Preparation method of functionalized polymer microspheres
A technology of polymer microspheres and functionalization, applied in the field of functional polymers, can solve the problems of cumbersome process, complicated process, solvent pollution, etc., and achieve the effect of energy saving in the preparation process and high product purity
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Example Embodiment
[0019] Example 1
[0020] First dissolve 0.08 g of 2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide as the initiator in 8 g of trimethylolpropane triacrylate, and place it in a glass reaction vessel containing 120 mL of deionized water Among them, use a disperser to emulsify the mixed solution for 20 minutes (set the rotation speed to 2500 rpm and maintain it until the end of the light), and add 20 mL of an aqueous solution of branched polyethyleneimine (concentration of 0.05 kg / L); the ultraviolet radiation intensity is 120 mW / cm 2 Under irradiation for 40 minutes, the resulting product was washed, centrifuged, and dried to obtain polymer microspheres with a particle size of 2-8μm and a yield of 82%. figure 1 SEM photo. Take 2g of the obtained polymer microspheres and place them in a 20mL branched polyethyleneimine aqueous solution (with a concentration of 0.1kg / L) in a glass reaction vessel, pour nitrogen into the system for 10 minutes and then seal, heat it at 80°C for 10 ho...
Example Embodiment
[0021] Example 2
[0022] Dissolve 0.1g of the initiator 2,4,6-trimethylbenzoylphosphonate ethyl ester in 6g of trimethylolpropane trimethacrylate, and place it in a glass reaction vessel containing 100mL of deionized water. Emulsify the disperser for 15min (rotation speed is set to 2500rpm, and maintain until the end of the light), add 10mL of aqueous solution of branched polyethyleneimine (concentration of 0.05kg / L); under the ultraviolet radiation intensity of 100mW / cm 2 Under irradiation for 60 minutes, the obtained product is washed, centrifuged, and dried to obtain polymer microspheres with a particle size of 8-15 μm and a yield of 78%. Place 1g of the obtained polymer microspheres in a glass reaction vessel containing 20mL of branched polyethyleneimine aqueous solution, pour nitrogen into the system for 8 minutes and then seal, heat at 60℃ for 8h, and take 1g of the obtained polymer microspheres and centrifuge Wash multiple times and dry to obtain the target product.
Example Embodiment
[0023] Example 3
[0024] Dissolve 0.5g of initiator bis(2,4,6-trimethylbenzoyl)phenyl phosphine oxide in 10g of 1,6-hexanediol diacrylate and place it in a glass reaction vessel containing 50mL of deionized water Among them, the disperser is emulsified for 15 minutes (the rotation speed is set to 2300 rpm, and maintained until the end of the light), and 25 mL of an aqueous solution of branched polyethyleneimine (concentration of 0.05 kg / L) is added; the ultraviolet radiation intensity is 20 mW / cm 2 Under irradiation for 90 minutes, the obtained product was washed, centrifuged and dried to obtain polymer microspheres with a particle size of 40-80 μm and a yield of 76%. Take 0.8g of the obtained polymer microspheres and place them in a 20mL branched polyethyleneimine aqueous solution (concentration of 0.1kg / L) in a glass reaction vessel, pour nitrogen into the system for 5 minutes, then seal, and heat at 100°C for 1 hour. The obtained polymer microspheres are centrifuged, washed s...
PUM
Property | Measurement | Unit |
---|---|---|
Particle size | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap