A kind of composite film and preparation method thereof
A technology of composite film and mass parts, applied in the direction of chemical instruments and methods, synthetic resin layered products, layered products, etc., can solve the problems of low tensile strength, low elongation at break and impact strength, softness and stiffness of products and poor barrier properties, to achieve the effects of high vertical and horizontal strength, reduced dosage, and high elongation at break
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Embodiment 1
[0028] The present embodiment provides a kind of composite film, and the thickness of described composite film is 0.04mm, comprises inner layer, middle layer and outer layer arranged successively, and described inner layer comprises the PBAT of 50 mass parts, the thermoplastic starch of 30 mass parts, 5 Parts by mass of ethylene acrylic resin, 8 parts by mass of nano-calcium carbonate and 1 part by mass of tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride copolymer, the middle layer includes 90 parts by mass of low-density polyethylene, 10 parts by mass of Metallocene polyethylene and 5 mass parts of simethicone, the outer layer includes 85 mass parts of PA6 and 5 mass parts of PE-g-MAH, the inner layer: the middle layer: the thickness ratio of the outer layer is 3: 1:1. The metallocene polyethylene in the middle layer has high molecular weight, narrow molecular weight distribution, less branched chain, low density, and high purity. Mixing it with low-density polyeth...
Embodiment 3
[0036] The present embodiment provides a kind of composite film, and the thickness of described composite film is 0.1mm, comprises inner layer, middle layer and outer layer arranged in sequence, and described inner layer comprises the thermoplastic starch of 70 mass parts, the thermoplastic starch of 50 mass parts, 3 The PE-g-GMA of mass parts, the nano barium sulfate of 5 mass parts and the microcrystalline wax of 3 mass parts, described middle layer comprises the low density polyethylene of 80 mass parts, the metallocene polyethylene of 20 mass parts and 2 mass parts polyvinyl alcohol, the outer layer includes 95 parts by mass of PA6 / PA66 and 5 parts by mass of PE-g-MAH, the mass ratio of PA6:PA66 in the PA6 / PA66 is 40:45, and the inner layer: The thickness ratio of middle layer: outer layer is 2.5:0.8:1.5.
[0037]The present embodiment also provides a kind of preparation method of above-mentioned composite film, the above-mentioned 70 mass parts of PBAT, 50 mass parts of t...
Embodiment 4
[0039] The present embodiment provides a kind of composite film, and the thickness of described composite film is 0.07mm, comprises inner layer, middle layer and outer layer arranged in sequence, and described inner layer comprises the PBAT of 60 mass parts, the thermoplastic starch of 40 mass parts, 4 parts by mass of siloxane, 7 parts by mass of nano kaolin and 2 parts by mass of ethylene-tetrafluoroethylene copolymer, the middle layer includes 85 parts by mass of low density polyethylene, 15 parts by mass of metallocene polyethylene and 4 parts by mass of Parts of sodium carboxymethyl starch, the outer layer includes 90 parts by mass of PA6 / PA66 and 8 parts by mass of PE-g-ST, and the mass ratio of PA6:PA66 in the PA6 / PA66 is 75:25, the The thickness ratio of inner layer: middle layer: outer layer is 3:1.5:0.8.
[0040] This embodiment also provides a method for preparing the above-mentioned composite film. The above-mentioned inner layer materials, middle layer materials a...
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