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Preparing method for oxygen-free copper belt used for solar cell module

A technology of solar cells and oxygen-free copper, applied in the direction of liquid chemical plating, coating, metal material coating process, etc., can solve the problems of serious surface oxidation, uneven thickness, easy discoloration of tin-plated copper strips, etc., to prevent Oxidation, high purity effect

Inactive Publication Date: 2017-11-10
江苏奔拓电气科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the photovoltaic cell functional component materials used in solar cells are tin alloy copper strips, and the coating alloys are mostly lead-containing tin alloys, which brings unavoidable lead pollution in the production and use of tin alloy copper strips. and poisoning problems, which is not conducive to human health and environmental protection
[0003] The tinned copper strip produced by the prior art method is before tinning because the copper strip surface pollutants and the oxide layer are not completely removed, the surface oxidation is serious, the appearance is uneven, and the thickness is uneven, so that the conductivity is poor when used after tinning, And the coating is easy to fall off; at the same time, after tin coating, not only the color of the tinned copper strip is easy to change, but also the surface of the tinned copper strip is prone to piles of tin or gaps, etc., which seriously affect the electrical performance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0019] Weigh 2kg of red copper sheet and cut it into small pieces of 3cm×1cm. Place the cut pieces in a beaker filled with 2L hydrochloric acid with a mass fraction of 15%. After soaking for 40min, filter to obtain filter residue. After washing with ethanol for 5 times, put the cleaned filter residue in a tube furnace with an induction furnace connected to the valve at the end, and then use an air pump to evacuate the tube furnace to a vacuum of 1.5kPa. Inject argon, control the rate of argon inflow to 100mL / min, and let it in for 20min. Into the light atomic weight gas for 10 to 15 minutes, and after vacuuming the vacuum induction furnace to 80Pa, open the valve at the end of the tube furnace to allow the gas in the tube furnace to enter the vacuum induction furnace for 15 minutes, then close the tube furnace The valve at the end allows the gas to be cooled into powder in the vacuum induction furnace, and then the vacuum induction furnace is programmed to heat up to 1200°C at...

example 2

[0021]Weigh 1 kg of red copper sheet and cut it into small pieces of 3cm×1cm. Place the cut pieces in a beaker filled with 1L hydrochloric acid with a mass fraction of 15%. After soaking for 30 minutes, filter to obtain the filter residue. After washing with ethanol for 3 times, put the cleaned filter residue in a tube furnace with an induction furnace connected to the valve at the end, and then use an air pump to evacuate the tube furnace to a vacuum degree of 1.3kPa, and then pass it into the tube furnace. Inject nitrogen, control the rate of nitrogen inflow to 100mL / min, and pass in for 15min. After the nitrogen inflow is completed, heat the tube furnace to 1800°C, keep warm for 20min, and continue to flow in the tube furnace at a rate of 100mL / min. Nitrogen for 10 minutes, and after vacuuming the vacuum induction furnace to 60Pa, open the valve at the end of the tube furnace to allow the gas in the tube furnace to enter the vacuum induction furnace for 10 minutes, then clos...

example 3

[0023] Weigh 2kg of red copper sheet and cut it into small pieces of 3cm×1cm. Place the cut pieces in a beaker filled with 1L of hydrochloric acid with a mass fraction of 15%. After soaking for 35min, filter to obtain the filter residue. After washing with ethanol for 4 times, put the cleaned filter residue in a tube furnace with an induction furnace connected to the valve at the end, and then use an air pump to vacuumize the tube furnace to a vacuum of 1.4kPa, and then pass it into the tube furnace. Inject nitrogen, control the rate of nitrogen inflow to 100mL / min, and let it in for 17min. After the inflow of nitrogen is over, heat the tube furnace to 1850°C, keep it warm for 25min, and continue to feed in the tube furnace at a rate of 100mL / min. Argon for 12 minutes, and after vacuuming the vacuum induction furnace to 70Pa, open the valve at the end of the tube furnace to allow the gas in the tube furnace to enter the vacuum induction furnace. After 12 minutes, close the valv...

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Abstract

The invention discloses a preparing method for an oxygen-free copper belt used for a solar cell module and belongs to the technical field of solar equipment modules. The preparing method includes the steps that firstly, a red copper sheet is cut and subjected to impurity removing, and then the red copper sheet is put into a tubular furnace to be heated so that copper can become copper steam; then the copper steam is led into a vacuum induction furnace to be condensed and then melted, and the melt is subjected to vacuum upcasting, and a non-oxygen copper bar is obtained; then the non-oxygen copper bar is subjected to operation such as extruding, annealing and impurity removing, and a blank obtained after impurity removing is obtained; then ammonium molybdate and ethyl orthosilicate serve as raw materials, are hydrolyzed and then react with ammonium hydroxide to generate sediment, polyving alcohol can be attached to the surface of the blank, and then the sediment is adsorbed under the chemical adsorption effect; and then calcination is conducted, the polyving alcohol is reduced, a layer of molybdenum silicide film is formed on the surface of the blank, and the copper belt is prevented from being oxidized. By means of the preparing method, the prepared non-oxygen copper belt used for the solar cell module is uniform in thickness and not likely to disengage, the electric conduction performance between the non-oxygen copper belt and a battery sheet is good, and the service life of the module is prolonged.

Description

technical field [0001] The invention belongs to the technical field of solar equipment components, and in particular relates to a preparation method of an oxygen-free copper strip for solar cell components. Background technique [0002] Due to the shortage of energy, human beings must develop new energy and high-efficiency energy-saving materials as soon as possible. This is a major issue that must be solved in the 21st century. As a widely distributed, inexhaustible and inexhaustible green, pollution-free and clean energy, solar energy is the preferred energy source for the sustainable development of human society. A solar cell is a device that uses the photoelectric effect to convert solar energy into electrical energy. Copper strip is the base material for making tin-coated solder strips of solar cell modules, which is used for the connection between cells of photovoltaic modules and is one of the key components of solar cells. It is required to have good thermal conduc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B15/14C23C18/12C22F1/08
CPCC22B15/006C22B15/0028C22F1/08C23C18/1204C23C18/1241
Inventor 黄菠莉王维李雪晴
Owner 江苏奔拓电气科技有限公司