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Novel flue gas desulfurization and denitrification process

A technology for desulfurization, denitrification, and flue gas, which is used in climate change adaptation, climate sustainability, and air quality improvement. It can solve the problems of immature process, secondary pollution, high investment and maintenance costs, achieve good economic benefits, reduce The effect of NO content and good economic benefits

Inactive Publication Date: 2018-08-17
陈琪雯
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the commonly used methods often separate desulfurization and denitrification, resulting in huge investment in equipment, large site occupation, and high investment and maintenance costs. Integrated methods include activated carbon method, SNOX process, electron beam method, etc., but at present, these methods all have problems such as high cost, immature process, and many problems in industrialization
[0004] Desulfurization and denitrification technology can be divided into wet method and dry method according to the state of use of desulfurization and denitrification agents. The wet method mainly includes limestone / gypsum method, ammonia method, magnesium method, and seawater desulfurization method, but there are often complex systems and large footprints. , the equipment is severely corroded, and a large amount of waste liquid is difficult to handle, etc.
The dry desulfurization process uses powdered desulfurization and denitrification agents mixed with flue gas for desulfurization and denitrification. Desulfurization and denitrification agents are often expensive, and the dust generated can easily enter the atmosphere and cause secondary pollution.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The sulfur dioxide content of the original flue gas is 1000-3000 mg / Nm 3 , Nitrogen oxide content is 200-500 mg / Nm 3、 The flow rate is 1-4m / s and the temperature is 90-120°C.

[0030] 1. Pre-dust removal step: pre-dedust the raw flue gas to remove most of the dust, thereby forming pre-dust removal flue gas;

[0031] 2. Pre-oxidation stage: Mix 50 parts of hydrogen peroxide with 50 parts of water, and then spray in the middle and lower sections of the chimney to remove part of SO 2 , NO 2 etc. At the same time, oxygen can be generated to oxidize NO to produce easily soluble NO2, and sulfuric acid, sulfurous acid, nitric acid, and nitrous acid solutions are prepared by this method; the content of hydrogen peroxide is dynamically adjusted according to the content of NO in the flue gas.

[0032] 3. Desulfurization and denitrification step: mix the dry powder desulfurization and denitrification agent with the flue gas treated in 2, and then transport it to the flue gas ab...

Embodiment 2

[0036] The sulfur dioxide content of the original flue gas is 1000-3000 mg / Nm 3 , Nitrogen oxide content is 200-500 mg / Nm 3、 The flow rate is 1-4m / s and the temperature is 90-120°C.

[0037] 1. Pre-dust removal step: pre-dedust the raw flue gas to remove most of the dust, thereby forming pre-dust removal flue gas;

[0038] 2. Pre-oxidation stage: mix 60 parts of hydrogen peroxide with 40 parts of water, and then spray in the middle and lower sections of the chimney to remove part of SO 2 , NO 2 etc. At the same time, oxygen can be generated to oxidize NO to produce easily soluble NO2, and sulfuric acid, sulfurous acid, nitric acid, and nitrous acid solutions are prepared by this method; the content of hydrogen peroxide is dynamically adjusted according to the content of NO in the flue gas.

[0039] 3. Desulfurization and denitrification step: mix the dry powder desulfurization and denitrification agent with the flue gas treated in 2, and then transport it to the flue gas abso...

Embodiment 3

[0043] The sulfur dioxide content of the original flue gas is 1000-3000 mg / Nm 3 , Nitrogen oxide content is 200-500 mg / Nm 3、 The flow rate is 1-4m / s and the temperature is 90-120°C.

[0044] 1. Pre-dust removal step: pre-dedust the raw flue gas to remove most of the dust, thereby forming pre-dust removal flue gas;

[0045] 2. Pre-oxidation stage: mix 60 parts of hydrogen peroxide with 40 parts of water, and then spray in the middle and lower sections of the chimney to remove part of SO 2 , NO 2 etc. At the same time, oxygen can be generated to oxidize NO to produce easily soluble NO2, and sulfuric acid, sulfurous acid, nitric acid, and nitrous acid solutions are prepared by this method; the content of hydrogen peroxide is dynamically adjusted according to the content of NO in the flue gas.

[0046] 3. Desulfurization and denitrification step: mix the dry powder desulfurization and denitrification agent with the flue gas treated in 2, and then transport it to the flue gas ab...

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PUM

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Abstract

The invention belongs to the field of flue gas purification and relates to a novel flue gas desulfurization and denitrification process. The novel flue gas desulfurization and denitrification processincludes that flue gas is subjected to pre-dedusting, pre-oxidation, desulfurization and denitrification, after-dedusting and the like. By pre-dedusting, the content of suspended particles in flue gascan be reduced to facilitate subsequent desulfurization and denitrification; by pre-oxidation, NO in the flue gas can be removed while corresponding acids are generated, and the generated acids havereaction with alkali substances to prepare materials required by construction; in the step of desulfurization and denitrification, a novel efficient low-cost desulfurization and denitrification agentis adopted and comprises a mixture of coal gangue, magnesium oxide and sodium carbonate; by after-dedusting of the treated flue gas, dust of the desulfurization and denitrification agent is preventedfrom entering the atmosphere, secondary pollution is avoided, and unreacted desulfurization and denitrification agent can be recovered, so that cost reduction is realized. The novel flue gas desulfurization and denitrification process has advantages of simplicity in operation process, simplicity and convenience in process, low investment and operating cost and recyclability of side products. Therefore, the technical scheme of desulfurization and denitrification has high economic benefits and promising industrial application prospect.

Description

technical field [0001] The invention relates to a flue gas desulfurization and denitrification process, in particular to a multi-stage graded flue gas desulfurization and denitrification method. Background technique [0002] Coal combustion produces a large amount of SO 2 , NO X Flue gas with other components poses a huge threat and damage to the atmospheric environment and human health. Especially in recent years, with the increase of smog weather, people have begun to pay more and more attention to the atmospheric environment, and the requirements for flue gas purification technology are also getting higher and higher. [0003] Desulfurization and denitrification technology refers to the removal of SO from flue gas through some methods 2 , NO X and other components to realize the coordinated control of multi-air pollutants. However, the commonly used methods often separate desulfurization and denitrification, resulting in huge investment in equipment, large site occupa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/60B01D53/73B01D53/75B01D53/76B01D53/78B01D53/83B03C3/017
CPCB01D53/60B01D53/73B01D53/75B01D53/76B01D53/78B01D53/83B01D2251/102B01D2251/106B01D2251/304B01D2251/402B01D2251/602B01D2251/606B03C3/017Y02A50/20Y02A50/2351
Inventor 陈琪雯
Owner 陈琪雯
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