three times, and then dispersed in deionized water to obtain a colloidal emulsion with a mass fraction of 10 wt%.
[0068] The polyacrylate adhesive is added in the prepared colloidal emulsion by the mass ratio of 1:50, stirs 20 minutes by magnetic stirrer, then adds carbon black, the mass ratio of colloidal emulsion and carbon black is 100:1, then Then ultrasonically...
Embodiment 2
[0096] The 40mm*50mm PET woven fabric was ultrasonically cleaned three times with ethanol and ultrapure water in order to remove surface impurities. After drying, it was treated with oxygen plasma for 180s under the condition of gas pressure 90Pa and discharge power 120W, and the polymer groups on the surface of the fabric were activated. Afterwards, it was grafted in acrylic acid gas for 180s under the conditions of air pressure 60Pa and discharge 50W.
[0097] P(St-MMA-AA) composite microspheres were synthesized by emulsion polymerization, and the composite microspheres with a particle size of 168nm were prepared. The P(St-MMA-AA) composite microspheres were centrifuged and washed three times, and then dispersed in deionized water to obtain a colloidal emulsion with a mass fraction of 10 wt%.
[0098] Add polyacrylate adhesive and carbon black to the prepared colloidal emulsion at a mass ratio of 100:2:1, stir with a magnetic stirrer for 20 minutes, and then ultrasonically v...
Embodiment 3
[0105] The 40mm*50mm PE non-woven fabric was ultrasonically cleaned three times with ethanol and ultrapure water to remove surface impurities. After drying, it was treated with oxygen plasma for 180s under the condition of gas pressure 90Pa and discharge power 120W, and the polymer groups on the surface of the fabric were treated. After activation, carry out acrylic acid grafting treatment for 180s under the conditions of air pressure 60Pa and discharge 50W.
[0106] The P(St-MMA-AA) microspheres were prepared with a diameter of 261nm, and then the P(St-MMA-AA) composite microspheres were centrifuged and washed three times, and then dispersed in deionized water to obtain a colloidal emulsion with a mass fraction of 15wt%.
[0107]Add polyacrylate adhesive and carbon black to the prepared colloidal emulsion at a mass ratio of 100:5:1, stir for 20 minutes with a magnetic stirrer, and then ultrasonically vibrate for 20 minutes with an ultrasonic machine to mix the prepared dyes u...
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