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A method for preparing lanthanum calcium manganese oxide nanoparticle ribbon array

A lanthanum-calcium-manganese-oxygen nanometer and array technology, which is applied in nanotechnology, nanotechnology, nanotechnology for materials and surface science, etc., can solve the problem that the aspect ratio cannot be further expanded and is unfavorable for the preparation of nanoarrays with large aspect ratio To achieve the effect of enriching the expressiveness of magnetic properties, broadening the structural basis and performance basis

Active Publication Date: 2019-04-12
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Its most important structural feature is that it has a large aspect ratio, which can ensure that the prepared nano-array material also has a large aspect ratio feature, which can further strengthen the quantum effect at the nanoscale. For example, one-dimensional nano-film materials can only be used in The thickness reaches the nanometer level, and the dimensions in other directions are not at the micro-nano level, while the quantum dot materials are all at the nanometer level in three-dimensional dimensions, and there is no aspect ratio. Only in two-dimensional nanomaterials such as nanowires, nanotubes, and nanorods There is an aspect ratio relationship in the equal shape, the diameter of the lateral dimension is nanometer level, and the length of the longitudinal dimension is micronano level. The performance of nanomaterials can be enhanced by increasing the aspect ratio. At present, lanthanum calcium manganese oxide nanoarrays are prepared. Most of the research focuses on the preparation of arrays of nanowires and nanotubes, because the limitation of the template's own structure can only completely depend on its own aspect ratio structural properties, because the limitation of the growth conditions of the template will cause the aspect ratio to be unable to be further expanded, which is very Not conducive to the preparation of nanoarrays with large aspect ratio

Method used

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  • A method for preparing lanthanum calcium manganese oxide nanoparticle ribbon array
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  • A method for preparing lanthanum calcium manganese oxide nanoparticle ribbon array

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Embodiment 1

[0032] Embodiment 1: The method for preparing a large aspect ratio lanthanum calcium manganese oxide nanoparticle ribbon array in this embodiment specifically includes the following steps:

[0033] (1) Primary oxidation process: the raw material of aluminum foil is cut according to specifications, high-temperature annealing, degreasing with acetone alcohol and electrochemical polishing with perchloric acid mixture to obtain surface-pretreated aluminum foil. Anode, platinum electrode as cathode, in 0.25mol / L oxalic acid electrolyte, under 40V DC voltage, perform primary oxidation for 1 hour to obtain a template for the primary oxidation process;

[0034] (2) Deoxidation process: Use a mixed acid solution with a mass fraction of 1.5% chromic acid and a mass fraction of 6% phosphoric acid to chemically corrode and elute the template in the primary oxidation process of step (1) for 1 hour at 75°C, in which chromic acid and The volume ratio of phosphoric acid is =1:1, the process...

Embodiment 2

[0044] Embodiment 2: In this embodiment, the method for preparing a ribbon array of lanthanum-calcium-manganese-oxygen nanoparticles with a large aspect ratio includes the following steps:

[0045] (1) Primary oxidation process: the raw material of aluminum foil is cut according to specifications, high-temperature annealing, degreasing with acetone alcohol and electrochemical polishing with perchloric acid mixture to obtain surface-pretreated aluminum foil. Anode, platinum electrode as cathode, in 0.3mol / L oxalic acid electrolyte, under 42.5V DC voltage, perform primary oxidation for 2 hours to obtain a template for the primary oxidation process;

[0046] (2) Deoxidation process: Use a mixed acid solution with a mass fraction of 1.75% chromic acid and a mass fraction of 7.5% phosphoric acid to chemically corrode and wash the template in step (1) for 2 hours at 70°C, in which chromic acid and The volume ratio of phosphoric acid is =1:2, the process template of pits arranged i...

Embodiment 3

[0055] Embodiment 3: The method for preparing a large aspect ratio lanthanum calcium manganese oxide nanoparticle ribbon array in this embodiment specifically includes the following steps:

[0056] (1) Primary oxidation process: the raw material of aluminum foil is cut according to specifications, high-temperature annealing, degreasing with acetone alcohol and electrochemical polishing with perchloric acid mixture to obtain surface-pretreated aluminum foil. Anode, platinum electrode as cathode, in 0.4mol / L oxalic acid electrolyte, 50V DC voltage, perform primary oxidation for 3 hours to obtain a template for the primary oxidation process;

[0057] (2) Deoxidation process: use a mixed acid solution with a mass fraction of 2% chromic acid and a mass fraction of 10% phosphoric acid to chemically corrode and wash the template obtained in the primary oxidation process in the above step (1) for 3 hours at 80°C, where The volume ratio of chromic acid to phosphoric acid is =1:3, the...

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Abstract

The invention discloses a method for preparing an LCMO nano particle belt array, and belongs to the technical field of nanomaterial preparation. A large length-to-diameter ratio LCMO nano sol-gel particle belt array can be obtained through the matching of negative-pressure suction filtration and the middle-lower voltage DC preferential electro-deposition growing process, and then a quick-drying gel isothermal treatment technology is conducted on the large length-to-diameter ratio LCMO nano sol-gel particle belt array to obtain the large length-to-diameter ratio LCMO nano particle belt array. By the adoption of the technology, the technical limitation that only a low-order length-to-diameter ratio LCMO nano array can be prepared in the prior art is broken through, and meanwhile a good referential technological means is provided for solving the problem about how to efficiently increase the length-to-diameter ratio of nano array materials. The magnetic property expressive force of the LCMO nano array as a micro-nano physics basic research object is enriched, and meanwhile the structure foundation and property foundation of the LCMO nano array as a magnetic device are widened.

Description

technical field [0001] The invention relates to a method for preparing a ribbon array of lanthanum calcium manganese oxide nanoparticles, and belongs to the technical field of preparing perovskite giant magnetoresistance nano arrays. Background technique [0002] Anodized aluminum templates are currently one of the most widely used hard templates, and the most widely used is the preparation or synthesis of nanomaterials. The anodized aluminum template not only has good space confinement ability, but also has a stable structure and can withstand high temperature, high pressure and strong acid and alkali environment. Its most important structural feature is that it has a large aspect ratio, which can ensure that the prepared nano-array material also has a large aspect ratio feature, which can further strengthen the quantum effect at the nanoscale. For example, one-dimensional nano-film materials can only be used in The thickness reaches the nanometer level, and the dimensions...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D11/10C25D11/12C25D11/16C25D9/08B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00C25D9/08C25D11/045C25D11/10C25D11/12C25D11/16
Inventor 陈清明杨盛安张辉刘翔金菲
Owner KUNMING UNIV OF SCI & TECH