Method for green and efficient preparation of graphite phase carbon nitride nanosheet and application

A technology of graphitic carbon nitride and nanosheets, applied in chemical instruments and methods, catalyst activation/preparation, inorganic chemistry, etc. To improve the photocatalytic performance, reduce the synthesis cost, and improve the separation of electrons and holes

Active Publication Date: 2018-07-13
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Mainly use metal to catalyze the steam reforming reaction, so as to accelerate the exfoliation of layered graphitic carbon nitride by water vapor, and then quickly and efficiently synthesize graphitic car

Method used

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  • Method for green and efficient preparation of graphite phase carbon nitride nanosheet and application
  • Method for green and efficient preparation of graphite phase carbon nitride nanosheet and application
  • Method for green and efficient preparation of graphite phase carbon nitride nanosheet and application

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Embodiment 1

[0023] (1) Take 10 g of melamine and add it to a ceramic crucible with a cover, and carry out high-temperature polymerization in a muffle furnace. The polymerization temperature is 550 ° C, and the temperature is kept at a constant temperature for three hours. Yellow powder, graphite phase carbon nitride;

[0024] (2) Take 0.3 g of the above-mentioned graphitic carbon nitride, disperse it into 100 mL of water, add 0.5 mL of chloroplatinic acid (the concentration of chloroplatinic acid is 1 g / 100 mL), and irradiate with a xenon lamp light source for 4 h after vacuuming. 15°C; after the reaction is completed, the above sample is washed with ethanol and water to obtain Pt / graphite phase carbon nitride;

[0025] (3) Take 0.2 g of Pt / graphite-phase carbon nitride prepared in step 2), and feed water vapor / Ar mixed gas into the tube furnace, the flow rate of the mixed gas is 100 mL / min, and the pumping amount of water vapor is (6 mL / h), the flow rate of argon was (99.9 mL / min); the ...

Embodiment 2

[0028] (1) Take 10 g of melamine and add it to a ceramic crucible with a cover, and carry out high-temperature polymerization in a muffle furnace. The polymerization temperature is 550 ° C, and the temperature is kept at a constant temperature for three hours. After cooling, a yellow bulk graphite phase carbon nitride is obtained; the sample is ground to obtain Yellow powder, graphite phase carbon nitride;

[0029] (2) Take 0.3 g of the above-mentioned graphitic carbon nitride, disperse it into 100 mL of water, add 0.5 mL of chloroplatinic acid (the concentration of chloroplatinic acid is 1 g / 100 mL), and irradiate with a xenon lamp light source for 4 h after vacuuming. (12 ℃); after the reaction is completed, the above samples are washed with ethanol and water to obtain Pt / graphite carbon nitride;

[0030] (3) Take 0.3 g of Pt / graphite-phase carbon nitride prepared in step 2), and feed water vapor / Ar mixed gas into the tube furnace, the flow rate of the mixed gas is 100 mL / mi...

Embodiment 3

[0032] (1) Take 10 g of melamine and add it to a ceramic crucible with a cover, and carry out high-temperature polymerization in a muffle furnace. The polymerization temperature is 550 ° C, and the temperature is kept at a constant temperature for three hours. After cooling, a yellow bulk graphite phase carbon nitride is obtained; the sample is ground to obtain Yellow powder, graphite phase carbon nitride;

[0033] (2) Take 0.3 g of the above graphitic carbon nitride, disperse it into 100 mL of water, add 0.5 mL of chloroplatinic acid (the concentration of chloroplatinic acid is 1 g / 100 mL), and irradiate with xenon light source for 4 hours after vacuuming. The reaction temperature is (18°C); after the reaction was completed, the above samples were washed with ethanol and water to obtain Pt / graphite phase carbon nitride;

[0034] (3) Take 0.3 g of Pt / graphite-phase carbon nitride prepared in step 2), and feed water vapor / Ar mixed gas into the tube furnace, the flow rate of the...

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Abstract

The invention discloses a method for green and efficient preparation of a graphite phase carbon nitride nanosheet and application. The method comprises the following steps: taking a layered graphite phase carbon nitride material as a raw material, and modifying Pt nanoparticles on the surface of graphite phase carbon nitride, so as to obtain Pt/graphite phase carbon nitride; putting the Pt/graphite phase carbon nitride into a tube furnace, and feeding high-temperature water vapor to treat the Pt/graphite phase carbon nitride, so as to obtain the graphite phase carbon nitride nanosheet. The method is simple in processes, mild and controllable in conditions, and high in the yield of the graphite phase carbon nitride nanosheet. The specific surface area of the formed graphite phase carbon nitride nanosheet is obviously increased, charge separation is obviously improved, and the graphite phase carbon nitride nanosheet has excellent photocatalytic performance.

Description

technical field [0001] The invention belongs to the technical field of nanomaterial preparation, and in particular relates to a green and high-efficiency preparation method and application of graphite-phase carbon nitride nanosheets. Background technique [0002] Carbon nitride has five allotropes, namely α phase, β phase, cubic phase, quasi-cubic phase and graphite phase, among which the graphite phase structure is the most stable. Graphite carbon nitride is widely used in photocatalytic pollutant degradation, photocatalytic water splitting for hydrogen production, photocatalytic organic synthesis, photocatalytic carbon dioxide reduction, etc. research field has been widely used. Recently, graphitic carbon nitride has gradually been applied in solar cells, fuel cells, thermal catalysis, biomedicine, etc. However, graphitic carbon nitride still has some problems as a photocatalyst, such as small specific surface area, high exciton binding energy, and limited response to vi...

Claims

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Application Information

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IPC IPC(8): B01J27/24B01J37/08B01J37/02B01J37/34B01J37/10C01B3/04
CPCB01J27/24B01J35/0013B01J35/004B01J37/0201B01J37/08B01J37/10B01J37/344C01B3/042Y02E60/36
Inventor 王心晨杨朋举汪锐睿
Owner FUZHOU UNIV
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