Titanium alloy composite capable of resisting high temperature oxidation and hot salt corrosion and preparation method thereof

A technology of anti-high temperature oxidation and composite materials, which is applied in the field of titanium alloy materials, can solve the problems of high temperature oxidation resistance and high temperature hot salt corrosion resistance of titanium alloy composite materials, and limit the technology of aeroengines, etc., and achieve enhanced transition characteristics , enhance chemical stability, good chemical stability effect

Inactive Publication Date: 2018-12-18
SICHUAN ENG TECHN COLLEGE
View PDF7 Cites 6 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0013] 2. When oxidation occurs at the interface between the enamel coating and the titanium alloy substrate, the oxygen in the enamel gradually migrates to the titanium alloy substrate at the interface, and the dissolved oxygen in the titanium alloy substrate will increase, thereby reducing the oxidation resistance of the ceramic coating ability;
[0014] 3. Most titanium alloys contain Al element, the main component of SiO in enamel coating 2 When in contact with TiAl in titanium alloy, it will react to form TiSiO under the condition of firing molding temperature. 3 Phase, TiSiO 3 Phase will reduce the bonding force between enamel coating and titanium alloy substrate
[0015] In summary, in the existing techno

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0083] The titanium alloy composite material of the present invention comprises a titanium alloy substrate made of TC4 titanium alloy material - that is, a titanium alloy part. The high temperature side surface of the titanium alloy substrate is provided with a ceramic transition layer and an enamel coating, and the ceramic transition layer is placed on the titanium alloy substrate. Between the ceramic transition layer and the enamel coating, the ceramic transition layer is a micro-arc oxidation ceramic layer. The thickness of the ceramic transition layer is about 10-17um. The gradient composite coating for high temperature protection is formed on the titanium alloy substrate by the enamel coating and the ceramic transition layer.

[0084] The electrolytic solution used for the preparation of the above-mentioned ceramic transition layer is mainly composed of raw materials with the following concentration ratios: sodium silicate is 60g / L, sodium hydroxide is 5g / L, sodium borate i...

Embodiment 2

[0108] The titanium alloy composite material of the present invention comprises a titanium alloy substrate made of TC4 titanium alloy material - that is, a titanium alloy part. The high temperature side surface of the titanium alloy substrate is provided with a ceramic transition layer and an enamel coating, and the ceramic transition layer is placed on the titanium alloy substrate. Between the ceramic transition layer and the enamel coating, the ceramic transition layer is a micro-arc oxidation ceramic layer. The thickness of the ceramic transition layer is about 12-20um. The gradient composite coating for high temperature protection is formed on the titanium alloy substrate by the enamel coating and the ceramic transition layer.

[0109] The electrolytic solution used for the preparation of the above-mentioned ceramic transition layer is mainly composed of raw materials with the following concentration ratios: sodium silicate is 58g / L, sodium hydroxide is 5.5g / L, sodium borate...

Embodiment 3

[0133] The titanium alloy composite material of the present invention comprises a titanium alloy substrate made of TC4 titanium alloy material - that is, a titanium alloy part. The high temperature side surface of the titanium alloy substrate is provided with a ceramic transition layer and an enamel coating, and the ceramic transition layer is placed on the titanium alloy substrate. Between the ceramic transition layer and the enamel coating, the ceramic transition layer is a micro-arc oxidation ceramic layer. The thickness of the ceramic transition layer is about 15-25um. The gradient composite coating for high temperature protection is formed on the titanium alloy substrate by the enamel coating and the ceramic transition layer.

[0134] The electrolytic solution used for the preparation of the above-mentioned ceramic transition layer is mainly composed of the raw materials of the following concentration ratio: sodium silicate is 61g / L, sodium hydroxide is 4.5g / L, sodium borat...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Thicknessaaaaaaaaaa
Granularityaaaaaaaaaa
Oxidative weight gainaaaaaaaaaa
Login to view more

Abstract

The invention discloses a titanium alloy composite capable of resisting high temperature oxidation and hot salt corrosion and a preparation method thereof. The titanium alloy composite comprises a titanium alloy substrate; a ceramic transition layer and an enamel coating are arranged on the surface of the titanium alloy substrate; the ceramic transition layer is located between the titanium alloysubstrate and the enamel coating; the ceramic transition layer is a micro-arc oxidation ceramic layer; and the enamel coating and the ceramic transition layer form a high-temperature protection gradient composite coating on the titanium alloy substrate. The titanium alloy composite is excellent in resistance to high temperature oxidation and high temperature hot salt corrosion and the gradient composite coating is good in chemical stability.

Description

technical field [0001] The invention relates to a titanium alloy material, in particular to a titanium alloy composite material resistant to high temperature oxidation and hot salt corrosion, and a preparation method of the titanium alloy composite material. Background technique [0002] Titanium alloy has the characteristics of low density, high specific strength, high-temperature mechanical properties and good corrosion resistance. It is an excellent high-temperature structural material and is mainly used for the preparation of aero-engines. [0003] When the titanium alloy is used at a temperature exceeding 600°C, an oxide film with poor oxidation resistance will be formed on the surface, which will lead to a serious decrease in the performance of the titanium alloy. [0004] At present, the heat-resistant titanium alloys used in my country's aero-engines are mainly TC1~TC10, etc., and their service temperature is usually lower than 600°C; in addition, when titanium alloy...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C25D11/26C23D5/02C03C8/14
CPCC03C8/14C23D5/02C25D11/026C25D11/26
Inventor 肖峰蔺虹宾苗景国张光明杜娟王新颖
Owner SICHUAN ENG TECHN COLLEGE
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products