A synthesis gas preparation system and method thereof
A preparation system and synthesis gas technology, applied in the field of synthesis gas preparation system, can solve the problems of high energy consumption per unit output, insufficient utilization of raw materials, low conversion efficiency, etc., to improve conversion efficiency and yield, reduce energy consumption, and ensure safety sex high effect
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Embodiment 1
[0059] Such as figure 1 As shown, the present embodiment provides a synthesis gas preparation system, which includes a solid oxide electrolytic cell 1, a feed gas supply system, a molten salt supply system and a synthesis gas mixing chamber 4, in addition, an external direct current Power supply 5; the cathode of the solid oxide electrolytic cell 1 is connected to the negative pole of the external DC power supply 5, the anode of the solid oxide electrolytic cell 1 is connected to the positive pole of the external DC power supply 5, and the raw material gas supply system includes steam generation device 21, shielding gas cylinder set 22 and gas mixing chamber 23, the steam generator 21 and the shielding gas cylinder set 22 are respectively connected to the gas mixing chamber 23, the gas mixing chamber 23 and the The cathode chamber of the solid oxide electrolytic cell 1 is connected, and the molten salt supply system includes a carbon powder / molten salt mixer 31 and a molten sa...
Embodiment 2
[0068] The synthesis gas preparation system and the structure of the solid oxide electrolytic cell in this embodiment are consistent with those in Embodiment 1, the difference is that this embodiment includes multiple tubular solid oxide electrolytic cells, and the specific parameters of the electrolytic cells are different from the synthesis gas preparation method.
[0069] Such as image 3 As shown, the solid oxide electrolytic cell 1 is arranged in a hot box, and the hot box includes a box body 61 and an insulating layer 62 arranged on the inner wall of the box body, and the shell material of the box body 61 is a steel plate. The thickness of the steel plate is 20mm, the material of the insulation layer is quartz wool, and the thickness of the insulation layer is 10cm. In the synthesis gas reactor in the present embodiment, 10 series-connected tubular solid oxide electrolytic cells ( image 3 The cross-section does not represent all tubular solid oxide electrolytic cells),...
Embodiment 3
[0073] The structure of the synthesis gas preparation system and the solid oxidation electrolytic cell of this embodiment is consistent with that of Embodiment 1, the difference is that:
[0074] (1) In the synthesis gas preparation system of the present embodiment, the anode is an LSM thin film electrode;
[0075] (2) In the synthesis gas preparation method of the present embodiment, the molten salt is CaCl 2 / NaCl mixed system molten salt, wherein the Fe catalyst content is 0.5%, and the operating temperature of the solid oxide electrolytic cell is 900°C.
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