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Method for preparing lithium aluminate modified ternary anode material based on spent lithium-ion battery cathode materials

A technology for waste lithium batteries and cathode materials, which is applied in the field of preparation of ternary material precursors, can solve problems such as poor stability of ternary cathode materials, and achieve the effects of improving electrochemical performance, good economy and high product quality.

Active Publication Date: 2018-11-23
SHANDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the existing ternary cathode materials prepared from waste lithium battery cathode materials generally have the defect of poor stability.

Method used

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  • Method for preparing lithium aluminate modified ternary anode material based on spent lithium-ion battery cathode materials
  • Method for preparing lithium aluminate modified ternary anode material based on spent lithium-ion battery cathode materials
  • Method for preparing lithium aluminate modified ternary anode material based on spent lithium-ion battery cathode materials

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Disassemble and separate the positive electrode sheet from the waste lithium-ion battery and bake it at 650°C for 15 minutes. The obtained roasted product is crushed on a crusher, sieved, and the positive electrode material is separated from the aluminum foil; the molar ratio of nickel, cobalt, and manganese in the positive electrode material 5:2:3 and 8:1:1;

[0048] The positive electrode material was leached with 2.5 mol / L sodium hydroxide solution at 95°C for 40 minutes, the liquid-solid ratio of the sodium hydroxide solution to the positive electrode material was 10:1 during leaching, and the filtrate and filter cake were obtained by filtration;

[0049] Add sodium carbonate whose molar number is 0.5 times of the lithium ion molar number in the filtrate, stir and react at 25°C for 60min, generate a turbid liquid, filter to obtain lithium carbonate solid and filtrate, and the filtrate is 2.2mol / L sodium hydroxide solution; The recovery rate was 94.6%;

[0050] The ...

Embodiment 2

[0057] Disassemble and separate the positive electrode sheet from the waste lithium-ion battery and roast it at 600°C for 30 minutes. The roasted product obtained is crushed on a crusher, sieved, and the positive electrode material is separated from the aluminum foil; the molar ratio of nickel, cobalt, and manganese in the positive electrode material 6:2:2 and 5:2:3;

[0058] The positive electrode material was leached with 2.0 mol / L potassium hydroxide solution at 75°C for 60 minutes, the liquid-solid ratio of the potassium hydroxide solution to the positive electrode material was 8:1 during leaching, and the filtrate and filter cake were obtained by filtration;

[0059] Add potassium carbonate whose molar number is 0.5 times the lithium ion molar number in the filtrate, stir and react at 40°C for 50min, generate a turbid liquid, filter to obtain lithium carbonate solid and filtrate, and the filtrate is potassium hydroxide solution of 1.7mol / L; The recovery rate is 94.8%;

...

Embodiment 3

[0067] Disassemble and separate the positive electrode sheet from the waste lithium-ion battery and bake it at 500°C for 45 minutes. The obtained roasted product is crushed on a crusher, sieved, and the positive electrode material is separated from the aluminum foil; the molar ratio of nickel, cobalt, and manganese in the positive electrode material 6:2:2 and 4:2:2;

[0068] The positive electrode material was leached with 1.5 mol / L potassium hydroxide solution at 50°C for 100 minutes, the liquid-solid ratio of the potassium hydroxide solution to the positive electrode material was 6:1 during leaching, and the filtrate and filter cake were obtained by filtration;

[0069] Add potassium carbonate whose molar number is 0.5 times the lithium ion molar number in the filtrate, stir and react at 70°C for 30min, generate a cloudy liquid, filter to obtain lithium carbonate solid and filtrate, and the filtrate is potassium hydroxide solution of 1.2mol / L; The recovery rate was 94.4%;

...

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Abstract

The invention belongs to the technical field of ternary material precursor preparation, and particularly to a method for preparing lithium aluminate modified ternary anode materials based on spent lithium-ion battery cathode materials. The method comprises the steps that anode materials are separated from spent lithium-ion batteries; the anode materials are leached in a caustic solution and filtered; lithium carbonate is obtained by adding carbonate to filtrate; a filter cake is leached with sulfuric acid and leaching liquid is obtained; an adjustment solution is obtained by adjusting the molar ratios of nickel, cobalt and manganese in a leaching solution; the adjustment solution, an ammonia water solution and a caustic solution are flow into a reaction still together, and the ternary material precursor is prepared by coprecipitation; then the ternary material precursor is mixed with lithium carbonate for roasting, and ternary anode materials are obtained; and the lithium aluminate modified ternary anode materials are prepared by adding sec-butyl alcohol, lithium methoxide and the ternary anode materials in a mixture of ethyl acetoacetate, ethanol and water for reaction and roasting. The ternary anode materials have good structure stability, good electrochemical performance, lower production cost and high product quality, and realize the directional circulation of nickel-cobalt-manganese lithium resources.

Description

technical field [0001] The invention belongs to the technical field of preparation of ternary material precursors, and in particular relates to a method for preparing lithium aluminate modified ternary positive electrode materials based on waste lithium battery positive electrode materials. Background technique [0002] Global energy consumption and carbon dioxide emissions are showing an exponential growth trend, and the demand for new renewable energy is also increasing. Since 2014, policies related to new energy vehicles have been introduced intensively. With the continuous improvement of power battery technology, the entire industrial chain has entered a period of rapid development, and the shipment of power batteries has shown a rapid growth trend. In 2018, the first batch of power batteries will be retired. tide. Ternary lithium-ion batteries have a high recycling value among consumer batteries. In the next three years, the decommissioning scale of ternary lithium-io...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/485H01M4/505H01M4/525H01M10/052H01M10/54
CPCH01M4/362H01M4/485H01M4/505H01M4/525H01M10/052H01M10/54Y02E60/10Y02W30/84
Inventor 张亚莉王鸣陈霞景晓华王晶楚玮张洋
Owner SHANDONG UNIV OF TECH
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