A method for preparing lanthanum calcium manganese oxide nanoparticle ribbon array
A lanthanum-calcium-manganese-oxygen nanometer and array technology, which is applied in nanotechnology, nanotechnology, nanotechnology for materials and surface science, etc., can solve the problem that the aspect ratio cannot be further expanded and is unfavorable for the preparation of nanoarrays with large aspect ratio To achieve the effect of enriching the expressiveness of magnetic properties, broadening the structural basis and performance basis
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Embodiment 1
[0032] Embodiment 1: The method for preparing a large aspect ratio lanthanum calcium manganese oxide nanoparticle ribbon array in this embodiment specifically includes the following steps:
[0033] (1) Primary oxidation process: the raw material of aluminum foil is cut according to specifications, high-temperature annealing, degreasing with acetone alcohol and electrochemical polishing with perchloric acid mixture to obtain surface-pretreated aluminum foil. Anode, platinum electrode as cathode, in 0.25mol / L oxalic acid electrolyte, under 40V DC voltage, perform primary oxidation for 1 hour to obtain a template for the primary oxidation process;
[0034] (2) Deoxidation process: Use a mixed acid solution with a mass fraction of 1.5% chromic acid and a mass fraction of 6% phosphoric acid to chemically corrode and elute the template in the primary oxidation process of step (1) for 1 hour at 75°C, in which chromic acid and The volume ratio of phosphoric acid is =1:1, the process...
Embodiment 2
[0044] Embodiment 2: In this embodiment, the method for preparing a ribbon array of lanthanum-calcium-manganese-oxygen nanoparticles with a large aspect ratio includes the following steps:
[0045] (1) Primary oxidation process: the raw material of aluminum foil is cut according to specifications, high-temperature annealing, degreasing with acetone alcohol and electrochemical polishing with perchloric acid mixture to obtain surface-pretreated aluminum foil. Anode, platinum electrode as cathode, in 0.3mol / L oxalic acid electrolyte, under 42.5V DC voltage, perform primary oxidation for 2 hours to obtain a template for the primary oxidation process;
[0046] (2) Deoxidation process: Use a mixed acid solution with a mass fraction of 1.75% chromic acid and a mass fraction of 7.5% phosphoric acid to chemically corrode and wash the template in step (1) for 2 hours at 70°C, in which chromic acid and The volume ratio of phosphoric acid is =1:2, the process template of pits arranged i...
Embodiment 3
[0055] Embodiment 3: The method for preparing a large aspect ratio lanthanum calcium manganese oxide nanoparticle ribbon array in this embodiment specifically includes the following steps:
[0056] (1) Primary oxidation process: the raw material of aluminum foil is cut according to specifications, high-temperature annealing, degreasing with acetone alcohol and electrochemical polishing with perchloric acid mixture to obtain surface-pretreated aluminum foil. Anode, platinum electrode as cathode, in 0.4mol / L oxalic acid electrolyte, 50V DC voltage, perform primary oxidation for 3 hours to obtain a template for the primary oxidation process;
[0057] (2) Deoxidation process: use a mixed acid solution with a mass fraction of 2% chromic acid and a mass fraction of 10% phosphoric acid to chemically corrode and wash the template obtained in the primary oxidation process in the above step (1) for 3 hours at 80°C, where The volume ratio of chromic acid to phosphoric acid is =1:3, the...
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Abstract
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