Palladium compound being stable in acetylene atmosphere at high temperature, and application thereof
A complex and palladium compound technology, applied in chemical/physical processes, physical/chemical process catalysts, catalyst activation/preparation, etc., can solve the problems of active component loss, catalyst activity decline, loss, etc., to achieve convenient operation and preparation simple effect
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Embodiment 1
[0045] The particle size of activated carbon is 40 mesh, the ash content is 5.0wt%, and the specific surface area is 900m 2 / g, pore volume 1.0mL / g, and treated with 300ml of 10wt% hydrochloric acid at 20°C for 3h, and then dried at 110°C for 12h to obtain the desired carrier.
[0046] 50ml of K 2 PdCl 4 solution (wherein the Pd content is 0.001g / ml) and 10ml of Na 2 The S solution (wherein the S content is 0.00015g / ml) was mixed evenly, and an appropriate amount of deionized water was added to make the volume to 100ml, and was added dropwise to 100g spherical activated carbon carrier at 30°C under the action of ultrasonic waves. Immersed for 5h under the action of ultrasonic waves, and then the catalyst was vacuum dried at 110°C for 5h, and the catalyst was tested to be PdS 0.1 Cl 1.8 / AC, wherein the Pd loading (relative to the mass of the support) is 0.05wt%, and the loading of S element (relative to the mass of the support) is 0.0015wt%.
[0047] Take 2g of this catal...
Embodiment 2
[0049] γ-Al 2 o 3 The particle size is 20 mesh and the specific surface area is 200m 2 / g, pore volume 0.6mL / g. 20ml of Na 2 PdCl 4 solution (in which the Pd content is 0.05g / ml) and 10ml of KHS solution (in which the S content is 0.03g / ml) are mixed evenly, add an appropriate amount of deionized water to make the volume to 60ml, and add it drop by drop under the action of ultrasonic waves at 60°C to 100g columnar γ-Al 2 o 3 Carrier, then the catalyst was dried in vacuum at 90°C for 10h, and the catalyst was detected to be PdS 1.9 Cl 0.1 / γ-Al 2 o 3 , wherein the loading of Pd (relative to the mass of the support) is 1 wt%, and the loading of S element (relative to the mass of the support) is 0.3 wt%.
[0050] Take 2g of this catalyst and apply it to the hydrochlorination of acetylene in a fixed bed reactor. The reaction conditions are: temperature 180°C, pressure 0.2MPa, n(HCl) / n(C 2 h 2 )=1.2 / 1, acetylene space velocity 60h -1 . At the beginning of the reaction...
Embodiment 3
[0052] SiO 2 The particle size is 80 mesh and the specific surface area is 100m 2 / g, pore volume 0.6mL / g. 50ml of (NH 4 ) 2 PdCl 4 solution (wherein the Pd content is 0.008g / ml) and 10ml of (NH 4 ) 2 S 2 o 3 The solution (in which the S content is 0.01g / ml) was mixed evenly, and was added dropwise to 100g columnar SiO 2 Carrier, then the catalyst was dried in vacuum at 80°C for 15h, and the catalyst was detected to be PdS 0.8 Cl 0.4 / SiO 2, wherein the loading of Pd (relative to the mass of the support) is 0.4wt%, and the loading of S element (relative to the mass of the support) is 0.1wt%.
[0053] Take 2g of this catalyst and apply it to the hydrochlorination of acetylene in a fixed bed reactor. The reaction conditions are: temperature 150°C, pressure 0.3MPa, n(HCl) / n(C 2 h 2 ) = 1.05 / 1, acetylene space velocity 10h -1 . At the beginning of the reaction, the conversion rate of acetylene was 99.9%, and the selectivity of vinyl chloride was 99.9%. After 2000 ho...
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