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A kind of styrene-acrylate oil-absorbing swelling elastomer

A technology of acrylate and hydroxyacrylate, which is applied in the field of functional polymer materials, can solve the problems of restricting practical use, etc., and achieve the effects of moderate oil absorption expansion rate, high strength retention rate and moderate mechanical strength

Active Publication Date: 2021-06-04
SHANDONG NON METALLIC MATERIAL RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in this technical solution, the preparation of the oil-absorbing swelling material requires emulsion polymerization and high-temperature vulcanization to obtain the oil-absorbing swelling rubber. The obtained sheet material can only be co-vulcanized or pasted in the application process, which limits the actual use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] After mixing and stirring 20 parts of dodecyl acrylate, 20 parts of methyl methacrylate, 16 parts of styrene, and 7.5 parts of hydroxyethyl acrylate, 32 parts of ethyl acetate and 1 part of initiator were added, and the mixture was fully stirred and dissolved to obtain a mixture;

[0031] The above mixture is divided into two parts of equal quality, one part is placed in a three-diameter flask, one part is placed in a constant pressure dropping funnel, and nitrogen is passed into the three-necked flask to remove the oxygen in the bottle, and the stirring speed is controlled as 300rmp, heat the three-diameter flask to 75°C for the reaction, after 5 hours of reaction, control the liquid in the constant pressure dropping funnel to drop into the three-diameter flask at a constant temperature of 75°C for 2h, and then keep the reaction at 75°C for 3h. Naturally cooled to room temperature, and the solvent was evaporated under reduced pressure to obtain an oil-absorbing swollen ...

Embodiment 2

[0034] 23 parts of dodecyl acrylate, 10 parts of methyl methacrylate, 13 parts of styrene, 10.5 parts of hydroxypropyl acrylate, after mixing and stirring, add 28 parts of ethyl acetate, 1 part of initiator, fully stir and dissolve to obtain a mixture;

[0035] The above mixture is divided into two parts of equal quality, one part is placed in a three-diameter flask, one part is placed in a constant pressure dropping funnel, and nitrogen is passed into the three-necked flask to remove the oxygen in the bottle, and the stirring speed is controlled as 300rmp, heat the three-diameter flask to 70 °C for the reaction, after 5.5 hours of reaction, control the liquid in the constant pressure dropping funnel to drop into the three-diameter flask at a constant temperature of 70 °C for 3 hours, and keep the reaction at 70 °C for 3 hours. Cool to room temperature naturally, add polyester polyol (Covestro Desmophen 670) 15 parts were mixed, evaporated under reduced pressure, and the oil-...

Embodiment 3

[0038] 25 parts of dodecyl acrylate, 16 parts of methyl methacrylate, 14 parts of styrene, 9.5 parts of hydroxyethyl acrylate, after mixing and stirring, add 32 parts of ethyl acetate, 1 part of initiator, fully stir and dissolve to obtain a mixture;

[0039] The above mixture is divided into two parts of equal quality, one part is placed in a three-diameter flask, one part is placed in a constant pressure dropping funnel, and nitrogen is passed into the three-necked flask to remove the oxygen in the bottle, and the stirring speed is controlled as 300rmp, heat the three-diameter flask to 80 °C for the reaction, and after 4 hours of reaction, control the liquid in the constant pressure dropping funnel to drop into the three-diameter flask at a constant temperature of 80 °C for 1.5 hours, and then keep the reaction at 80 °C for 2 hours. Cool to room temperature naturally, add polyether polyol (Wanhua WANOL C2004) 20 parts were mixed evenly, evaporated under reduced pressure, a...

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Abstract

The invention belongs to the technical field of functional polymer materials. Styrene, acrylate and hydroxyl-containing acrylate are used to copolymerize chain-like resins, and polyisocyanate resins are cross-linked at room temperature to form oil-absorbing swelling elastomers; matching elastomers with oil-absorbing capabilities to achieve rare swelling. The styrene-acrylate oil-absorbing swelling elastomer involved in the present invention is composed of styrene-acrylate-hydroxyl-containing acrylate copolymer and isocyanate, and the equivalent ratio of active hydrogen to isocyanate in the copolymer is between 0.95 and 1.1; copolymerization The mass composition of the material is: 20-40 parts of long-chain alkyl acrylate, 5-25 parts of short-chain alkyl acrylate, 7.5-11.5 parts of hydroxyl-containing acrylic acid, and 5-16 parts of styrene. The oil-absorbing swellable elastomer has fast oil-absorbing rate and moderate oil-absorbing expansion rate; moderate mechanical strength, high strength retention rate after oil-absorbing, and good sealing effect; simple and quick construction; suitable for the field of oil leakage sealing, especially for oil tank leakage prevention Coating field.

Description

technical field [0001] The invention belongs to the technical field of functional polymer materials, relates to the design technology of oil absorption and swelling functional materials, and particularly relates to the design technology of oil absorption and swelling polymer materials. Background technique [0002] In order to enhance the protection of equipment fuel tanks, fuel tanks and storage tanks of fuel vehicles, a special coating has appeared on the fuel tank, which can quickly close the perforation after being hit by a light weapon to prevent oil leakage, fire and explosion. coating. The coating is made of elastic oil-absorbing and expanding rubber material. It is based on natural rubber with a low degree of vulcanization. After moderate cross-linking, a network structure is formed. The oil-absorbing material is stored in the grid structure by van der Waals force. The bullet closes the perforation to prevent the oil from seeping out. However, this traditional oil-...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/62C08F220/18C08F220/14C08F212/08C08F220/20C09D175/04
CPCC09D175/04C08F220/18C08G18/6225C08F220/1818C08F220/1812C08F220/14C08F212/08C08F220/20C08F220/1804C08F220/1802
Inventor 侯瑞张岩李明俊周桂明马晓斌段衍鹏刘景李桂群
Owner SHANDONG NON METALLIC MATERIAL RES INST