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Metal cleaning agent added with functional modified graphene and preparing method of metal cleaning agent

A metal cleaning agent and graphene technology, applied in the field of metal cleaning agents, can solve problems such as high cost, incomplete cleaning, complex formula, etc., and achieve the effects of reducing surface tension, good wax removal effect, and strong adsorption capacity

Inactive Publication Date: 2017-12-26
郴州国盛新材科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the prior art, water-based metal cleaning agents are often mainly based on wax and oil removal, and the effect on metal ions (such as copper ions, iron ions) and subsequent anti-corrosion treatment on the metal surface is not obvious, and the dispersion is unstable, resulting in poor cleaning. Thoroughly, in order to solve the above problems, complexing agents and penetrating agents are often added to the cleaning agent to achieve the effect of adsorbing metal ions, but on the one hand, the effect is not obvious, on the other hand, the formula is complicated and the cost is high

Method used

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  • Metal cleaning agent added with functional modified graphene and preparing method of metal cleaning agent
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  • Metal cleaning agent added with functional modified graphene and preparing method of metal cleaning agent

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Embodiment 1

[0035] The present embodiment provides a kind of preparation method of triethanolamine functionalized graphene, comprises the following steps:

[0036] S1. Preparation of triethanolamine functionalized graphene:

[0037] S11. Adopt graphene oxide as raw material, be dissolved in deionized water, concentration is 2mg / L, pH is 1, ultrasonic dispersion 30min, obtain uniform dispersion liquid, uniform dispersion liquid and triethanolamine are mixed by volume ratio 20:1, obtain mixed solution;

[0038] S12. Heat the mixed solution in step S11 in a water bath at 70°C for 2 hours, centrifuge the reacted suspension, wash with absolute ethanol and deionized water until neutral, and dry at 60°C to obtain triethanolamine functionalized Graphene.

Embodiment 2

[0040] The present embodiment provides a kind of preparation method of triethanolamine functionalized graphene, comprises the following steps:

[0041] S1. Preparation of triethanolamine functionalized graphene:

[0042] S11. Adopt graphene oxide as raw material, be dissolved in deionized water, concentration is 3mg / L, pH is 2, ultrasonic dispersion 30min, obtain uniform dispersion liquid, uniform dispersion liquid and triethanolamine are mixed by volume ratio 25:1, obtain mixed solution;

[0043] S12. Heat the mixed solution in step S11 in a water bath at 90°C for 5 hours, centrifuge the reacted suspension, wash with absolute ethanol and deionized water until neutral, and dry at 70°C to obtain triethanolamine functionalized Graphene.

Embodiment 3

[0045] The present embodiment provides a kind of preparation method that adds the metal cleaning agent of functionalized modified graphene, comprises the following steps:

[0046] S1. adopt the triethanolamine functionalized graphene prepared by embodiment 1 as raw material;

[0047] S2. Add 4wt% triethanolamine functionalized graphene, 10t% coconut oil fatty acid diethanolamide, 2wt% fatty alcohol polyoxyethylene ether sodium sulfate, 1wt% ten dialkyl sodium sulfate, 1wt% of benzotriazole, 0.1wt% of sodium hydroxymethylglycinate and the rest of water, stirred for 1-2 hours at a stirring speed of 80-100r / min, to a black uniform liquid, and finally obtained functionalized modified graphite Alkene metal cleaner.

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Abstract

The invention relates to a metal cleaning agent, and discloses a metal cleaning agent added with functional modified graphene and a preparing method of the metal cleaning agent. The metal cleaning agent is composed of 4-15wt% of triethanolamine functional graphene, 13-25wt% of surfactant, 1-2wt% of metal corrosion inhibitor, 0.1-0.8wt% preservative and the balance water. According to the metal cleaning agent, the triethanolamine functional graphene is creatively used to be added into the metal cleaning agent, triethanolamine of the triethanolamine functional graphene and the graphene are bonded as covalent bond, and the surface of the metal cleaning agent contains a large amount of tertiary amine nitrogen and hydroxyl active functional groups; and amino ionic liquid functional graphene achieves graphene modification through the non-covalent interaction between imidazole rings and graphite rings, the graphene has the super large specific surface area, the strong complexing effect is achieved after the grapheme and the triethanolamine are functionalized, so that the strong adsorption capacity is achieved, the hydrophilic and lipophilicity of the triethanolamine are retained, the strong adsorption capacity also can be achieved, and the metal cleaning agent is used without matching of an additional complexing agent.

Description

technical field [0001] The invention relates to a metal cleaning agent, more specifically, to a metal cleaning agent added with functionalized modified graphene and a preparation method thereof. Background technique [0002] Metal cleaning agents are widely used in industrial production, and are often used for surface degreasing and descaling before and after metal processing, as well as cleaning processes before assembly or packaging of finished products. In the electronics industry, cleaning agents must also be used to remove harmful residues after soldering printed circuit boards. In addition, metal cleaning agents are often used in the maintenance process of mechanical equipment. [0003] At present, the commonly used metal cleaning agents are divided into solvent type, semi-solvent type and water-based type. Among solvent-based metal cleaners, petroleum solvents are flammable, explosive, and a waste of resources. Chlorofluorocarbons are the most commonly used solvent...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23G1/26
CPCC23G1/26
Inventor 李丽萍
Owner 郴州国盛新材科技有限公司
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