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Super-hydrophobic material and method for preparing super-hydrophobic material by using in-situ polymerizing method

A super-hydrophobic, thermal polymerization technology, applied in the direction of repelling liquid fibers, coatings, textiles and papermaking, etc., can solve the problems of complex preparation process, poor durability and high cost, and achieve low preparation cost and simple preparation process. Effect

Active Publication Date: 2017-09-01
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Currently disclosed methods include plasma technology combined with spraying methods to form a coating on the surface substrate (Chinese patent CN 105969174 A), and impregnate the surface with polycation electrolyte aqueous solution and polydimethylsiloxane solution (Chinese patent CN 106215461 A), depositing polydopamine and nano-silver particles (Chinese patent CN 104562709 A), using expensive low surface energy substances such as fluoride (Chinese patent CN 104213108 A), sol-gel method (Chinese patent CN105544187 A), etc., but At present, these methods for preparing superhydrophobic materials have problems such as complicated preparation process, high cost, and poor durability.

Method used

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  • Super-hydrophobic material and method for preparing super-hydrophobic material by using in-situ polymerizing method
  • Super-hydrophobic material and method for preparing super-hydrophobic material by using in-situ polymerizing method
  • Super-hydrophobic material and method for preparing super-hydrophobic material by using in-situ polymerizing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] An ionic liquid precursor with the following molecular formula

[0038]

[0039] Dissolve in dichloromethane to form a solution with a concentration of 1wt%, then add 0.5wt% of 20nm silicon dioxide particles, and ultrasonically disperse for 30min to form a uniform solution; soak the cotton fabric in this solution for 1min and take it out, then Placed in an oven at 120°C for 24 hours. The contact angle of the obtained superhydrophobic material is 155°.

Embodiment 2

[0041] A kind of molecular formula is the ionic liquid precursor of following formula

[0042]

[0043] Dissolve in methanol to form a solution with a concentration of 5wt%, then add 1wt% of 200nm alumina particles, ultrasonically disperse for 30min, and form a uniform solution; soak the copper mesh in this solution for 0.5min, take it out, and then place it at 110 ℃ oven reaction 12h. The contact angle of the obtained superhydrophobic material is 158°.

[0044] The difference between this embodiment and embodiment 1 is that the anion of the ionic liquid monomer is changed to Br - , the length of the longest carbon chain on the cationic group was changed to 16, the dosage was changed to 5wt%, the solvent was changed to methanol, the micro-nano particles were changed to 1wt% of 200nm alumina particles, the base material was changed to copper mesh, and the soaking time was shortened , the oven temperature was lowered, and the reaction time was halved, but the contact angle ...

Embodiment 3

[0046] A kind of molecular formula is the ionic liquid precursor of following formula

[0047]

[0048] Dissolve in ethanol to form a solution with a concentration of 10wt%, then add 1wt% of 300nm titanium dioxide particles, ultrasonically disperse for 30 minutes, and form a uniform solution; soak the stainless steel mesh in this solution for 30 minutes, take it out, and then place it in an oven at 150°C Medium reaction 60h. The resulting superhydrophobic metal mesh magnified 2500 times electron microscope picture as attached figure 2 As shown, its contact angle value is 157°.

[0049]The difference between this embodiment and embodiment 2 is that the anion of the ionic liquid monomer is changed to BF 4 - , the dosage is changed to 10wt%, the solvent is changed to ethanol, the base material is changed to stainless steel mesh, the micro-nano particles are changed to 300nm titanium dioxide particles, the soaking time is increased, the oven temperature is increased, and th...

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Abstract

The invention relates to a super-hydrophobic material prepared by an in-situ polymerizing method and a preparation method thereof. The preparation method comprises the following steps of dissolving a hydrophobic ion liquid or an ion compound with styrene groups into an organic solvent, fully mixing and dispersing with micro-nano particles, and impregnating a substrate material into the solution; then, fetching out the substrate, putting into an oven, generating in-situ heat polymerizing reaction at certain temperature, and reacting for a period of time, so as to obtain the super-hydrophobic material. The preparation method has the advantages that the preparation technology is simple, the cost of raw materials is low, and the obtaining is easy; the special instrument equipment is not needed, the utilization rate of atoms is 100%, and the super-hydrophobic material can be widely applied to any substrate; the durability is higher, and the super-hydrophobic material can be applied to complicated separating environments; the prepared super-hydrophobic material also has the super-oleophylic characteristic, can be prepared in a large-scale way, and can be used for separating oil from water.

Description

technical field [0001] The invention specifically relates to a method for preparing superhydrophobic materials based on in-situ thermal polymerization of hydrophobic ionic liquids or ionic compounds with styrene groups. Background technique [0002] With the increase of oil demand and the improvement of industrialization, the research of oil-water separation technology is of great significance to improve the quality of water and oil. In recent years, biomimetic superhydrophobic materials have attracted extensive attention due to their special surface wettability. Superhydrophobicity is a special kind of surface wettability. A superhydrophobic surface refers to a surface that is repellent to water and aqueous solutions. Water droplets cannot slide and spread on the surface and maintain a spherical rolling shape, thereby achieving the effect of rolling and self-cleaning. The lotus leaf in nature is a typical representative of this material. Superhydrophobic materials are wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/233D06M11/79D06M11/45D06M11/46C09D125/18C09D7/12C08J9/40C03C17/00D06M101/06
CPCC03C17/009C08J9/405C08K2003/2227C08K2003/2241C08K2201/011C09D125/18D06M11/45D06M11/46D06M11/79D06M15/233D06M2101/06D06M2200/12
Inventor 杨华伟张宏杰张吕鸿杨娜
Owner TIANJIN UNIV
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